Synthesis, Spectroscopic Studies of Some Transition Metal Complexes of Schiff Bases Derived from Diamine Compounds
The present work include preparation of three ligands (Schiff base) by condensation of (Phthaldialdehyde) with 1,3-diamino-2-propanol) to give ligands (L) L: (1Z,6Z)-4,5-dihydro -3H-2,6-benzodiazonin-4-ol o characterize the structure of prepared ligands and their complexes, elemental analysis (C.H...
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| Format: | Article |
| Language: | English |
| Published: |
University of Thi-Qar
2019-05-01
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| Series: | مجلة علوم ذي قار |
| Subjects: | |
| Online Access: | http://jsci.utq.edu.iq/index.php/main/article/view/119 |
| Summary: | The present work include preparation of three ligands (Schiff base) by condensation of (Phthaldialdehyde) with
1,3-diamino-2-propanol) to give ligands (L)
L: (1Z,6Z)-4,5-dihydro -3H-2,6-benzodiazonin-4-ol
o characterize the structure of prepared ligands and their complexes, elemental analysis (C.H.N),Infrared
Spectroscopy (IR), Nuclear Magnetic Resonance Spectroscopy(
1
H-NMR),Mass Spectra and Molar conductivity
echniques were applied . The results showed that:
- The complexes of [Co(III) and Cr(III)] for ligand have shown octahedral configuration.
- Complexes of [ Ni(II)] with ligands have shown tetrahedral configuration.
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| ISSN: | 1991-8690 2709-0256 |