EFFECT OF MOS2 DOPED CONDUCTING POLYMERS TO CORROSION OF MILD STEEL

One of the most common ways of protecting metals from corrosion is to form a film on metal surfaces or to coat them with suitable materials. Thus, metals are protected from corrosive components in their environment. However, in the case of openings at the micro level that may occur in the formation...

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Main Authors: Abdurrahman Asan, Gülden ASAN
Format: Article
Language:English
Published: Turkish Chemical Society 2019-11-01
Series:Journal of the Turkish Chemical Society Section B: Chemical Engineering
Subjects:
Online Access:https://dergipark.org.tr/en/pub/jotcsb/issue/45604/573053
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author Abdurrahman Asan
Gülden ASAN
author_facet Abdurrahman Asan
Gülden ASAN
author_sort Abdurrahman Asan
collection DOAJ
description One of the most common ways of protecting metals from corrosion is to form a film on metal surfaces or to coat them with suitable materials. Thus, metals are protected from corrosive components in their environment. However, in the case of openings at the micro level that may occur in the formation of the coating or in case of scratches and similar openings that may occur after the coating, water and air will reach the metal surface and initiate corrosion. In this study, the effect of polypyrrole (PPy), polyaniline (PANI) and MoS2 doped PPy and PANI coatings on the corrosion rate of steel was investigated. Corrosion resistance of these coatings was determined by measuring corrosion rates by Tafel Polarization method in 0.1 M NaCl medium. Because of the experiments, it was determined that these homogeneous and adhering coatings were effective against corrosion. The best protection against corrosion was found as 96.7%, 89.0%, 69.5% and 45.2% for PPy + MoS2, PPy, PANI + MoS2 and PANI coatings, respectively. MoS2 additive yielded positive results for both coatings. Better protection of PPy than PANI can be explained by the fact that the oxidation potential of pyrrole (0.6 V) is lower than the aniline oxidation potential.
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spelling doaj.art-ac101d4c8e034eee9c2bbe48ccde3a0a2023-08-08T16:36:42ZengTurkish Chemical SocietyJournal of the Turkish Chemical Society Section B: Chemical Engineering2564-69072019-11-0122133136 EFFECT OF MOS2 DOPED CONDUCTING POLYMERS TO CORROSION OF MILD STEEL Abdurrahman Asan0https://orcid.org/0000-0002-1010-3981Gülden ASAN 1https://orcid.org/0000-0002-6075-159X HITIT UNIVERSITY HITIT UNIVERSITY One of the most common ways of protecting metals from corrosion is to form a film on metal surfaces or to coat them with suitable materials. Thus, metals are protected from corrosive components in their environment. However, in the case of openings at the micro level that may occur in the formation of the coating or in case of scratches and similar openings that may occur after the coating, water and air will reach the metal surface and initiate corrosion. In this study, the effect of polypyrrole (PPy), polyaniline (PANI) and MoS2 doped PPy and PANI coatings on the corrosion rate of steel was investigated. Corrosion resistance of these coatings was determined by measuring corrosion rates by Tafel Polarization method in 0.1 M NaCl medium. Because of the experiments, it was determined that these homogeneous and adhering coatings were effective against corrosion. The best protection against corrosion was found as 96.7%, 89.0%, 69.5% and 45.2% for PPy + MoS2, PPy, PANI + MoS2 and PANI coatings, respectively. MoS2 additive yielded positive results for both coatings. Better protection of PPy than PANI can be explained by the fact that the oxidation potential of pyrrole (0.6 V) is lower than the aniline oxidation potential.https://dergipark.org.tr/en/pub/jotcsb/issue/45604/573053corrosionconducting polymersmos2. tafel polarizationmild steel
spellingShingle Abdurrahman Asan
Gülden ASAN
EFFECT OF MOS2 DOPED CONDUCTING POLYMERS TO CORROSION OF MILD STEEL
Journal of the Turkish Chemical Society Section B: Chemical Engineering
corrosion
conducting polymers
mos2
. tafel polarization
mild steel
title EFFECT OF MOS2 DOPED CONDUCTING POLYMERS TO CORROSION OF MILD STEEL
title_full EFFECT OF MOS2 DOPED CONDUCTING POLYMERS TO CORROSION OF MILD STEEL
title_fullStr EFFECT OF MOS2 DOPED CONDUCTING POLYMERS TO CORROSION OF MILD STEEL
title_full_unstemmed EFFECT OF MOS2 DOPED CONDUCTING POLYMERS TO CORROSION OF MILD STEEL
title_short EFFECT OF MOS2 DOPED CONDUCTING POLYMERS TO CORROSION OF MILD STEEL
title_sort effect of mos2 doped conducting polymers to corrosion of mild steel
topic corrosion
conducting polymers
mos2
. tafel polarization
mild steel
url https://dergipark.org.tr/en/pub/jotcsb/issue/45604/573053
work_keys_str_mv AT abdurrahmanasan effectofmos2dopedconductingpolymerstocorrosionofmildsteel
AT guldenasan effectofmos2dopedconductingpolymerstocorrosionofmildsteel