Selective Oxidation of Glycerol via Acceptorless Dehydrogenation Driven by Ir(I)-NHC Catalysts

Selective Oxidation of Glycerol via Acceptorless Dehydrogenation Driven by Ir(I)-NHC Catalysts

Iridium(I) compounds featuring bridge-functionalized bis-NHC ligands (NHC = N-heterocyclic carbene), [Ir(cod)(bis-NHC)] and [Ir(CO)<sub>2</sub>(bis-NHC)], have been prepared from the appropriate carboxylate- or hydroxy-functionalized bis-imidazolium salts. The related complexes [Ir(cod)(...

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Bibliographic Details
Main Authors: M. Victoria Jiménez, Ana I. Ojeda-Amador, Raquel Puerta-Oteo, Joaquín Martínez-Sal, Vincenzo Passarelli, Jesús J. Pérez-Torrente
Format: Article
Language:English
Published: MDPI AG 2022-11-01
Series:Molecules
Subjects:
glycerol
lactic acid
dehydrogenation
hydrogen release
N-heterocyclic carbenes
iridium
Online Access:https://www.mdpi.com/1420-3049/27/22/7666

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