Syntheses of Bi2X3 (X = S, Se, Te) from elements under hydrothermal conditions

Bismuth chalcogenides (Bi2X3, X = S, Se, Te) were synthesized from the elements under hydrothermal condition. Single phases of Bi2S3 and Bi2Se3 were produced at 240 °C. Bi2Te3 was obtained as an almost single phase with a small amount of Bi2TeO5. From the results of control experiments without water...

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Main Authors: Keitaro Tezuka, Saori Kase, Yue Jin Shan
Format: Article
Language:English
Published: Taylor & Francis Group 2014-12-01
Series:Journal of Asian Ceramic Societies
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2187076414000852
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author Keitaro Tezuka
Saori Kase
Yue Jin Shan
author_facet Keitaro Tezuka
Saori Kase
Yue Jin Shan
author_sort Keitaro Tezuka
collection DOAJ
description Bismuth chalcogenides (Bi2X3, X = S, Se, Te) were synthesized from the elements under hydrothermal condition. Single phases of Bi2S3 and Bi2Se3 were produced at 240 °C. Bi2Te3 was obtained as an almost single phase with a small amount of Bi2TeO5. From the results of control experiments without water, the hydrothermal condition in the production of Bi2S3 was more effective than that of Bi2Se3. The particles of obtained Bi2S3 were spherical, with a diameter of ∼1 μm. The Bi2Se3 particles were in a plate-like form, with a width of ∼1 μm and a thickness of ∼0.2 μm.
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spelling doaj.art-ab2eea7d2c52466a84e8fe591cc5a03a2022-12-21T19:42:51ZengTaylor & Francis GroupJournal of Asian Ceramic Societies2187-07642014-12-012436637010.1016/j.jascer.2014.07.009Syntheses of Bi2X3 (X = S, Se, Te) from elements under hydrothermal conditionsKeitaro TezukaSaori KaseYue Jin ShanBismuth chalcogenides (Bi2X3, X = S, Se, Te) were synthesized from the elements under hydrothermal condition. Single phases of Bi2S3 and Bi2Se3 were produced at 240 °C. Bi2Te3 was obtained as an almost single phase with a small amount of Bi2TeO5. From the results of control experiments without water, the hydrothermal condition in the production of Bi2S3 was more effective than that of Bi2Se3. The particles of obtained Bi2S3 were spherical, with a diameter of ∼1 μm. The Bi2Se3 particles were in a plate-like form, with a width of ∼1 μm and a thickness of ∼0.2 μm.http://www.sciencedirect.com/science/article/pii/S2187076414000852Hydrothermal reactionBismuthChalcogenideX-ray methods
spellingShingle Keitaro Tezuka
Saori Kase
Yue Jin Shan
Syntheses of Bi2X3 (X = S, Se, Te) from elements under hydrothermal conditions
Journal of Asian Ceramic Societies
Hydrothermal reaction
Bismuth
Chalcogenide
X-ray methods
title Syntheses of Bi2X3 (X = S, Se, Te) from elements under hydrothermal conditions
title_full Syntheses of Bi2X3 (X = S, Se, Te) from elements under hydrothermal conditions
title_fullStr Syntheses of Bi2X3 (X = S, Se, Te) from elements under hydrothermal conditions
title_full_unstemmed Syntheses of Bi2X3 (X = S, Se, Te) from elements under hydrothermal conditions
title_short Syntheses of Bi2X3 (X = S, Se, Te) from elements under hydrothermal conditions
title_sort syntheses of bi2x3 x s se te from elements under hydrothermal conditions
topic Hydrothermal reaction
Bismuth
Chalcogenide
X-ray methods
url http://www.sciencedirect.com/science/article/pii/S2187076414000852
work_keys_str_mv AT keitarotezuka synthesesofbi2x3xssetefromelementsunderhydrothermalconditions
AT saorikase synthesesofbi2x3xssetefromelementsunderhydrothermalconditions
AT yuejinshan synthesesofbi2x3xssetefromelementsunderhydrothermalconditions