Mechanistic Study of Silane Alcoholysis Reactions with Self-Assembled Monolayer-Functionalized Gold Nanoparticle Catalysts

Mechanistic Study of Silane Alcoholysis Reactions with Self-Assembled Monolayer-Functionalized Gold Nanoparticle Catalysts

The self-assembled monolayer (SAM)-modified metallic nanoparticles (MNPs) often exhibit improved chemoselectivity in various catalytic reactions by controlling the reactants’ orientations adsorbed in the SAM; however, there have been a few examples showing that the reaction rate, i.e., catalytic act...

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Bibliographic Details
Main Authors: Katsuhiro Isozaki, Tomoya Taguchi, Kosuke Ishibashi, Takafumi Shimoaka, Wataru Kurashige, Yuichi Negishi, Takeshi Hasegawa, Masaharu Nakamura, Kazushi Miki
Format: Article
Language:English
Published: MDPI AG 2020-08-01
Series:Catalysts
Subjects:
gold nanoparticle
catalysts
self-assembled monolayer
silane alcoholysis
size effect
support effect
Online Access:https://www.mdpi.com/2073-4344/10/8/908

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