Fabrication of an Anti-Reflective and Super-Hydrophobic Structure by Vacuum Ultraviolet Light-Assisted Bonding and Nanoscale Pattern Transfer

The application of subwavelength, textured structures to glass surfaces has been shown to reduce reflectivity and also results in self-cleaning due to super-hydrophobicity. However, current methods of producing such textures are typically either expensive or difficult to scale up. Based on prior wor...

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Main Authors: Yuki Hashimoto, Takatoki Yamamoto
Format: Article
Language:English
Published: MDPI AG 2018-04-01
Series:Micromachines
Subjects:
Online Access:http://www.mdpi.com/2072-666X/9/4/186
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author Yuki Hashimoto
Takatoki Yamamoto
author_facet Yuki Hashimoto
Takatoki Yamamoto
author_sort Yuki Hashimoto
collection DOAJ
description The application of subwavelength, textured structures to glass surfaces has been shown to reduce reflectivity and also results in self-cleaning due to super-hydrophobicity. However, current methods of producing such textures are typically either expensive or difficult to scale up. Based on prior work by the authors, the present study employed a combination of vacuum ultraviolet (VUV) light-assisted bonding and release agent-free pattern transfer to fabricate a moth-eye texture on a glass substrate. This was accomplished by forming a cyclic olefin polymer mold master with a moth-eye pattern, transferring this pattern to a polydimethylsiloxane (PDMS) spin coating, activating both the PDMS and a glass substrate with VUV light, and then bonding the PDMS to the glass before releasing the mold. Atomic force microscopy demonstrated that the desired pattern was successfully replicated on the PDMS surface with a high degree of accuracy, and the textured glass specimen exhibited approximately 3% higher transmittance than untreated glass. Contact angle measurements also showed that the hydrophobicity of the textured surface was significantly increased. These results confirm that this new technique is a viable means of fabricating optical nanostructures via a simple, inexpensive process.
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spelling doaj.art-acabc717daf74e3b8c5744ba11f56fb82022-12-21T20:35:55ZengMDPI AGMicromachines2072-666X2018-04-019418610.3390/mi9040186mi9040186Fabrication of an Anti-Reflective and Super-Hydrophobic Structure by Vacuum Ultraviolet Light-Assisted Bonding and Nanoscale Pattern TransferYuki Hashimoto0Takatoki Yamamoto1Department of Mechanical and Control Engineering, Tokyo Institute of Technology, Tokyo, 1528552, JapanDepartment of Mechanical and Control Engineering, Tokyo Institute of Technology, Tokyo, 1528552, JapanThe application of subwavelength, textured structures to glass surfaces has been shown to reduce reflectivity and also results in self-cleaning due to super-hydrophobicity. However, current methods of producing such textures are typically either expensive or difficult to scale up. Based on prior work by the authors, the present study employed a combination of vacuum ultraviolet (VUV) light-assisted bonding and release agent-free pattern transfer to fabricate a moth-eye texture on a glass substrate. This was accomplished by forming a cyclic olefin polymer mold master with a moth-eye pattern, transferring this pattern to a polydimethylsiloxane (PDMS) spin coating, activating both the PDMS and a glass substrate with VUV light, and then bonding the PDMS to the glass before releasing the mold. Atomic force microscopy demonstrated that the desired pattern was successfully replicated on the PDMS surface with a high degree of accuracy, and the textured glass specimen exhibited approximately 3% higher transmittance than untreated glass. Contact angle measurements also showed that the hydrophobicity of the textured surface was significantly increased. These results confirm that this new technique is a viable means of fabricating optical nanostructures via a simple, inexpensive process.http://www.mdpi.com/2072-666X/9/4/186anti-reflectionsuper-hydrophobicityvacuum ultravioletpolydimethylsiloxane
spellingShingle Yuki Hashimoto
Takatoki Yamamoto
Fabrication of an Anti-Reflective and Super-Hydrophobic Structure by Vacuum Ultraviolet Light-Assisted Bonding and Nanoscale Pattern Transfer
Micromachines
anti-reflection
super-hydrophobicity
vacuum ultraviolet
polydimethylsiloxane
title Fabrication of an Anti-Reflective and Super-Hydrophobic Structure by Vacuum Ultraviolet Light-Assisted Bonding and Nanoscale Pattern Transfer
title_full Fabrication of an Anti-Reflective and Super-Hydrophobic Structure by Vacuum Ultraviolet Light-Assisted Bonding and Nanoscale Pattern Transfer
title_fullStr Fabrication of an Anti-Reflective and Super-Hydrophobic Structure by Vacuum Ultraviolet Light-Assisted Bonding and Nanoscale Pattern Transfer
title_full_unstemmed Fabrication of an Anti-Reflective and Super-Hydrophobic Structure by Vacuum Ultraviolet Light-Assisted Bonding and Nanoscale Pattern Transfer
title_short Fabrication of an Anti-Reflective and Super-Hydrophobic Structure by Vacuum Ultraviolet Light-Assisted Bonding and Nanoscale Pattern Transfer
title_sort fabrication of an anti reflective and super hydrophobic structure by vacuum ultraviolet light assisted bonding and nanoscale pattern transfer
topic anti-reflection
super-hydrophobicity
vacuum ultraviolet
polydimethylsiloxane
url http://www.mdpi.com/2072-666X/9/4/186
work_keys_str_mv AT yukihashimoto fabricationofanantireflectiveandsuperhydrophobicstructurebyvacuumultravioletlightassistedbondingandnanoscalepatterntransfer
AT takatokiyamamoto fabricationofanantireflectiveandsuperhydrophobicstructurebyvacuumultravioletlightassistedbondingandnanoscalepatterntransfer