Study of barium sulfate dissolution by scale dissolver based on solutions of DTPA

Abstract In offshore oil wells it is very common to perform seawater injection through injection wells for hydrocarbon recovery. When seawater, rich in sulfate ion, mixes with formation water, whose composition can contain divalent cations such as barium and calcium, it often leads to sulfate salts...

Full description

Bibliographic Details
Main Authors: GEIZILA A.P. ABIB, GEORGIANA F. DA CRUZ, ALEXANDRE S.L. VAZ JUNIOR
Format: Article
Language:English
Published: Academia Brasileira de Ciências
Series:Anais da Academia Brasileira de Ciências
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652018000603185&lng=en&tlng=en
_version_ 1818209193671262208
author GEIZILA A.P. ABIB
GEORGIANA F. DA CRUZ
ALEXANDRE S.L. VAZ JUNIOR
author_facet GEIZILA A.P. ABIB
GEORGIANA F. DA CRUZ
ALEXANDRE S.L. VAZ JUNIOR
author_sort GEIZILA A.P. ABIB
collection DOAJ
description Abstract In offshore oil wells it is very common to perform seawater injection through injection wells for hydrocarbon recovery. When seawater, rich in sulfate ion, mixes with formation water, whose composition can contain divalent cations such as barium and calcium, it often leads to sulfate salts formation due to their chemical incompatibility. These salts can cause serious damage in production wells. The barium sulfate (BaSO4) is the most problematic scale and may cause many complications. In order to solve this issue, polycarboxylic acids, such as diethylene triamine pentaacetic acid, are used. Thus, the primary focus of this work was to develop an experimental procedure to study the BaSO4 dissolution. Initially, through static tests to understand the relationship between dissolver concentration, temperature and dissolution time, and then through dynamic tests in sandstone reservoirs. Based on the results obtained, in the static tests the best condition for barite to dissolve was at high temperatures (80 ºC) and contact time of 48 hours, since from 50 °C there is an increase in dissolution rate, associated with a long contact time between dissolver and barite. In the dynamic tests, after scale formation, barite could be removed, but the high DTPA concentration should be avoided.
first_indexed 2024-12-12T04:56:49Z
format Article
id doaj.art-acd5ac5473bc46409c6a38a9ce8e9483
institution Directory Open Access Journal
issn 1678-2690
language English
last_indexed 2024-12-12T04:56:49Z
publisher Academia Brasileira de Ciências
record_format Article
series Anais da Academia Brasileira de Ciências
spelling doaj.art-acd5ac5473bc46409c6a38a9ce8e94832022-12-22T00:37:20ZengAcademia Brasileira de CiênciasAnais da Academia Brasileira de Ciências1678-26909033185319610.1590/0001-3765201820170728S0001-37652018000603185Study of barium sulfate dissolution by scale dissolver based on solutions of DTPAGEIZILA A.P. ABIBGEORGIANA F. DA CRUZALEXANDRE S.L. VAZ JUNIORAbstract In offshore oil wells it is very common to perform seawater injection through injection wells for hydrocarbon recovery. When seawater, rich in sulfate ion, mixes with formation water, whose composition can contain divalent cations such as barium and calcium, it often leads to sulfate salts formation due to their chemical incompatibility. These salts can cause serious damage in production wells. The barium sulfate (BaSO4) is the most problematic scale and may cause many complications. In order to solve this issue, polycarboxylic acids, such as diethylene triamine pentaacetic acid, are used. Thus, the primary focus of this work was to develop an experimental procedure to study the BaSO4 dissolution. Initially, through static tests to understand the relationship between dissolver concentration, temperature and dissolution time, and then through dynamic tests in sandstone reservoirs. Based on the results obtained, in the static tests the best condition for barite to dissolve was at high temperatures (80 ºC) and contact time of 48 hours, since from 50 °C there is an increase in dissolution rate, associated with a long contact time between dissolver and barite. In the dynamic tests, after scale formation, barite could be removed, but the high DTPA concentration should be avoided.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652018000603185&lng=en&tlng=enMineral scalebariteoil reservoirformation damage
spellingShingle GEIZILA A.P. ABIB
GEORGIANA F. DA CRUZ
ALEXANDRE S.L. VAZ JUNIOR
Study of barium sulfate dissolution by scale dissolver based on solutions of DTPA
Anais da Academia Brasileira de Ciências
Mineral scale
barite
oil reservoir
formation damage
title Study of barium sulfate dissolution by scale dissolver based on solutions of DTPA
title_full Study of barium sulfate dissolution by scale dissolver based on solutions of DTPA
title_fullStr Study of barium sulfate dissolution by scale dissolver based on solutions of DTPA
title_full_unstemmed Study of barium sulfate dissolution by scale dissolver based on solutions of DTPA
title_short Study of barium sulfate dissolution by scale dissolver based on solutions of DTPA
title_sort study of barium sulfate dissolution by scale dissolver based on solutions of dtpa
topic Mineral scale
barite
oil reservoir
formation damage
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652018000603185&lng=en&tlng=en
work_keys_str_mv AT geizilaapabib studyofbariumsulfatedissolutionbyscaledissolverbasedonsolutionsofdtpa
AT georgianafdacruz studyofbariumsulfatedissolutionbyscaledissolverbasedonsolutionsofdtpa
AT alexandreslvazjunior studyofbariumsulfatedissolutionbyscaledissolverbasedonsolutionsofdtpa