High field phase transition of cathode material Li2MnSiO4 for lithium-ion battery
The magnetic properties of the candidate lithium-ion battery cathode materials Li _2 MnSiO _4 have been studied experimentally using static and pulsed high magnetic fields. A field-induced magnetic transition is observed in low temperature region, in which a saturation magnetization is observed abov...
| Main Authors: | , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
IOP Publishing
2020-01-01
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| Series: | Materials Research Express |
| Subjects: | |
| Online Access: | https://doi.org/10.1088/2053-1591/ab5c39 |
| _version_ | 1797747167430967296 |
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| author | Feng Yang Zhengcai Xia Sha Huang Xiaoxing Zhang Yujie Song Guiling Xiao Gangqin Shao Yong Liu Han Deng Dequan Jiang Zhongwen Ouyang |
| author_facet | Feng Yang Zhengcai Xia Sha Huang Xiaoxing Zhang Yujie Song Guiling Xiao Gangqin Shao Yong Liu Han Deng Dequan Jiang Zhongwen Ouyang |
| author_sort | Feng Yang |
| collection | DOAJ |
| description | The magnetic properties of the candidate lithium-ion battery cathode materials Li _2 MnSiO _4 have been studied experimentally using static and pulsed high magnetic fields. A field-induced magnetic transition is observed in low temperature region, in which a saturation magnetization is observed above 27 T which confirms that the Mn-ion has a dominant low spin state with a saturated magnetic moment of ∼3.1 μ _B /Mn. With the change of temperature and magnetic field, the Li _2 MnSiO _4 shows a complex magnetic phase transition. Considering to the coupling between spin, charge and orbital, the field-induced magnetic transition may affect the charge-discharge behavior of the cathode material, thus, the study is expected to explore the possibility and stability of the candidate lithium-ion battery cathode materials used in the low temperature and high magnetic field circumstance and its performance degradation. |
| first_indexed | 2024-03-12T15:48:11Z |
| format | Article |
| id | doaj.art-aacad04f4af846d4a67bf450102dcf2a |
| institution | Directory Open Access Journal |
| issn | 2053-1591 |
| language | English |
| last_indexed | 2024-03-12T15:48:11Z |
| publishDate | 2020-01-01 |
| publisher | IOP Publishing |
| record_format | Article |
| series | Materials Research Express |
| spelling | doaj.art-aacad04f4af846d4a67bf450102dcf2a2023-08-09T15:21:08ZengIOP PublishingMaterials Research Express2053-15912020-01-017202610410.1088/2053-1591/ab5c39High field phase transition of cathode material Li2MnSiO4 for lithium-ion batteryFeng Yang0https://orcid.org/0000-0001-6480-3417Zhengcai Xia1https://orcid.org/0000-0002-6383-573XSha Huang2Xiaoxing Zhang3https://orcid.org/0000-0003-0262-2666Yujie Song4Guiling Xiao5Gangqin Shao6Yong Liu7Han Deng8Dequan Jiang9Zhongwen Ouyang10https://orcid.org/0000-0002-2887-6755Wuhan National High Magnetic Field Center & School of Physics, Huazhong University of Science and Technology , Wuhan 430074, People’s Republic of ChinaWuhan National High Magnetic Field Center & School of Physics, Huazhong University of Science and Technology , Wuhan 430074, People’s Republic of ChinaWuhan National High Magnetic Field Center & School of Physics, Huazhong University of Science and Technology , Wuhan 430074, People’s Republic of ChinaWuhan National High Magnetic Field Center & School of Physics, Huazhong University of Science and Technology , Wuhan 430074, People’s Republic of ChinaWuhan National High Magnetic Field Center & School of Physics, Huazhong University of Science and Technology , Wuhan 430074, People’s Republic of ChinaWuhan National High Magnetic Field Center & School of Physics, Huazhong University of Science and Technology , Wuhan 430074, People’s Republic of ChinaState Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology , Wuhan 430074, People’s Republic of ChinaSchool of Physics and Technology, Wuhan University , Wuhan 430072, People’s Republic of ChinaWuhan National High Magnetic Field Center & School of Physics, Huazhong University of Science and Technology , Wuhan 430074, People’s Republic of ChinaWuhan National High Magnetic Field Center & School of Physics, Huazhong University of Science and Technology , Wuhan 430074, People’s Republic of ChinaWuhan National High Magnetic Field Center & School of Physics, Huazhong University of Science and Technology , Wuhan 430074, People’s Republic of ChinaThe magnetic properties of the candidate lithium-ion battery cathode materials Li _2 MnSiO _4 have been studied experimentally using static and pulsed high magnetic fields. A field-induced magnetic transition is observed in low temperature region, in which a saturation magnetization is observed above 27 T which confirms that the Mn-ion has a dominant low spin state with a saturated magnetic moment of ∼3.1 μ _B /Mn. With the change of temperature and magnetic field, the Li _2 MnSiO _4 shows a complex magnetic phase transition. Considering to the coupling between spin, charge and orbital, the field-induced magnetic transition may affect the charge-discharge behavior of the cathode material, thus, the study is expected to explore the possibility and stability of the candidate lithium-ion battery cathode materials used in the low temperature and high magnetic field circumstance and its performance degradation.https://doi.org/10.1088/2053-1591/ab5c39Li2MnSiO4cathodemagnetizationhigh magnetic field |
| spellingShingle | Feng Yang Zhengcai Xia Sha Huang Xiaoxing Zhang Yujie Song Guiling Xiao Gangqin Shao Yong Liu Han Deng Dequan Jiang Zhongwen Ouyang High field phase transition of cathode material Li2MnSiO4 for lithium-ion battery Materials Research Express Li2MnSiO4 cathode magnetization high magnetic field |
| title | High field phase transition of cathode material Li2MnSiO4 for lithium-ion battery |
| title_full | High field phase transition of cathode material Li2MnSiO4 for lithium-ion battery |
| title_fullStr | High field phase transition of cathode material Li2MnSiO4 for lithium-ion battery |
| title_full_unstemmed | High field phase transition of cathode material Li2MnSiO4 for lithium-ion battery |
| title_short | High field phase transition of cathode material Li2MnSiO4 for lithium-ion battery |
| title_sort | high field phase transition of cathode material li2mnsio4 for lithium ion battery |
| topic | Li2MnSiO4 cathode magnetization high magnetic field |
| url | https://doi.org/10.1088/2053-1591/ab5c39 |
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