Synthesis of chiral mono(N-heterocyclic carbene) palladium and gold complexes with a 1,1'-biphenyl scaffold and their applications in catalysis

Synthesis of chiral mono(N-heterocyclic carbene) palladium and gold complexes with a 1,1'-biphenyl scaffold and their applications in catalysis

Axially chiral mono(NHC)–Pd(II) and mono(NHC)–Au(I) complexes with one side shaped 1,1'-biphenyl backbone have been prepared from chiral 6,6'-dimethoxybiphenyl-2,2'-diamine. The complexes were characterized by X-ray crystal structure diffraction. The Pd(II) complex showed good catalyt...

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Bibliographic Details
Main Authors: Lian-jun Liu, Feijun Wang, Wenfeng Wang, Mei-xin Zhao, Min Shi
Format: Article
Language:English
Published: Beilstein-Institut 2011-05-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
chiral mono(N-heterocyclic carbene) complex
Heck–Mizoroki reaction
hydroamination
Suzuki–Miyaura reaction
Online Access:https://doi.org/10.3762/bjoc.7.64

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