Poly[(μ4-1,2,3-benzothiadiazole-7-carboxylato)silver(I)]
In the crystal structure of the title compound, [Ag(C7H3N2O2S)]n, the AgI atom is coordinated by two N atoms and three O atoms of four organic ligands forming a distorted square pyramid. The carboxylate group acts as a bidentate ligand on one AgI atom and as a bridging group for a symmetry-related A...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-08-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810027029 |
| _version_ | 1818945859474161664 |
|---|---|
| author | Jiong-Peng Zhao Fu-Chen Liu |
| author_facet | Jiong-Peng Zhao Fu-Chen Liu |
| author_sort | Jiong-Peng Zhao |
| collection | DOAJ |
| description | In the crystal structure of the title compound, [Ag(C7H3N2O2S)]n, the AgI atom is coordinated by two N atoms and three O atoms of four organic ligands forming a distorted square pyramid. The carboxylate group acts as a bidentate ligand on one AgI atom and as a bridging group for a symmetry-related AgI atom, forming a dimer. Futhermore, the two N atoms of two thiadiazole rings bridge a third symmetry-related AgI atom, forming a six-membered ring. These two frameworks, AgO2Ag and AgN4Ag, extend in three directions, forming a three-dimensionnal polymer. The whole polymer is organized around inversion centers. |
| first_indexed | 2024-12-20T08:05:49Z |
| format | Article |
| id | doaj.art-ac37d75b9aaf4846bfd13aa3d9b338d7 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T08:05:49Z |
| publishDate | 2010-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-ac37d75b9aaf4846bfd13aa3d9b338d72022-12-21T19:47:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668m974m97410.1107/S1600536810027029Poly[(μ4-1,2,3-benzothiadiazole-7-carboxylato)silver(I)]Jiong-Peng ZhaoFu-Chen LiuIn the crystal structure of the title compound, [Ag(C7H3N2O2S)]n, the AgI atom is coordinated by two N atoms and three O atoms of four organic ligands forming a distorted square pyramid. The carboxylate group acts as a bidentate ligand on one AgI atom and as a bridging group for a symmetry-related AgI atom, forming a dimer. Futhermore, the two N atoms of two thiadiazole rings bridge a third symmetry-related AgI atom, forming a six-membered ring. These two frameworks, AgO2Ag and AgN4Ag, extend in three directions, forming a three-dimensionnal polymer. The whole polymer is organized around inversion centers.http://scripts.iucr.org/cgi-bin/paper?S1600536810027029 |
| spellingShingle | Jiong-Peng Zhao Fu-Chen Liu Poly[(μ4-1,2,3-benzothiadiazole-7-carboxylato)silver(I)] Acta Crystallographica Section E |
| title | Poly[(μ4-1,2,3-benzothiadiazole-7-carboxylato)silver(I)] |
| title_full | Poly[(μ4-1,2,3-benzothiadiazole-7-carboxylato)silver(I)] |
| title_fullStr | Poly[(μ4-1,2,3-benzothiadiazole-7-carboxylato)silver(I)] |
| title_full_unstemmed | Poly[(μ4-1,2,3-benzothiadiazole-7-carboxylato)silver(I)] |
| title_short | Poly[(μ4-1,2,3-benzothiadiazole-7-carboxylato)silver(I)] |
| title_sort | poly amp 956 4 1 2 3 benzothiadiazole 7 carboxylato silver i |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810027029 |
| work_keys_str_mv | AT jiongpengzhao polyamp9564123benzothiadiazole7carboxylatosilveri AT fuchenliu polyamp9564123benzothiadiazole7carboxylatosilveri |