Triprolidinium dichloranilate–chloranilic acid–methanol–water (2/1/2/2)
In the triprolidinium cation of the title compound {systematic name: 2-[1-(4-methylphenyl)-3-(pyrrolidin-1-ium-1-yl)prop-1-en-1-yl]pyridin-1-ium bis(2,5-dichloro-4-hydroxy-3,6-dioxocyclohexa-1,4-dien-1-olate)–2,5-dichloro-3,6-dihydroxycyclohexa-2,5-diene-1,4-dione–methano...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812010136 |
| _version_ | 1798030949380784128 |
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| author | A. S. Dayananda Ray J. Butcher Mehmet Akkurt H. S. Yathirajan B. Narayana |
| author_facet | A. S. Dayananda Ray J. Butcher Mehmet Akkurt H. S. Yathirajan B. Narayana |
| author_sort | A. S. Dayananda |
| collection | DOAJ |
| description | In the triprolidinium cation of the title compound {systematic name: 2-[1-(4-methylphenyl)-3-(pyrrolidin-1-ium-1-yl)prop-1-en-1-yl]pyridin-1-ium bis(2,5-dichloro-4-hydroxy-3,6-dioxocyclohexa-1,4-dien-1-olate)–2,5-dichloro-3,6-dihydroxycyclohexa-2,5-diene-1,4-dione–methanol–water (2/1/2/2)}, C19H24N22+·2C6HCl2O4−·0.5C6H2Cl2O4·CH3OH·H2O, the N atoms on both the pyrrolidine and pyridine groups are protonated. The neutral chloranilic acid molecule is on an inversion symmetry element and its hydroxy H atoms are disordered over two positions with site-occupancy factors of 0.53 (6) and 0.47 (6). The methanol solvent molecule is disordered over two positions in a 0.836 (4):0.164 (4) ratio. In the crystal, N—H...O, O—H...O and C—H...O interactions link the components. The crystal structure also features π–π interactions between the benzene rings [centroid–centroid distances = 3.5674 (15), 3.5225 (15) and 3.6347 (15) Å]. |
| first_indexed | 2024-04-11T19:48:20Z |
| format | Article |
| id | doaj.art-abc6293027a14b078a0c9504c1bf6206 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T19:48:20Z |
| publishDate | 2012-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-abc6293027a14b078a0c9504c1bf62062022-12-22T04:06:22ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-04-01684o1037o103810.1107/S1600536812010136Triprolidinium dichloranilate–chloranilic acid–methanol–water (2/1/2/2)A. S. DayanandaRay J. ButcherMehmet AkkurtH. S. YathirajanB. NarayanaIn the triprolidinium cation of the title compound {systematic name: 2-[1-(4-methylphenyl)-3-(pyrrolidin-1-ium-1-yl)prop-1-en-1-yl]pyridin-1-ium bis(2,5-dichloro-4-hydroxy-3,6-dioxocyclohexa-1,4-dien-1-olate)–2,5-dichloro-3,6-dihydroxycyclohexa-2,5-diene-1,4-dione–methanol–water (2/1/2/2)}, C19H24N22+·2C6HCl2O4−·0.5C6H2Cl2O4·CH3OH·H2O, the N atoms on both the pyrrolidine and pyridine groups are protonated. The neutral chloranilic acid molecule is on an inversion symmetry element and its hydroxy H atoms are disordered over two positions with site-occupancy factors of 0.53 (6) and 0.47 (6). The methanol solvent molecule is disordered over two positions in a 0.836 (4):0.164 (4) ratio. In the crystal, N—H...O, O—H...O and C—H...O interactions link the components. The crystal structure also features π–π interactions between the benzene rings [centroid–centroid distances = 3.5674 (15), 3.5225 (15) and 3.6347 (15) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536812010136 |
| spellingShingle | A. S. Dayananda Ray J. Butcher Mehmet Akkurt H. S. Yathirajan B. Narayana Triprolidinium dichloranilate–chloranilic acid–methanol–water (2/1/2/2) Acta Crystallographica Section E |
| title | Triprolidinium dichloranilate–chloranilic acid–methanol–water (2/1/2/2) |
| title_full | Triprolidinium dichloranilate–chloranilic acid–methanol–water (2/1/2/2) |
| title_fullStr | Triprolidinium dichloranilate–chloranilic acid–methanol–water (2/1/2/2) |
| title_full_unstemmed | Triprolidinium dichloranilate–chloranilic acid–methanol–water (2/1/2/2) |
| title_short | Triprolidinium dichloranilate–chloranilic acid–methanol–water (2/1/2/2) |
| title_sort | triprolidinium dichloranilate amp 8211 chloranilic acid amp 8211 methanol amp 8211 water 2 1 2 2 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812010136 |
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