A study on electrospray mass spectrometry of fullerenol C60(OH)24
Full characterization of fullerenol C60(OH)24 by HPLC ESI-MS in negative and positive ionization modes was achieved. Fragmentor voltage and capillary voltage were optimized in order to obtain a good signal stability and the best peak intensity distribution for the fullerenol C60(OH)24 in both negati...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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Beilstein-Institut
2013-07-01
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| Series: | Beilstein Journal of Organic Chemistry |
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| Online Access: | https://doi.org/10.3762/bjoc.9.145 |
| _version_ | 1819276012924436480 |
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| author | Mihaela Silion Andrei Dascalu Mariana Pinteala Bogdan C. Simionescu Cezar Ungurenasu |
| author_facet | Mihaela Silion Andrei Dascalu Mariana Pinteala Bogdan C. Simionescu Cezar Ungurenasu |
| author_sort | Mihaela Silion |
| collection | DOAJ |
| description | Full characterization of fullerenol C60(OH)24 by HPLC ESI-MS in negative and positive ionization modes was achieved. Fragmentor voltage and capillary voltage were optimized in order to obtain a good signal stability and the best peak intensity distribution for the fullerenol C60(OH)24 in both negative and positive modes. While the predominant base peak observed for C60(OH)24 in the negative ionization mode was [M − H]− at m/z 1127, those observed in the positive mode were multiply charged [M − H2O + 4H]4+ at m/z 279 and [M − 12H2O + 2NH3 + 6H]6+ at m/z 158. |
| first_indexed | 2024-12-23T23:33:27Z |
| format | Article |
| id | doaj.art-aa65ed7bdf224f6ca5d0953faa3264a3 |
| institution | Directory Open Access Journal |
| issn | 1860-5397 |
| language | English |
| last_indexed | 2024-12-23T23:33:27Z |
| publishDate | 2013-07-01 |
| publisher | Beilstein-Institut |
| record_format | Article |
| series | Beilstein Journal of Organic Chemistry |
| spelling | doaj.art-aa65ed7bdf224f6ca5d0953faa3264a32022-12-21T17:25:57ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972013-07-01911285129510.3762/bjoc.9.1451860-5397-9-145A study on electrospray mass spectrometry of fullerenol C60(OH)24Mihaela Silion0Andrei Dascalu1Mariana Pinteala2Bogdan C. Simionescu3Cezar Ungurenasu4Petru Poni Institute of Macromolecular Chemistry, Centre of Advanced Research in Bionanoconjugates and Biopolymers, Aleea Grigore Ghica Voda 41A, Iasi 700487, RomaniaPetru Poni Institute of Macromolecular Chemistry, Centre of Advanced Research in Bionanoconjugates and Biopolymers, Aleea Grigore Ghica Voda 41A, Iasi 700487, RomaniaPetru Poni Institute of Macromolecular Chemistry, Centre of Advanced Research in Bionanoconjugates and Biopolymers, Aleea Grigore Ghica Voda 41A, Iasi 700487, RomaniaPetru Poni Institute of Macromolecular Chemistry, Centre of Advanced Research in Bionanoconjugates and Biopolymers, Aleea Grigore Ghica Voda 41A, Iasi 700487, RomaniaPetru Poni Institute of Macromolecular Chemistry, Centre of Advanced Research in Bionanoconjugates and Biopolymers, Aleea Grigore Ghica Voda 41A, Iasi 700487, RomaniaFull characterization of fullerenol C60(OH)24 by HPLC ESI-MS in negative and positive ionization modes was achieved. Fragmentor voltage and capillary voltage were optimized in order to obtain a good signal stability and the best peak intensity distribution for the fullerenol C60(OH)24 in both negative and positive modes. While the predominant base peak observed for C60(OH)24 in the negative ionization mode was [M − H]− at m/z 1127, those observed in the positive mode were multiply charged [M − H2O + 4H]4+ at m/z 279 and [M − 12H2O + 2NH3 + 6H]6+ at m/z 158.https://doi.org/10.3762/bjoc.9.145electrosprayfullerenol C60(OH)24mass spectrometry |
| spellingShingle | Mihaela Silion Andrei Dascalu Mariana Pinteala Bogdan C. Simionescu Cezar Ungurenasu A study on electrospray mass spectrometry of fullerenol C60(OH)24 Beilstein Journal of Organic Chemistry electrospray fullerenol C60(OH)24 mass spectrometry |
| title | A study on electrospray mass spectrometry of fullerenol C60(OH)24 |
| title_full | A study on electrospray mass spectrometry of fullerenol C60(OH)24 |
| title_fullStr | A study on electrospray mass spectrometry of fullerenol C60(OH)24 |
| title_full_unstemmed | A study on electrospray mass spectrometry of fullerenol C60(OH)24 |
| title_short | A study on electrospray mass spectrometry of fullerenol C60(OH)24 |
| title_sort | study on electrospray mass spectrometry of fullerenol c60 oh 24 |
| topic | electrospray fullerenol C60(OH)24 mass spectrometry |
| url | https://doi.org/10.3762/bjoc.9.145 |
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