Effect of Boronizing on the Microstructure and Mechanical Properties of CoCrFeNiMn High-Entropy Alloy

The CoCrFeNiMn high-entropy alloys were treated by powder-pack boriding to improve their surface hardness and wear resistance. The variation of boriding layer thickness with time and temperature was studied. Then, the frequency factor D<sub>0</sub> and diffusion activation energy Q of el...

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Main Authors: Mingyu Hu, Xuemei Ouyang, Fucheng Yin, Xu Zhao, Zuchuan Zhang, Xinming Wang
Format: Article
Language:English
Published: MDPI AG 2023-05-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/16/10/3754
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author Mingyu Hu
Xuemei Ouyang
Fucheng Yin
Xu Zhao
Zuchuan Zhang
Xinming Wang
author_facet Mingyu Hu
Xuemei Ouyang
Fucheng Yin
Xu Zhao
Zuchuan Zhang
Xinming Wang
author_sort Mingyu Hu
collection DOAJ
description The CoCrFeNiMn high-entropy alloys were treated by powder-pack boriding to improve their surface hardness and wear resistance. The variation of boriding layer thickness with time and temperature was studied. Then, the frequency factor D<sub>0</sub> and diffusion activation energy Q of element B in HEA are calculated to be 9.15 × 10<sup>−5</sup> m<sup>2</sup>/s and 206.93 kJ/mol, respectively. The diffusion behavior of elements in the boronizing process was investigated and shows that the boride layer forms with the metal atoms diffusing outward and the diffusion layer forms with the B atoms diffusing inward by the Pt-labeling method. In addition, the surface microhardness of CoCrFeNiMn HEA was significantly improved to 23.8 ± 1.4 Gpa, and the friction coefficient was reduced from 0.86 to 0.48~0.61.
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spelling doaj.art-acffaef9ef224436ba7c5e96c39e218a2023-11-18T02:15:41ZengMDPI AGMaterials1996-19442023-05-011610375410.3390/ma16103754Effect of Boronizing on the Microstructure and Mechanical Properties of CoCrFeNiMn High-Entropy AlloyMingyu Hu0Xuemei Ouyang1Fucheng Yin2Xu Zhao3Zuchuan Zhang4Xinming Wang5School of Materials Science and Engineering, Xiangtan University, Xiangtan 411105, ChinaSchool of Materials Science and Engineering, Xiangtan University, Xiangtan 411105, ChinaSchool of Materials Science and Engineering, Xiangtan University, Xiangtan 411105, ChinaSchool of Materials Science and Engineering, Xiangtan University, Xiangtan 411105, ChinaSchool of Materials Science and Engineering, Xiangtan University, Xiangtan 411105, ChinaSchool of Materials Science and Engineering, Xiangtan University, Xiangtan 411105, ChinaThe CoCrFeNiMn high-entropy alloys were treated by powder-pack boriding to improve their surface hardness and wear resistance. The variation of boriding layer thickness with time and temperature was studied. Then, the frequency factor D<sub>0</sub> and diffusion activation energy Q of element B in HEA are calculated to be 9.15 × 10<sup>−5</sup> m<sup>2</sup>/s and 206.93 kJ/mol, respectively. The diffusion behavior of elements in the boronizing process was investigated and shows that the boride layer forms with the metal atoms diffusing outward and the diffusion layer forms with the B atoms diffusing inward by the Pt-labeling method. In addition, the surface microhardness of CoCrFeNiMn HEA was significantly improved to 23.8 ± 1.4 Gpa, and the friction coefficient was reduced from 0.86 to 0.48~0.61.https://www.mdpi.com/1996-1944/16/10/3754high entropy alloyboronizinggrowth kineticsboronizing mechanismwear resistance
spellingShingle Mingyu Hu
Xuemei Ouyang
Fucheng Yin
Xu Zhao
Zuchuan Zhang
Xinming Wang
Effect of Boronizing on the Microstructure and Mechanical Properties of CoCrFeNiMn High-Entropy Alloy
Materials
high entropy alloy
boronizing
growth kinetics
boronizing mechanism
wear resistance
title Effect of Boronizing on the Microstructure and Mechanical Properties of CoCrFeNiMn High-Entropy Alloy
title_full Effect of Boronizing on the Microstructure and Mechanical Properties of CoCrFeNiMn High-Entropy Alloy
title_fullStr Effect of Boronizing on the Microstructure and Mechanical Properties of CoCrFeNiMn High-Entropy Alloy
title_full_unstemmed Effect of Boronizing on the Microstructure and Mechanical Properties of CoCrFeNiMn High-Entropy Alloy
title_short Effect of Boronizing on the Microstructure and Mechanical Properties of CoCrFeNiMn High-Entropy Alloy
title_sort effect of boronizing on the microstructure and mechanical properties of cocrfenimn high entropy alloy
topic high entropy alloy
boronizing
growth kinetics
boronizing mechanism
wear resistance
url https://www.mdpi.com/1996-1944/16/10/3754
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