Cellulose acetate butyrate graphene oxide nanocomposite membrane: Fabrication, characterization, and performance
In this study, the effects of graphene oxide (GO) nanosheets on the physicochemical properties and performances of cellulose acetate butyrate (CAB) membranes were investigated. Nanocomposite membranes were fabricated using CAB and a small amount of GO in the range of 0 to 0.07 wt.%, using a conventi...
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Format: | Article |
Language: | English |
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Association of the Chemical Engineers of Serbia
2021-01-01
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Series: | Chemical Industry and Chemical Engineering Quarterly |
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Online Access: | http://www.doiserbia.nb.rs/img/doi/1451-9372/2021/1451-93722000022A.pdf |
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author | Alghamdi Majed M. El-Zahhar Adel A. |
author_facet | Alghamdi Majed M. El-Zahhar Adel A. |
author_sort | Alghamdi Majed M. |
collection | DOAJ |
description | In this study, the effects of graphene oxide (GO) nanosheets on the physicochemical properties and performances of cellulose acetate butyrate (CAB) membranes were investigated. Nanocomposite membranes were fabricated using CAB and a small amount of GO in the range of 0 to 0.07 wt.%, using a conventional phase-inversion method. Membranes were characterized by different methods and their performances were tested using a dead-end filtration system. Compared with pristine CAB membrane, experimental results demonstrated an improvement in features such as hydrophilicity, permeability, salt rejection, antifouling, and stability. The results proved an increase in the porosity and pore sizes of membranes with GO addition. Furthermore, the membrane containing 0.07 wt.% of GO exhibited a low contact angle of 37°and a dramatic improvement in water flux of about 450% (from 2 to 11 L/(m2 h)). Moreover, it demonstrated a salt rejection of 39% for NaCl and 87% for Na2SO4, corresponding to improvements of about 144 and 93%, respectively. Furthermore, the results revealed a higher antifouling property with an 86% improvement in flux recovery and higher stability in terms of performance and thermal properties compared to CAB. |
first_indexed | 2024-12-14T10:29:14Z |
format | Article |
id | doaj.art-ab6ebc226f494a05b60973c125f0560f |
institution | Directory Open Access Journal |
issn | 1451-9372 2217-7434 |
language | English |
last_indexed | 2024-12-14T10:29:14Z |
publishDate | 2021-01-01 |
publisher | Association of the Chemical Engineers of Serbia |
record_format | Article |
series | Chemical Industry and Chemical Engineering Quarterly |
spelling | doaj.art-ab6ebc226f494a05b60973c125f0560f2022-12-21T23:06:12ZengAssociation of the Chemical Engineers of SerbiaChemical Industry and Chemical Engineering Quarterly1451-93722217-74342021-01-01271354410.2298/CICEQ200128022A1451-93722000022ACellulose acetate butyrate graphene oxide nanocomposite membrane: Fabrication, characterization, and performanceAlghamdi Majed M.0El-Zahhar Adel A.1Environmental Monitoring, Assessment & Treatment (EMAT) Research Group, Department of Chemistry, College of Science, King Khalid University, Abha, Saudi ArabiaEnvironmental Monitoring, Assessment & Treatment (EMAT) Research Group, Department of Chemistry, College of Science, King Khalid University, Abha, Saudi Arabia + Nuclear Chem. Dept. AEA, Cairo, EgyptIn this study, the effects of graphene oxide (GO) nanosheets on the physicochemical properties and performances of cellulose acetate butyrate (CAB) membranes were investigated. Nanocomposite membranes were fabricated using CAB and a small amount of GO in the range of 0 to 0.07 wt.%, using a conventional phase-inversion method. Membranes were characterized by different methods and their performances were tested using a dead-end filtration system. Compared with pristine CAB membrane, experimental results demonstrated an improvement in features such as hydrophilicity, permeability, salt rejection, antifouling, and stability. The results proved an increase in the porosity and pore sizes of membranes with GO addition. Furthermore, the membrane containing 0.07 wt.% of GO exhibited a low contact angle of 37°and a dramatic improvement in water flux of about 450% (from 2 to 11 L/(m2 h)). Moreover, it demonstrated a salt rejection of 39% for NaCl and 87% for Na2SO4, corresponding to improvements of about 144 and 93%, respectively. Furthermore, the results revealed a higher antifouling property with an 86% improvement in flux recovery and higher stability in terms of performance and thermal properties compared to CAB.http://www.doiserbia.nb.rs/img/doi/1451-9372/2021/1451-93722000022A.pdfcellulose acetate butyrategraphene oxidenanocompositemembranesalt rejection |
spellingShingle | Alghamdi Majed M. El-Zahhar Adel A. Cellulose acetate butyrate graphene oxide nanocomposite membrane: Fabrication, characterization, and performance Chemical Industry and Chemical Engineering Quarterly cellulose acetate butyrate graphene oxide nanocomposite membrane salt rejection |
title | Cellulose acetate butyrate graphene oxide nanocomposite membrane: Fabrication, characterization, and performance |
title_full | Cellulose acetate butyrate graphene oxide nanocomposite membrane: Fabrication, characterization, and performance |
title_fullStr | Cellulose acetate butyrate graphene oxide nanocomposite membrane: Fabrication, characterization, and performance |
title_full_unstemmed | Cellulose acetate butyrate graphene oxide nanocomposite membrane: Fabrication, characterization, and performance |
title_short | Cellulose acetate butyrate graphene oxide nanocomposite membrane: Fabrication, characterization, and performance |
title_sort | cellulose acetate butyrate graphene oxide nanocomposite membrane fabrication characterization and performance |
topic | cellulose acetate butyrate graphene oxide nanocomposite membrane salt rejection |
url | http://www.doiserbia.nb.rs/img/doi/1451-9372/2021/1451-93722000022A.pdf |
work_keys_str_mv | AT alghamdimajedm celluloseacetatebutyrategrapheneoxidenanocompositemembranefabricationcharacterizationandperformance AT elzahharadela celluloseacetatebutyrategrapheneoxidenanocompositemembranefabricationcharacterizationandperformance |