Enhancement of Sm<sup>3+</sup>emission by SnO<sub>2</sub>nanocrystals in the silica matrix
<p>Abstract</p><p>Silica xerogels containing Sm<sup>3+</sup>ions and SnO<sub>2</sub>nanocrystals were prepared in a sol–gel process. The image of transmission electron microscopy (TEM) shows that the SnO<sub>2</sub>nanocrystals are disp...
Main Authors: | , , |
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Format: | Article |
Language: | English |
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SpringerOpen
2007-01-01
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Series: | Nanoscale Research Letters |
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Online Access: | http://dx.doi.org/10.1007/s11671-006-9037-1 |
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author | Mu Jin Liu Lingyun Kang Shi-Zhao |
author_facet | Mu Jin Liu Lingyun Kang Shi-Zhao |
author_sort | Mu Jin |
collection | DOAJ |
description | <p>Abstract</p><p>Silica xerogels containing Sm<sup>3+</sup>ions and SnO<sub>2</sub>nanocrystals were prepared in a sol–gel process. The image of transmission electron microscopy (TEM) shows that the SnO<sub>2</sub>nanocrystals are dispersed in the silica matrix. The X-ray diffraction (XRD) of the sample confirms the tetragonal phase of SnO<sub>2</sub>. The xerogels containing SnO<sub>2</sub>nanocrystals and Sm<sup>3+</sup>ions display the characteristic emission of Sm<sup>3+</sup>ions (<sup>4</sup>G<sub>5/2 </sub>→ <sup>6</sup>H<sub><it>J</it></sub>(<it>J</it> = 5/2, 7/2, 9/2)) at the excitation of 335 nm which energy corresponds to the energy gap of the SnO<sub>2</sub>nanocrystals, while no emission of Sm<sup>3+</sup>ions can be observed for the samples containing Sm<sup>3+</sup>ions. The enhancement of the Sm<sup>3+</sup>emission is probably due to the energy transfer from SnO<sub>2</sub>nanocrystals to Sm<sup>3+</sup>ions.</p> |
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issn | 1931-7573 1556-276X |
language | English |
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spelling | doaj.art-ac2aac633c914c46af5df3822334bb3c2023-09-03T01:52:24ZengSpringerOpenNanoscale Research Letters1931-75731556-276X2007-01-0122100103Enhancement of Sm<sup>3+</sup>emission by SnO<sub>2</sub>nanocrystals in the silica matrixMu JinLiu LingyunKang Shi-Zhao<p>Abstract</p><p>Silica xerogels containing Sm<sup>3+</sup>ions and SnO<sub>2</sub>nanocrystals were prepared in a sol–gel process. The image of transmission electron microscopy (TEM) shows that the SnO<sub>2</sub>nanocrystals are dispersed in the silica matrix. The X-ray diffraction (XRD) of the sample confirms the tetragonal phase of SnO<sub>2</sub>. The xerogels containing SnO<sub>2</sub>nanocrystals and Sm<sup>3+</sup>ions display the characteristic emission of Sm<sup>3+</sup>ions (<sup>4</sup>G<sub>5/2 </sub>→ <sup>6</sup>H<sub><it>J</it></sub>(<it>J</it> = 5/2, 7/2, 9/2)) at the excitation of 335 nm which energy corresponds to the energy gap of the SnO<sub>2</sub>nanocrystals, while no emission of Sm<sup>3+</sup>ions can be observed for the samples containing Sm<sup>3+</sup>ions. The enhancement of the Sm<sup>3+</sup>emission is probably due to the energy transfer from SnO<sub>2</sub>nanocrystals to Sm<sup>3+</sup>ions.</p>http://dx.doi.org/10.1007/s11671-006-9037-1Sm<sup>3+</sup>ionsEmissionSensibilizationSnO<sub>2</sub>nanocrystalsSilica matrix |
spellingShingle | Mu Jin Liu Lingyun Kang Shi-Zhao Enhancement of Sm<sup>3+</sup>emission by SnO<sub>2</sub>nanocrystals in the silica matrix Nanoscale Research Letters Sm<sup>3+</sup>ions Emission Sensibilization SnO<sub>2</sub>nanocrystals Silica matrix |
title | Enhancement of Sm<sup>3+</sup>emission by SnO<sub>2</sub>nanocrystals in the silica matrix |
title_full | Enhancement of Sm<sup>3+</sup>emission by SnO<sub>2</sub>nanocrystals in the silica matrix |
title_fullStr | Enhancement of Sm<sup>3+</sup>emission by SnO<sub>2</sub>nanocrystals in the silica matrix |
title_full_unstemmed | Enhancement of Sm<sup>3+</sup>emission by SnO<sub>2</sub>nanocrystals in the silica matrix |
title_short | Enhancement of Sm<sup>3+</sup>emission by SnO<sub>2</sub>nanocrystals in the silica matrix |
title_sort | enhancement of sm sup 3 sup emission by sno sub 2 sub nanocrystals in the silica matrix |
topic | Sm<sup>3+</sup>ions Emission Sensibilization SnO<sub>2</sub>nanocrystals Silica matrix |
url | http://dx.doi.org/10.1007/s11671-006-9037-1 |
work_keys_str_mv | AT mujin enhancementofsmsup3supemissionbysnosub2subnanocrystalsinthesilicamatrix AT liulingyun enhancementofsmsup3supemissionbysnosub2subnanocrystalsinthesilicamatrix AT kangshizhao enhancementofsmsup3supemissionbysnosub2subnanocrystalsinthesilicamatrix |