Immobilization of Humic Acid on Bentonite and Its Application for Adsorption of Cs137 and Am241

In the present work, immobilization of humic acid on bentonite and its application as an adsorbent of Cs137 (Cesium) and Am241 (Americium) is performed. The parameters studied are rate constant, adsorption capacity, and adsorption energy. This research started with the immobilization of humic acid o...

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Main Author: H. P. Suseno and A. D. Warisaura
Format: Article
Language:English
Published: Technoscience Publications 2022-09-01
Series:Nature Environment and Pollution Technology
Subjects:
Online Access:https://neptjournal.com/upload-images/(39)D-1302.pdf
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author H. P. Suseno and A. D. Warisaura
author_facet H. P. Suseno and A. D. Warisaura
author_sort H. P. Suseno and A. D. Warisaura
collection DOAJ
description In the present work, immobilization of humic acid on bentonite and its application as an adsorbent of Cs137 (Cesium) and Am241 (Americium) is performed. The parameters studied are rate constant, adsorption capacity, and adsorption energy. This research started with the immobilization of humic acid on a bentonite surface followed by a stability test for immobilization of humic acid at various acidities. Adsorption of Cs 137 and AM 241 ions was conducted by first examining the optimum pH giving minimum complexed ions by the soluble fraction of humic acid and maximum adsorbed ions on the adsorbent. While adsorption energy and capacity were determined by the Langmuir isotherm adsorption model. The result shows that the amount of immobilization of humic acid on bentonite is 39.75 % (w/w) at optimum conditions. Immobilization of humic acid was stable up to pH 12.0. For both ions, optimum adsorption occurred at pH 5. At this optimum condition, the adsorption energies of 21.481 kJ.mol-1 and 22.276 kJ.mol-1 for Cs173 and Am241 are obtained, respectively. The result also shows that adsorption capacity and energy for Am241 were higher than that for Cs137 which indicates the affinity of Am241 for both adsorbents was higher than that of Cs137.
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spelling doaj.art-acad295b21934341803b5191f78358e22022-12-22T01:48:58ZengTechnoscience PublicationsNature Environment and Pollution Technology0972-62682395-34542022-09-012131325133110.46488/NEPT.2022.v21i03.039Immobilization of Humic Acid on Bentonite and Its Application for Adsorption of Cs137 and Am241H. P. Suseno and A. D. WarisauraIn the present work, immobilization of humic acid on bentonite and its application as an adsorbent of Cs137 (Cesium) and Am241 (Americium) is performed. The parameters studied are rate constant, adsorption capacity, and adsorption energy. This research started with the immobilization of humic acid on a bentonite surface followed by a stability test for immobilization of humic acid at various acidities. Adsorption of Cs 137 and AM 241 ions was conducted by first examining the optimum pH giving minimum complexed ions by the soluble fraction of humic acid and maximum adsorbed ions on the adsorbent. While adsorption energy and capacity were determined by the Langmuir isotherm adsorption model. The result shows that the amount of immobilization of humic acid on bentonite is 39.75 % (w/w) at optimum conditions. Immobilization of humic acid was stable up to pH 12.0. For both ions, optimum adsorption occurred at pH 5. At this optimum condition, the adsorption energies of 21.481 kJ.mol-1 and 22.276 kJ.mol-1 for Cs173 and Am241 are obtained, respectively. The result also shows that adsorption capacity and energy for Am241 were higher than that for Cs137 which indicates the affinity of Am241 for both adsorbents was higher than that of Cs137.https://neptjournal.com/upload-images/(39)D-1302.pdfadsorption, am241, cs137, humic acid, immobilization
spellingShingle H. P. Suseno and A. D. Warisaura
Immobilization of Humic Acid on Bentonite and Its Application for Adsorption of Cs137 and Am241
Nature Environment and Pollution Technology
adsorption, am241, cs137, humic acid, immobilization
title Immobilization of Humic Acid on Bentonite and Its Application for Adsorption of Cs137 and Am241
title_full Immobilization of Humic Acid on Bentonite and Its Application for Adsorption of Cs137 and Am241
title_fullStr Immobilization of Humic Acid on Bentonite and Its Application for Adsorption of Cs137 and Am241
title_full_unstemmed Immobilization of Humic Acid on Bentonite and Its Application for Adsorption of Cs137 and Am241
title_short Immobilization of Humic Acid on Bentonite and Its Application for Adsorption of Cs137 and Am241
title_sort immobilization of humic acid on bentonite and its application for adsorption of cs137 and am241
topic adsorption, am241, cs137, humic acid, immobilization
url https://neptjournal.com/upload-images/(39)D-1302.pdf
work_keys_str_mv AT hpsusenoandadwarisaura immobilizationofhumicacidonbentoniteanditsapplicationforadsorptionofcs137andam241