Aquatricarbonyl(3,5,7-tribromotropolonato)rhenium(I) methanol solvate
The title complex, [Re(C7H2Br3O2)(CO)3(H2O)]·CH3OH, crystallized as a neutral ReI compound and one methanol solvent molecule in the asymmetric unit. The metal centre is coordinated facially by three carbonyl groups. The bidentate tribromotropolanate ligand and a water molecule complete the...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-12-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808038737 |
| _version_ | 1818491374245249024 |
|---|---|
| author | Andreas Roodt Hendrik G. Visser Marietjie Schutte |
| author_facet | Andreas Roodt Hendrik G. Visser Marietjie Schutte |
| author_sort | Andreas Roodt |
| collection | DOAJ |
| description | The title complex, [Re(C7H2Br3O2)(CO)3(H2O)]·CH3OH, crystallized as a neutral ReI compound and one methanol solvent molecule in the asymmetric unit. The metal centre is coordinated facially by three carbonyl groups. The bidentate tribromotropolanate ligand and a water molecule complete the distorted octahedral coordination around the central metal. Intermolecular Br...O [3.226 (5) Å] and Br...Br [3.590 (2) Å] contacts are observed between adjacent molecules. These contacts, together with an array of O—H...O, O—H...Br and C—H...O hydrogen bonds, complete a three-dimensional polymeric network formed between the methanol solvent and the complex. |
| first_indexed | 2024-12-10T17:29:59Z |
| format | Article |
| id | doaj.art-aafe87f5d31d47b6849ff150d6cc6875 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T17:29:59Z |
| publishDate | 2008-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-aafe87f5d31d47b6849ff150d6cc68752022-12-22T01:39:43ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-12-016412m1610m161110.1107/S1600536808038737Aquatricarbonyl(3,5,7-tribromotropolonato)rhenium(I) methanol solvateAndreas RoodtHendrik G. VisserMarietjie SchutteThe title complex, [Re(C7H2Br3O2)(CO)3(H2O)]·CH3OH, crystallized as a neutral ReI compound and one methanol solvent molecule in the asymmetric unit. The metal centre is coordinated facially by three carbonyl groups. The bidentate tribromotropolanate ligand and a water molecule complete the distorted octahedral coordination around the central metal. Intermolecular Br...O [3.226 (5) Å] and Br...Br [3.590 (2) Å] contacts are observed between adjacent molecules. These contacts, together with an array of O—H...O, O—H...Br and C—H...O hydrogen bonds, complete a three-dimensional polymeric network formed between the methanol solvent and the complex.http://scripts.iucr.org/cgi-bin/paper?S1600536808038737 |
| spellingShingle | Andreas Roodt Hendrik G. Visser Marietjie Schutte Aquatricarbonyl(3,5,7-tribromotropolonato)rhenium(I) methanol solvate Acta Crystallographica Section E |
| title | Aquatricarbonyl(3,5,7-tribromotropolonato)rhenium(I) methanol solvate |
| title_full | Aquatricarbonyl(3,5,7-tribromotropolonato)rhenium(I) methanol solvate |
| title_fullStr | Aquatricarbonyl(3,5,7-tribromotropolonato)rhenium(I) methanol solvate |
| title_full_unstemmed | Aquatricarbonyl(3,5,7-tribromotropolonato)rhenium(I) methanol solvate |
| title_short | Aquatricarbonyl(3,5,7-tribromotropolonato)rhenium(I) methanol solvate |
| title_sort | aquatricarbonyl 3 5 7 tribromotropolonato rhenium i methanol solvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808038737 |
| work_keys_str_mv | AT andreasroodt aquatricarbonyl357tribromotropolonatorheniumimethanolsolvate AT hendrikgvisser aquatricarbonyl357tribromotropolonatorheniumimethanolsolvate AT marietjieschutte aquatricarbonyl357tribromotropolonatorheniumimethanolsolvate |