Study on the Fluorescent Activity of N2-Indolyl-1,2,3-triazole

A new type of blue emitter, N2-Indolyl-1,2,3-triazoles (NITs), with the λmax ranging from 420–480 nm and the Stokes shift from 89–143 nm, were synthesized through the coupling reaction of indoles with triazole derivatives. The influence of different substitution patterns on the optical properties (e...

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Main Authors: You-Can Zhang, Rui Jin, Luo-Yuan Li, Zili Chen, Li-Min Fu
Format: Article
Language:English
Published: MDPI AG 2017-09-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/22/9/1380
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author You-Can Zhang
Rui Jin
Luo-Yuan Li
Zili Chen
Li-Min Fu
author_facet You-Can Zhang
Rui Jin
Luo-Yuan Li
Zili Chen
Li-Min Fu
author_sort You-Can Zhang
collection DOAJ
description A new type of blue emitter, N2-Indolyl-1,2,3-triazoles (NITs), with the λmax ranging from 420–480 nm and the Stokes shift from 89–143 nm, were synthesized through the coupling reaction of indoles with triazole derivatives. The influence of different substitution patterns on the optical properties (efficiency, excitation, and emission wavelengths) of the NITs was investigated. In addition, one palladium complex were synthesized by using NITs as the ligands, which, however, exhibited no fluorescent activity, but did show the enhanced co-planarity. Lastly, two bio-active molecule derivatives were explored for the potential use of these novel dyes in related chemical and biological applications.
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spelling doaj.art-abe94d3391084685b35cfdd9cd1707792022-12-22T02:42:58ZengMDPI AGMolecules1420-30492017-09-01229138010.3390/molecules22091380molecules22091380Study on the Fluorescent Activity of N2-Indolyl-1,2,3-triazoleYou-Can Zhang0Rui Jin1Luo-Yuan Li2Zili Chen3Li-Min Fu4Department of Chemistry, Renmin University of China, Beijing 100872, ChinaDepartment of Chemistry, Renmin University of China, Beijing 100872, ChinaDepartment of Chemistry, Renmin University of China, Beijing 100872, ChinaDepartment of Chemistry, Renmin University of China, Beijing 100872, ChinaDepartment of Chemistry, Renmin University of China, Beijing 100872, ChinaA new type of blue emitter, N2-Indolyl-1,2,3-triazoles (NITs), with the λmax ranging from 420–480 nm and the Stokes shift from 89–143 nm, were synthesized through the coupling reaction of indoles with triazole derivatives. The influence of different substitution patterns on the optical properties (efficiency, excitation, and emission wavelengths) of the NITs was investigated. In addition, one palladium complex were synthesized by using NITs as the ligands, which, however, exhibited no fluorescent activity, but did show the enhanced co-planarity. Lastly, two bio-active molecule derivatives were explored for the potential use of these novel dyes in related chemical and biological applications.https://www.mdpi.com/1420-3049/22/9/1380N2-indolyl-1,2,3-triazoles (NITs)fluorescent activityblue-emissive fluorophoreN2-aryl-1,2,3-triazoles (NATs)
spellingShingle You-Can Zhang
Rui Jin
Luo-Yuan Li
Zili Chen
Li-Min Fu
Study on the Fluorescent Activity of N2-Indolyl-1,2,3-triazole
Molecules
N2-indolyl-1,2,3-triazoles (NITs)
fluorescent activity
blue-emissive fluorophore
N2-aryl-1,2,3-triazoles (NATs)
title Study on the Fluorescent Activity of N2-Indolyl-1,2,3-triazole
title_full Study on the Fluorescent Activity of N2-Indolyl-1,2,3-triazole
title_fullStr Study on the Fluorescent Activity of N2-Indolyl-1,2,3-triazole
title_full_unstemmed Study on the Fluorescent Activity of N2-Indolyl-1,2,3-triazole
title_short Study on the Fluorescent Activity of N2-Indolyl-1,2,3-triazole
title_sort study on the fluorescent activity of n2 indolyl 1 2 3 triazole
topic N2-indolyl-1,2,3-triazoles (NITs)
fluorescent activity
blue-emissive fluorophore
N2-aryl-1,2,3-triazoles (NATs)
url https://www.mdpi.com/1420-3049/22/9/1380
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