Extraction of Iron and Other Metals from Copper Tailings through Leaching

Currently, mining operations have increased the generation of tailings, which contain a variety of elements that can be valorized. In this research, tailing samples were leached with hydrochloric acid of concentrations greater than 3 M, considering the monitoring of iron, copper, aluminum, calcium a...

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Main Authors: Lidia E. Santibáñez-Velásquez, Alexis Guzmán, Mauricio J. Morel
Format: Article
Language:English
Published: MDPI AG 2022-11-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/12/11/1924
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author Lidia E. Santibáñez-Velásquez
Alexis Guzmán
Mauricio J. Morel
author_facet Lidia E. Santibáñez-Velásquez
Alexis Guzmán
Mauricio J. Morel
author_sort Lidia E. Santibáñez-Velásquez
collection DOAJ
description Currently, mining operations have increased the generation of tailings, which contain a variety of elements that can be valorized. In this research, tailing samples were leached with hydrochloric acid of concentrations greater than 3 M, considering the monitoring of iron, copper, aluminum, calcium and magnesium, as relevant elements of the leached solution. Time and temperature were also studied. The original tailing sample was taken by trial pits, and a size distribution analysis was performed. The process generated an insoluble solid, rich in aluminosilicates, and an acid liquid solution with different metal ions. Elemental analyses were performed on liquid samples by Atomic Absorption Spectroscopy (AAS), and solid samples by Scanning Electron Microscopy-Energy Dispersive Spectroscopy (SEM-EDX) and X-ray Diffraction (XRD). Results showed an increasing trend of the iron concentration as a function of the acid concentration. However, copper is not affected by the change in acid concentration, but by time and temperature. Aluminum decreases with acid concentration, keeps constant with time, and yields at 50 °C. In the range of the studied parameters, calcium and magnesium showed a variation without a clear trend. The elements in the acid solution prepared with a tailing from northern Chile can be recovered for subsequent applications.
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spelling doaj.art-ab01cfc6393b46789ec51943fdf4227f2023-11-24T05:53:19ZengMDPI AGMetals2075-47012022-11-011211192410.3390/met12111924Extraction of Iron and Other Metals from Copper Tailings through LeachingLidia E. Santibáñez-Velásquez0Alexis Guzmán1Mauricio J. Morel2Departamento de Ingeniería en Metalurgia, Facultad de Ingeniería, Universidad de Atacama, Copiapó 1531772, ChileDepartamento de Ingeniería en Metalurgia, Facultad de Ingeniería, Universidad de Atacama, Copiapó 1531772, ChileDepartamento de Química y Biología, Facultad de Ciencias Naturales, Universidad de Atacama, Copiapó 1531772, ChileCurrently, mining operations have increased the generation of tailings, which contain a variety of elements that can be valorized. In this research, tailing samples were leached with hydrochloric acid of concentrations greater than 3 M, considering the monitoring of iron, copper, aluminum, calcium and magnesium, as relevant elements of the leached solution. Time and temperature were also studied. The original tailing sample was taken by trial pits, and a size distribution analysis was performed. The process generated an insoluble solid, rich in aluminosilicates, and an acid liquid solution with different metal ions. Elemental analyses were performed on liquid samples by Atomic Absorption Spectroscopy (AAS), and solid samples by Scanning Electron Microscopy-Energy Dispersive Spectroscopy (SEM-EDX) and X-ray Diffraction (XRD). Results showed an increasing trend of the iron concentration as a function of the acid concentration. However, copper is not affected by the change in acid concentration, but by time and temperature. Aluminum decreases with acid concentration, keeps constant with time, and yields at 50 °C. In the range of the studied parameters, calcium and magnesium showed a variation without a clear trend. The elements in the acid solution prepared with a tailing from northern Chile can be recovered for subsequent applications.https://www.mdpi.com/2075-4701/12/11/1924copper tailingleachingvalorization
spellingShingle Lidia E. Santibáñez-Velásquez
Alexis Guzmán
Mauricio J. Morel
Extraction of Iron and Other Metals from Copper Tailings through Leaching
Metals
copper tailing
leaching
valorization
title Extraction of Iron and Other Metals from Copper Tailings through Leaching
title_full Extraction of Iron and Other Metals from Copper Tailings through Leaching
title_fullStr Extraction of Iron and Other Metals from Copper Tailings through Leaching
title_full_unstemmed Extraction of Iron and Other Metals from Copper Tailings through Leaching
title_short Extraction of Iron and Other Metals from Copper Tailings through Leaching
title_sort extraction of iron and other metals from copper tailings through leaching
topic copper tailing
leaching
valorization
url https://www.mdpi.com/2075-4701/12/11/1924
work_keys_str_mv AT lidiaesantibanezvelasquez extractionofironandothermetalsfromcoppertailingsthroughleaching
AT alexisguzman extractionofironandothermetalsfromcoppertailingsthroughleaching
AT mauriciojmorel extractionofironandothermetalsfromcoppertailingsthroughleaching