Bis(μ-2-phenylquinoline-4-carboxylato)bis[aqua(1,10-phenanthroline)(2-phenylquinoline-4-carboxylato)manganese(II)] dihydrate
In the centrosymmetric dinuclear title complex, [Mn2(C16H10NO2)4(C12H8N2)2(H2O)2]·2H2O, the MnII cation is in a distorted octahedral coordination geometry defined by two N atoms from a 1,10-phenanthroline ligand, one water O atom and three O atoms from three 2-phenylquinoline-4-carboxyl...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811039341 |
| _version_ | 1818958625355333632 |
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| author | Xing Li Tian-Hua Li Mei-Qin Zha Yue Bing Wei-Wei Li |
| author_facet | Xing Li Tian-Hua Li Mei-Qin Zha Yue Bing Wei-Wei Li |
| author_sort | Xing Li |
| collection | DOAJ |
| description | In the centrosymmetric dinuclear title complex, [Mn2(C16H10NO2)4(C12H8N2)2(H2O)2]·2H2O, the MnII cation is in a distorted octahedral coordination geometry defined by two N atoms from a 1,10-phenanthroline ligand, one water O atom and three O atoms from three 2-phenylquinoline-4-carboxylate anions. A pair of 2-phenylquinoline-4-carboxylate anions bridge two Mn cations, forming the dinuclear molecule. An intramoleculr O—H...O hydrogen bond occurs. Intermolecular O—H...O and O—H...N hydrogen bonds are present in the crystal structure. |
| first_indexed | 2024-12-20T11:28:43Z |
| format | Article |
| id | doaj.art-aaf5beaecc974b62a98c197b30967482 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:28:43Z |
| publishDate | 2011-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-aaf5beaecc974b62a98c197b309674822022-12-21T19:42:18ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-10-016710m1464m146510.1107/S1600536811039341Bis(μ-2-phenylquinoline-4-carboxylato)bis[aqua(1,10-phenanthroline)(2-phenylquinoline-4-carboxylato)manganese(II)] dihydrateXing LiTian-Hua LiMei-Qin ZhaYue BingWei-Wei LiIn the centrosymmetric dinuclear title complex, [Mn2(C16H10NO2)4(C12H8N2)2(H2O)2]·2H2O, the MnII cation is in a distorted octahedral coordination geometry defined by two N atoms from a 1,10-phenanthroline ligand, one water O atom and three O atoms from three 2-phenylquinoline-4-carboxylate anions. A pair of 2-phenylquinoline-4-carboxylate anions bridge two Mn cations, forming the dinuclear molecule. An intramoleculr O—H...O hydrogen bond occurs. Intermolecular O—H...O and O—H...N hydrogen bonds are present in the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536811039341 |
| spellingShingle | Xing Li Tian-Hua Li Mei-Qin Zha Yue Bing Wei-Wei Li Bis(μ-2-phenylquinoline-4-carboxylato)bis[aqua(1,10-phenanthroline)(2-phenylquinoline-4-carboxylato)manganese(II)] dihydrate Acta Crystallographica Section E |
| title | Bis(μ-2-phenylquinoline-4-carboxylato)bis[aqua(1,10-phenanthroline)(2-phenylquinoline-4-carboxylato)manganese(II)] dihydrate |
| title_full | Bis(μ-2-phenylquinoline-4-carboxylato)bis[aqua(1,10-phenanthroline)(2-phenylquinoline-4-carboxylato)manganese(II)] dihydrate |
| title_fullStr | Bis(μ-2-phenylquinoline-4-carboxylato)bis[aqua(1,10-phenanthroline)(2-phenylquinoline-4-carboxylato)manganese(II)] dihydrate |
| title_full_unstemmed | Bis(μ-2-phenylquinoline-4-carboxylato)bis[aqua(1,10-phenanthroline)(2-phenylquinoline-4-carboxylato)manganese(II)] dihydrate |
| title_short | Bis(μ-2-phenylquinoline-4-carboxylato)bis[aqua(1,10-phenanthroline)(2-phenylquinoline-4-carboxylato)manganese(II)] dihydrate |
| title_sort | bis amp 956 2 phenylquinoline 4 carboxylato bis aqua 1 10 phenanthroline 2 phenylquinoline 4 carboxylato manganese ii dihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811039341 |
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