Performance Enhancement of Three-Dimensional MAPbI<sub>3</sub> Perovskite Solar Cells by Doping Perovskite Films with CsPbX<sub>3</sub> Quantum Dots

Perovskite thin films directly impact solar cell properties, making defect reduction crucial in perovskite solar cell research. In our study, we used perovskite quantum dots in the anti-solvent to act as nucleation centers in MAPbI3 thin films. These centers had lower nucleation barriers than homoge...

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Bibliographic Details
Main Authors: Ming-Chen Tsai, Sheng-Yuan Chu, Po-Ching Kao
Format: Article
Language:English
Published: MDPI AG 2024-03-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/17/6/1238
Description
Summary:Perovskite thin films directly impact solar cell properties, making defect reduction crucial in perovskite solar cell research. In our study, we used perovskite quantum dots in the anti-solvent to act as nucleation centers in MAPbI3 thin films. These centers had lower nucleation barriers than homogeneous nucleation, improving perovskite crystallinity, reducing defects, and extending carrier lifetime. Fine-tuning the energy band also enhanced carrier transport. The most effective results were obtained using CsPb(Br<sub>0.5</sub> I<sub>0.5</sub>)<sub>3</sub> perovskite quantum dots. The resulting device, ITO/SnO<sub>2</sub>/MAPbI<sub>3</sub> (300 nm)/spiro-OMeTAD (200 nm)/Ag (100 nm), achieved a 12.88% power conversion efficiency, a 16% increase from the standard element. The modified device maintained approximately 95% of its efficiency over 100 h in a 70% humidity environment.
ISSN:1996-1944