Effect of CO-SCR by CTAB modified vanadosilicate molecular sieve on low temperature catalytic denitrification

To improve the NO-CO low-temperature selective catalytic reduction (SCR) denitration rate, finding new effective denitration catalysts has become the focus of the denitration field. A vanadium-substituted molecular sieve AM-6 was synthesized by hydrothermal method, the performance of AM-6 molecular...

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Bibliographic Details
Main Authors: HE Han-bing, FU Guo-you, ZHANG Li, ZENG Jing, WANG Yu-si, LONG Hong-ming, FAN You-qi, ZHENG Ya-jie, MA Ying
Format: Article
Language:zho
Published: Journal of Materials Engineering 2021-12-01
Series:Cailiao gongcheng
Subjects:
Online Access:http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2020.001076
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Summary:To improve the NO-CO low-temperature selective catalytic reduction (SCR) denitration rate, finding new effective denitration catalysts has become the focus of the denitration field. A vanadium-substituted molecular sieve AM-6 was synthesized by hydrothermal method, the performance of AM-6 molecular sieve was improved by surfactant-assisted synthesis. The effect of different amounts of CTAB on the morphology, composition and the catalytic reduction performance was studied. These catalysts were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The results show that the addition of CTAB does not introduce other impurity elements. When the ratio of CTAB to V is 1:4, AM-6(1/4CTAB) has more regular surface morphology, better crystalline formability, well-balanced ratio of V5+/V4+, and the denitrification activity reaches 81.54% at 150℃, which is reduced by 50℃ than the temperature at which the denitrification activity of AM-6 reaches 80%.
ISSN:1001-4381