Bis(μ2-3,5-diisopropyl-4H-1,2,4-triazole-κ2N1:N2)bis[(nitrato-κO)silver(I)]
The neutral N-heterocycle in the title centrosymmetric dinuclear compound, [Ag2(NO3)2(C8H15N3)2], bridges two metal atoms through its imino N atoms. The N—Ag—N skeleton is bent [N—Ag—N = 127.2 (3)°]; as one of two O a...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809028384 |
| _version_ | 1818948313704038400 |
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| author | Guang Yang Seik Weng Ng Ying-Li Wang Zhao-Yang Wang |
| author_facet | Guang Yang Seik Weng Ng Ying-Li Wang Zhao-Yang Wang |
| author_sort | Guang Yang |
| collection | DOAJ |
| description | The neutral N-heterocycle in the title centrosymmetric dinuclear compound, [Ag2(NO3)2(C8H15N3)2], bridges two metal atoms through its imino N atoms. The N—Ag—N skeleton is bent [N—Ag—N = 127.2 (3)°]; as one of two O atoms of the nitrate anion is nearly coplanar with this N—Ag—N skeleton [Ag—O = 2.63 (1) Å], the coordination geometry around the AgI atom is regarded as trigonal-planar. One of the two isopropyl groups is disordered over two positions in respect of the methyl groups in a 1:1 ratio. In the crystal structure, intermolecular N—H...O hydrogen bonding is observed between the nitrate groups and triazole ligands. |
| first_indexed | 2024-12-20T08:44:49Z |
| format | Article |
| id | doaj.art-acec7fdd924f45999f339c2ac60e1d11 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T08:44:49Z |
| publishDate | 2009-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-acec7fdd924f45999f339c2ac60e1d112022-12-21T19:46:16ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-08-01658m974m97410.1107/S1600536809028384Bis(μ2-3,5-diisopropyl-4H-1,2,4-triazole-κ2N1:N2)bis[(nitrato-κO)silver(I)]Guang YangSeik Weng NgYing-Li WangZhao-Yang WangThe neutral N-heterocycle in the title centrosymmetric dinuclear compound, [Ag2(NO3)2(C8H15N3)2], bridges two metal atoms through its imino N atoms. The N—Ag—N skeleton is bent [N—Ag—N = 127.2 (3)°]; as one of two O atoms of the nitrate anion is nearly coplanar with this N—Ag—N skeleton [Ag—O = 2.63 (1) Å], the coordination geometry around the AgI atom is regarded as trigonal-planar. One of the two isopropyl groups is disordered over two positions in respect of the methyl groups in a 1:1 ratio. In the crystal structure, intermolecular N—H...O hydrogen bonding is observed between the nitrate groups and triazole ligands.http://scripts.iucr.org/cgi-bin/paper?S1600536809028384 |
| spellingShingle | Guang Yang Seik Weng Ng Ying-Li Wang Zhao-Yang Wang Bis(μ2-3,5-diisopropyl-4H-1,2,4-triazole-κ2N1:N2)bis[(nitrato-κO)silver(I)] Acta Crystallographica Section E |
| title | Bis(μ2-3,5-diisopropyl-4H-1,2,4-triazole-κ2N1:N2)bis[(nitrato-κO)silver(I)] |
| title_full | Bis(μ2-3,5-diisopropyl-4H-1,2,4-triazole-κ2N1:N2)bis[(nitrato-κO)silver(I)] |
| title_fullStr | Bis(μ2-3,5-diisopropyl-4H-1,2,4-triazole-κ2N1:N2)bis[(nitrato-κO)silver(I)] |
| title_full_unstemmed | Bis(μ2-3,5-diisopropyl-4H-1,2,4-triazole-κ2N1:N2)bis[(nitrato-κO)silver(I)] |
| title_short | Bis(μ2-3,5-diisopropyl-4H-1,2,4-triazole-κ2N1:N2)bis[(nitrato-κO)silver(I)] |
| title_sort | bis amp 956 2 3 5 diisopropyl 4h 1 2 4 triazole amp 954 2n1 n2 bis nitrato amp 954 o silver i |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809028384 |
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