Biological investigation of sonochemically synthesized CZTS nanoparticles

Cu2ZnSnS4 (CZTS) nanoparticles (NPs) are synthesized by sonochemical technique. The composition analysis showed the synthesized NPs to be stoichiometric. The X-ray diffraction confirms the CZTS phase and tetragonal unit cell structure. Three peaks corresponding to CZTS have been observed in Raman sp...

Full description

Bibliographic Details
Main Authors: Anilkumar B. Hirpara, Sunil H. Chaki, Rohitkumar M. Kannaujiya, Ankurkumar J. Khimani, Zubin R. Parekh, Yati H. Vaidya, Ranjan Kr. Giri, M.P. Deshpande
Format: Article
Language:English
Published: Elsevier 2022-12-01
Series:Applied Surface Science Advances
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2666523922001283
_version_ 1811298028479315968
author Anilkumar B. Hirpara
Sunil H. Chaki
Rohitkumar M. Kannaujiya
Ankurkumar J. Khimani
Zubin R. Parekh
Yati H. Vaidya
Ranjan Kr. Giri
M.P. Deshpande
author_facet Anilkumar B. Hirpara
Sunil H. Chaki
Rohitkumar M. Kannaujiya
Ankurkumar J. Khimani
Zubin R. Parekh
Yati H. Vaidya
Ranjan Kr. Giri
M.P. Deshpande
author_sort Anilkumar B. Hirpara
collection DOAJ
description Cu2ZnSnS4 (CZTS) nanoparticles (NPs) are synthesized by sonochemical technique. The composition analysis showed the synthesized NPs to be stoichiometric. The X-ray diffraction confirms the CZTS phase and tetragonal unit cell structure. Three peaks corresponding to CZTS have been observed in Raman spectroscopy positioned at 293.47 cm−1, 373.8 cm−1, and 336.67 cm−1. The electron diffraction in the selected area showed faded rings with spot patterns indicating crystalline nature. The CZTS NPs have a direct optical bandgap of 1.62 eV, being ascertained by optical absorbance spectroscopy. The CZTS NPs antibacterial activity is determined against pathogenic gram-negative (E. coli, P. aeruginosa, P. vulgaris, and E. aerogenes) and gram-positive (S. aureus) bacteria by measuring the inhibition zone. The 2, 2-diphenyl-1-picrylhydrazyl assay is employed in deciding the antioxidant efficacy of CZTS NPs. The cytotoxicity of CZTS NPs is evaluated in Brine shrimp (Artemia salina) eggs hatched in synthetic seawater made from 38 g/l commercial sea salt. The findings are discussed in detail.
first_indexed 2024-04-13T06:13:39Z
format Article
id doaj.art-ab615592b58744579708546e441deeaa
institution Directory Open Access Journal
issn 2666-5239
language English
last_indexed 2024-04-13T06:13:39Z
publishDate 2022-12-01
publisher Elsevier
record_format Article
series Applied Surface Science Advances
spelling doaj.art-ab615592b58744579708546e441deeaa2022-12-22T02:58:56ZengElsevierApplied Surface Science Advances2666-52392022-12-0112100338Biological investigation of sonochemically synthesized CZTS nanoparticlesAnilkumar B. Hirpara0Sunil H. Chaki1Rohitkumar M. Kannaujiya2Ankurkumar J. Khimani3Zubin R. Parekh4Yati H. Vaidya5Ranjan Kr. Giri6M.P. Deshpande7P. G. Department of Physics, Sardar Patel University, Vallabh Vidyanagar-388120, Gujarat, India; Corresponding author.P. G. Department of Physics, Sardar Patel University, Vallabh Vidyanagar-388120, Gujarat, India; P. G. Department of Applied & Interdisciplinary Sciences, CISST, Sardar Patel University, Vallabh Vidyanagar 388 120, Gujarat, India; Corresponding author.P. G. Department of Physics, Sardar Patel University, Vallabh Vidyanagar-388120, Gujarat, IndiaP. G. Department