Study on the Fluorescent Activity of N2-Indolyl-1,2,3-triazole
A new type of blue emitter, N2-Indolyl-1,2,3-triazoles (NITs), with the λmax ranging from 420–480 nm and the Stokes shift from 89–143 nm, were synthesized through the coupling reaction of indoles with triazole derivatives. The influence of different substitution patterns on the optical properties (e...
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MDPI AG
2017-09-01
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Online Access: | https://www.mdpi.com/1420-3049/22/9/1380 |
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author | You-Can Zhang Rui Jin Luo-Yuan Li Zili Chen Li-Min Fu |
author_facet | You-Can Zhang Rui Jin Luo-Yuan Li Zili Chen Li-Min Fu |
author_sort | You-Can Zhang |
collection | DOAJ |
description | A new type of blue emitter, N2-Indolyl-1,2,3-triazoles (NITs), with the λmax ranging from 420–480 nm and the Stokes shift from 89–143 nm, were synthesized through the coupling reaction of indoles with triazole derivatives. The influence of different substitution patterns on the optical properties (efficiency, excitation, and emission wavelengths) of the NITs was investigated. In addition, one palladium complex were synthesized by using NITs as the ligands, which, however, exhibited no fluorescent activity, but did show the enhanced co-planarity. Lastly, two bio-active molecule derivatives were explored for the potential use of these novel dyes in related chemical and biological applications. |
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format | Article |
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institution | Directory Open Access Journal |
issn | 1420-3049 |
language | English |
last_indexed | 2024-04-13T14:38:01Z |
publishDate | 2017-09-01 |
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series | Molecules |
spelling | doaj.art-abe94d3391084685b35cfdd9cd1707792022-12-22T02:42:58ZengMDPI AGMolecules1420-30492017-09-01229138010.3390/molecules22091380molecules22091380Study on the Fluorescent Activity of N2-Indolyl-1,2,3-triazoleYou-Can Zhang0Rui Jin1Luo-Yuan Li2Zili Chen3Li-Min Fu4Department of Chemistry, Renmin University of China, Beijing 100872, ChinaDepartment of Chemistry, Renmin University of China, Beijing 100872, ChinaDepartment of Chemistry, Renmin University of China, Beijing 100872, ChinaDepartment of Chemistry, Renmin University of China, Beijing 100872, ChinaDepartment of Chemistry, Renmin University of China, Beijing 100872, ChinaA new type of blue emitter, N2-Indolyl-1,2,3-triazoles (NITs), with the λmax ranging from 420–480 nm and the Stokes shift from 89–143 nm, were synthesized through the coupling reaction of indoles with triazole derivatives. The influence of different substitution patterns on the optical properties (efficiency, excitation, and emission wavelengths) of the NITs was investigated. In addition, one palladium complex were synthesized by using NITs as the ligands, which, however, exhibited no fluorescent activity, but did show the enhanced co-planarity. Lastly, two bio-active molecule derivatives were explored for the potential use of these novel dyes in related chemical and biological applications.https://www.mdpi.com/1420-3049/22/9/1380N2-indolyl-1,2,3-triazoles (NITs)fluorescent activityblue-emissive fluorophoreN2-aryl-1,2,3-triazoles (NATs) |
spellingShingle | You-Can Zhang Rui Jin Luo-Yuan Li Zili Chen Li-Min Fu Study on the Fluorescent Activity of N2-Indolyl-1,2,3-triazole Molecules N2-indolyl-1,2,3-triazoles (NITs) fluorescent activity blue-emissive fluorophore N2-aryl-1,2,3-triazoles (NATs) |
title | Study on the Fluorescent Activity of N2-Indolyl-1,2,3-triazole |
title_full | Study on the Fluorescent Activity of N2-Indolyl-1,2,3-triazole |
title_fullStr | Study on the Fluorescent Activity of N2-Indolyl-1,2,3-triazole |
title_full_unstemmed | Study on the Fluorescent Activity of N2-Indolyl-1,2,3-triazole |
title_short | Study on the Fluorescent Activity of N2-Indolyl-1,2,3-triazole |
title_sort | study on the fluorescent activity of n2 indolyl 1 2 3 triazole |
topic | N2-indolyl-1,2,3-triazoles (NITs) fluorescent activity blue-emissive fluorophore N2-aryl-1,2,3-triazoles (NATs) |
url | https://www.mdpi.com/1420-3049/22/9/1380 |
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