Enhancement of Sm<sup>3+</sup>emission by SnO<sub>2</sub>nanocrystals in the silica matrix

<p>Abstract</p><p>Silica xerogels containing Sm<sup>3+</sup>ions and SnO<sub>2</sub>nanocrystals were prepared in a sol&#8211;gel process. The image of transmission electron microscopy (TEM) shows that the SnO<sub>2</sub>nanocrystals are disp...

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Main Authors: Mu Jin, Liu Lingyun, Kang Shi-Zhao
Format: Article
Language:English
Published: SpringerOpen 2007-01-01
Series:Nanoscale Research Letters
Subjects:
Online Access:http://dx.doi.org/10.1007/s11671-006-9037-1
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author Mu Jin
Liu Lingyun
Kang Shi-Zhao
author_facet Mu Jin
Liu Lingyun
Kang Shi-Zhao
author_sort Mu Jin
collection DOAJ
description <p>Abstract</p><p>Silica xerogels containing Sm<sup>3+</sup>ions and SnO<sub>2</sub>nanocrystals were prepared in a sol&#8211;gel process. The image of transmission electron microscopy (TEM) shows that the SnO<sub>2</sub>nanocrystals are dispersed in the silica matrix. The X-ray diffraction (XRD) of the sample confirms the tetragonal phase of SnO<sub>2</sub>. The xerogels containing SnO<sub>2</sub>nanocrystals and Sm<sup>3+</sup>ions display the characteristic emission of Sm<sup>3+</sup>ions (<sup>4</sup>G<sub>5/2 </sub>&#8594; <sup>6</sup>H<sub><it>J</it></sub>(<it>J</it> = 5/2, 7/2, 9/2)) at the excitation of 335 nm which energy corresponds to the energy gap of the SnO<sub>2</sub>nanocrystals, while no emission of Sm<sup>3+</sup>ions can be observed for the samples containing Sm<sup>3+</sup>ions. The enhancement of the Sm<sup>3+</sup>emission is probably due to the energy transfer from SnO<sub>2</sub>nanocrystals to Sm<sup>3+</sup>ions.</p>
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spelling doaj.art-ac2aac633c914c46af5df3822334bb3c2023-09-03T01:52:24ZengSpringerOpenNanoscale Research Letters1931-75731556-276X2007-01-0122100103Enhancement of Sm<sup>3+</sup>emission by SnO<sub>2</sub>nanocrystals in the silica matrixMu JinLiu LingyunKang Shi-Zhao<p>Abstract</p><p>Silica xerogels containing Sm<sup>3+</sup>ions and SnO<sub>2</sub>nanocrystals were prepared in a sol&#8211;gel process. The image of transmission electron microscopy (TEM) shows that the SnO<sub>2</sub>nanocrystals are dispersed in the silica matrix. The X-ray diffraction (XRD) of the sample confirms the tetragonal phase of SnO<sub>2</sub>. The xerogels containing SnO<sub>2</sub>nanocrystals and Sm<sup>3+</sup>ions display the characteristic emission of Sm<sup>3+</sup>ions (<sup>4</sup>G<sub>5/2 </sub>&#8594; <sup>6</sup>H<sub><it>J</it></sub>(<it>J</it> = 5/2, 7/2, 9/2)) at the excitation of 335 nm which energy corresponds to the energy gap of the SnO<sub>2</sub>nanocrystals, while no emission of Sm<sup>3+</sup>ions can be observed for the samples containing Sm<sup>3+</sup>ions. The enhancement of the Sm<sup>3+</sup>emission is probably due to the energy transfer from SnO<sub>2</sub>nanocrystals to Sm<sup>3+</sup>ions.</p>http://dx.doi.org/10.1007/s11671-006-9037-1Sm<sup>3+</sup>ionsEmissionSensibilizationSnO<sub>2</sub>nanocrystalsSilica matrix
spellingShingle Mu Jin
Liu Lingyun
Kang Shi-Zhao
Enhancement of Sm<sup>3+</sup>emission by SnO<sub>2</sub>nanocrystals in the silica matrix
Nanoscale Research Letters
Sm<sup>3+</sup>ions
Emission
Sensibilization
SnO<sub>2</sub>nanocrystals
Silica matrix
title Enhancement of Sm<sup>3+</sup>emission by SnO<sub>2</sub>nanocrystals in the silica matrix
title_full Enhancement of Sm<sup>3+</sup>emission by SnO<sub>2</sub>nanocrystals in the silica matrix
title_fullStr Enhancement of Sm<sup>3+</sup>emission by SnO<sub>2</sub>nanocrystals in the silica matrix
title_full_unstemmed Enhancement of Sm<sup>3+</sup>emission by SnO<sub>2</sub>nanocrystals in the silica matrix
title_short Enhancement of Sm<sup>3+</sup>emission by SnO<sub>2</sub>nanocrystals in the silica matrix
title_sort enhancement of sm sup 3 sup emission by sno sub 2 sub nanocrystals in the silica matrix
topic Sm<sup>3+</sup>ions
Emission
Sensibilization
SnO<sub>2</sub>nanocrystals
Silica matrix
url http://dx.doi.org/10.1007/s11671-006-9037-1
work_keys_str_mv AT mujin enhancementofsmsup3supemissionbysnosub2subnanocrystalsinthesilicamatrix
AT liulingyun enhancementofsmsup3supemissionbysnosub2subnanocrystalsinthesilicamatrix
AT kangshizhao enhancementofsmsup3supemissionbysnosub2subnanocrystalsinthesilicamatrix