of Physics, Sardar Patel University, Vallabh Vidyanagar-388120, Gujarat, IndiaP. G. Department of Physics, Sardar Patel University, Vallabh Vidyanagar-388120, Gujarat, IndiaDepartment of Microbiology, Shri Alpesh N. Patel PG Institute of Science and Research, Anand, Gujarat 388120, IndiaP. G. Department of Physics, Sardar Patel University, Vallabh Vidyanagar-388120, Gujarat, IndiaP. G. Department of Physics, Sardar Patel University, Vallabh Vidyanagar-388120, Gujarat, IndiaCu2ZnSnS4 (CZTS) nanoparticles (NPs) are synthesized by sonochemical technique. The composition analysis showed the synthesized NPs to be stoichiometric. The X-ray diffraction confirms the CZTS phase and tetragonal unit cell structure. Three peaks corresponding to CZTS have been observed in Raman spectroscopy positioned at 293.47 cm−1, 373.8 cm−1, and 336.67 cm−1. The electron diffraction in the selected area showed faded rings with spot patterns indicating crystalline nature. The CZTS NPs have a direct optical bandgap of 1.62 eV, being ascertained by optical absorbance spectroscopy. The CZTS NPs antibacterial activity is determined against pathogenic gram-negative (E. coli, P. aeruginosa, P. vulgaris, and E. aerogenes) and gram-positive (S. aureus) bacteria by measuring the inhibition zone. The 2, 2-diphenyl-1-picrylhydrazyl assay is employed in deciding the antioxidant efficacy of CZTS NPs. The cytotoxicity of CZTS NPs is evaluated in Brine shrimp (Artemia salina) eggs hatched in synthetic seawater made from 38 g/l commercial sea salt. The findings are discussed in detail.http://www.sciencedirect.com/science/article/pii/S2666523922001283Cu2ZnSnS4NanoparticlesCytotoxicityAntibacterialAnti-oxidant
spellingShingle Anilkumar B. Hirpara
Sunil H. Chaki
Rohitkumar M. Kannaujiya
Ankurkumar J. Khimani
Zubin R. Parekh
Yati H. Vaidya
Ranjan Kr. Giri
M.P. Deshpande
Biological investigation of sonochemically synthesized CZTS nanoparticles
Applied Surface Science Advances
Cu2ZnSnS4
Nanoparticles
Cytotoxicity
Antibacterial
Anti-oxidant
title Biological investigation of sonochemically synthesized CZTS nanoparticles
title_full Biological investigation of sonochemically synthesized CZTS nanoparticles
title_fullStr Biological investigation of sonochemically synthesized CZTS nanoparticles
title_full_unstemmed Biological investigation of sonochemically synthesized CZTS nanoparticles
title_short Biological investigation of sonochemically synthesized CZTS nanoparticles
title_sort biological investigation of sonochemically synthesized czts nanoparticles
topic Cu2ZnSnS4
Nanoparticles
Cytotoxicity
Antibacterial
Anti-oxidant
url http://www.sciencedirect.com/science/article/pii/S2666523922001283
work_keys_str_mv AT anilkumarbhirpara biologicalinvestigationofsonochemicallysynthesizedcztsnanoparticles
AT sunilhchaki biologicalinvestigationofsonochemicallysynthesizedcztsnanoparticles
AT rohitkumarmkannaujiya biologicalinvestigationofsonochemicallysynthesizedcztsnanoparticles
AT ankurkumarjkhimani biologicalinvestigationofsonochemicallysynthesizedcztsnanoparticles
AT zubinrparekh biologicalinvestigationofsonochemicallysynthesizedcztsnanoparticles
AT yatihvaidya biologicalinvestigationofsonochemicallysynthesizedcztsnanoparticles
AT ranjankrgiri biologicalinvestigationofsonochemicallysynthesizedcztsnanoparticles
AT mpdeshpande biologicalinvestigationofsonochemicallysynthesizedcztsnanoparticles