Multiple Stimuli-Responsive Conformational Exchanges of Biphen[3]arene Macrocycle
Conformational exchanges of synthetic macrocyclic acceptors are rather fast, which is rarely studied in the absence of guests. Here, we report multiple stimuli-responsive conformational exchanges between two preexisting conformations of 2,2′,4,4′-tetramethoxyl biphen[3]arene (MeBP3) macrocycle. Stru...
| Main Authors: | , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2020-12-01
|
| Series: | Molecules |
| Subjects: | |
| Online Access: | https://www.mdpi.com/1420-3049/25/24/5780 |
| _version_ | 1797545415166394368 |
|---|---|
| author | Yiliang Wang Liu-Pan Yang Xiang Zhao Lei Cui Jian Li Xueshun Jia Jianhui Fang Chunju Li |
| author_facet | Yiliang Wang Liu-Pan Yang Xiang Zhao Lei Cui Jian Li Xueshun Jia Jianhui Fang Chunju Li |
| author_sort | Yiliang Wang |
| collection | DOAJ |
| description | Conformational exchanges of synthetic macrocyclic acceptors are rather fast, which is rarely studied in the absence of guests. Here, we report multiple stimuli-responsive conformational exchanges between two preexisting conformations of 2,2′,4,4′-tetramethoxyl biphen[3]arene (MeBP3) macrocycle. Structures of these two conformations are both observed in solid state, and characterized by <sup>1</sup>H NMR, <sup>13</sup>C NMR and 2D NMR in solution. In particular, conformational exchanges can respond to solvents, temperatures, guest binding and acid/base addition. The current system may have a role to play in the construction of molecular switches and other stimuli-responsive systems. |
| first_indexed | 2024-03-10T14:15:50Z |
| format | Article |
| id | doaj.art-aae956fc2271417b913643364fbc0129 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-10T14:15:50Z |
| publishDate | 2020-12-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-aae956fc2271417b913643364fbc01292023-11-20T23:51:20ZengMDPI AGMolecules1420-30492020-12-012524578010.3390/molecules25245780Multiple Stimuli-Responsive Conformational Exchanges of Biphen[3]arene MacrocycleYiliang Wang0Liu-Pan Yang1Xiang Zhao2Lei Cui3Jian Li4Xueshun Jia5Jianhui Fang6Chunju Li7Center for Supramolecular Chemistry and Catalysis and Department of Chemistry, School of Materials Science and Engineering, Shanghai University, Shanghai 200444, ChinaAcademy for Advanced Interdisciplinary Studies, Southern University of Science and Technology, Xueyuan Blvd 1088, Shenzhen 518055, ChinaCenter for Supramolecular Chemistry and Catalysis and Department of Chemistry, School of Materials Science and Engineering, Shanghai University, Shanghai 200444, ChinaCenter for Supramolecular Chemistry and Catalysis and Department of Chemistry, School of Materials Science and Engineering, Shanghai University, Shanghai 200444, ChinaCenter for Supramolecular Chemistry and Catalysis and Department of Chemistry, School of Materials Science and Engineering, Shanghai University, Shanghai 200444, ChinaCenter for Supramolecular Chemistry and Catalysis and Department of Chemistry, School of Materials Science and Engineering, Shanghai University, Shanghai 200444, ChinaCenter for Supramolecular Chemistry and Catalysis and Department of Chemistry, School of Materials Science and Engineering, Shanghai University, Shanghai 200444, ChinaCenter for Supramolecular Chemistry and Catalysis and Department of Chemistry, School of Materials Science and Engineering, Shanghai University, Shanghai 200444, ChinaConformational exchanges of synthetic macrocyclic acceptors are rather fast, which is rarely studied in the absence of guests. Here, we report multiple stimuli-responsive conformational exchanges between two preexisting conformations of 2,2′,4,4′-tetramethoxyl biphen[3]arene (MeBP3) macrocycle. Structures of these two conformations are both observed in solid state, and characterized by <sup>1</sup>H NMR, <sup>13</sup>C NMR and 2D NMR in solution. In particular, conformational exchanges can respond to solvents, temperatures, guest binding and acid/base addition. The current system may have a role to play in the construction of molecular switches and other stimuli-responsive systems.https://www.mdpi.com/1420-3049/25/24/5780macrocycleconformational exchangemultiple stimuli-responsive |
| spellingShingle | Yiliang Wang Liu-Pan Yang Xiang Zhao Lei Cui Jian Li Xueshun Jia Jianhui Fang Chunju Li Multiple Stimuli-Responsive Conformational Exchanges of Biphen[3]arene Macrocycle Molecules macrocycle conformational exchange multiple stimuli-responsive |
| title | Multiple Stimuli-Responsive Conformational Exchanges of Biphen[3]arene Macrocycle |
| title_full | Multiple Stimuli-Responsive Conformational Exchanges of Biphen[3]arene Macrocycle |
| title_fullStr | Multiple Stimuli-Responsive Conformational Exchanges of Biphen[3]arene Macrocycle |
| title_full_unstemmed | Multiple Stimuli-Responsive Conformational Exchanges of Biphen[3]arene Macrocycle |
| title_short | Multiple Stimuli-Responsive Conformational Exchanges of Biphen[3]arene Macrocycle |
| title_sort | multiple stimuli responsive conformational exchanges of biphen 3 arene macrocycle |
| topic | macrocycle conformational exchange multiple stimuli-responsive |
| url | https://www.mdpi.com/1420-3049/25/24/5780 |
| work_keys_str_mv | AT yiliangwang multiplestimuliresponsiveconformationalexchangesofbiphen3arenemacrocycle AT liupanyang multiplestimuliresponsiveconformationalexchangesofbiphen3arenemacrocycle AT xiangzhao multiplestimuliresponsiveconformationalexchangesofbiphen3arenemacrocycle AT leicui multiplestimuliresponsiveconformationalexchangesofbiphen3arenemacrocycle AT jianli multiplestimuliresponsiveconformationalexchangesofbiphen3arenemacrocycle AT xueshunjia multiplestimuliresponsiveconformationalexchangesofbiphen3arenemacrocycle AT jianhuifang multiplestimuliresponsiveconformationalexchangesofbiphen3arenemacrocycle AT chunjuli multiplestimuliresponsiveconformationalexchangesofbiphen3arenemacrocycle |