Bis(2,4,6-triamino-1,3,5-triazin-1-ium) pyrazine-2,3-dicarboxylate tetrahydrate: a synchrotron radiation study
The title compound, 2C3H7N6+·C6H2N2O42−·4H2O or (tataH)2(pzdc)·4H2O, was synthesised by a reaction between pyrazine-2,3-dicarboxylic acid (H2pzdc) as a proton donor and 2,4,6-triamino-1,3,5-triazin (tata) as a proton acceptor. In the crystal struc...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810017290 |
| _version_ | 1819281187416309760 |
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| author | Hossein Eshtiagh-Hosseini Azam Hassanpoor Laura Canadillas-Delgado Masoud Mirzaei |
| author_facet | Hossein Eshtiagh-Hosseini Azam Hassanpoor Laura Canadillas-Delgado Masoud Mirzaei |
| author_sort | Hossein Eshtiagh-Hosseini |
| collection | DOAJ |
| description | The title compound, 2C3H7N6+·C6H2N2O42−·4H2O or (tataH)2(pzdc)·4H2O, was synthesised by a reaction between pyrazine-2,3-dicarboxylic acid (H2pzdc) as a proton donor and 2,4,6-triamino-1,3,5-triazin (tata) as a proton acceptor. In the crystal structure, an extensive series of O—H...O, O—H...N, N—H...O and N—H...N hydrogen bonds generates a three-dimensional framework with the hydrogen bonding involving most donor and acceptor centers. π–π stacking interactions are also observed between adjacent triazine rings, with centroid–centroid distances of 3.4994 (8) and 3.5922 (7) Å. |
| first_indexed | 2024-12-24T00:55:42Z |
| format | Article |
| id | doaj.art-aad30c80fba1464f817dad8155464716 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:55:42Z |
| publishDate | 2010-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-aad30c80fba1464f817dad81554647162022-12-21T17:23:29ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-06-01666o1368o136910.1107/S1600536810017290Bis(2,4,6-triamino-1,3,5-triazin-1-ium) pyrazine-2,3-dicarboxylate tetrahydrate: a synchrotron radiation studyHossein Eshtiagh-HosseiniAzam HassanpoorLaura Canadillas-DelgadoMasoud MirzaeiThe title compound, 2C3H7N6+·C6H2N2O42−·4H2O or (tataH)2(pzdc)·4H2O, was synthesised by a reaction between pyrazine-2,3-dicarboxylic acid (H2pzdc) as a proton donor and 2,4,6-triamino-1,3,5-triazin (tata) as a proton acceptor. In the crystal structure, an extensive series of O—H...O, O—H...N, N—H...O and N—H...N hydrogen bonds generates a three-dimensional framework with the hydrogen bonding involving most donor and acceptor centers. π–π stacking interactions are also observed between adjacent triazine rings, with centroid–centroid distances of 3.4994 (8) and 3.5922 (7) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536810017290 |
| spellingShingle | Hossein Eshtiagh-Hosseini Azam Hassanpoor Laura Canadillas-Delgado Masoud Mirzaei Bis(2,4,6-triamino-1,3,5-triazin-1-ium) pyrazine-2,3-dicarboxylate tetrahydrate: a synchrotron radiation study Acta Crystallographica Section E |
| title | Bis(2,4,6-triamino-1,3,5-triazin-1-ium) pyrazine-2,3-dicarboxylate tetrahydrate: a synchrotron radiation study |
| title_full | Bis(2,4,6-triamino-1,3,5-triazin-1-ium) pyrazine-2,3-dicarboxylate tetrahydrate: a synchrotron radiation study |
| title_fullStr | Bis(2,4,6-triamino-1,3,5-triazin-1-ium) pyrazine-2,3-dicarboxylate tetrahydrate: a synchrotron radiation study |
| title_full_unstemmed | Bis(2,4,6-triamino-1,3,5-triazin-1-ium) pyrazine-2,3-dicarboxylate tetrahydrate: a synchrotron radiation study |
| title_short | Bis(2,4,6-triamino-1,3,5-triazin-1-ium) pyrazine-2,3-dicarboxylate tetrahydrate: a synchrotron radiation study |
| title_sort | bis 2 4 6 triamino 1 3 5 triazin 1 ium pyrazine 2 3 dicarboxylate tetrahydrate a synchrotron radiation study |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810017290 |
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