(2,2′-Biquinoline-κ2N,N′)dibromidopalladium(II)
The PdII ion in the title complex, [PdBr2(C18H12N2)], is four-coordinated in a distorted square-planar environment by the two N atoms from the chelating 2,2′-biquinoline (Biqu) ligand and two mutually cis Br− anions. The Biqu ligand is not planar, the dihedral angle betwe...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812015425 |
| _version_ | 1818321422586478592 |
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| author | Kwang Ha |
| author_facet | Kwang Ha |
| author_sort | Kwang Ha |
| collection | DOAJ |
| description | The PdII ion in the title complex, [PdBr2(C18H12N2)], is four-coordinated in a distorted square-planar environment by the two N atoms from the chelating 2,2′-biquinoline (Biqu) ligand and two mutually cis Br− anions. The Biqu ligand is not planar, the dihedral angle between the quinoline systems being 17.2 (2)°. In the crystal, the complex molecules are connected by C—H...Br hydrogen bonds, forming chains along the c axis. When viewed down the b axis, successive chains are stacked in opposite directions. Intramolecular C—H...Br hydrogen bonds are also observed. |
| first_indexed | 2024-12-13T10:40:39Z |
| format | Article |
| id | doaj.art-ad033103469d4ffe97a7eba7060c0924 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:40:39Z |
| publishDate | 2012-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-ad033103469d4ffe97a7eba7060c09242022-12-21T23:50:31ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-05-01685m618m61810.1107/S1600536812015425(2,2′-Biquinoline-κ2N,N′)dibromidopalladium(II)Kwang HaThe PdII ion in the title complex, [PdBr2(C18H12N2)], is four-coordinated in a distorted square-planar environment by the two N atoms from the chelating 2,2′-biquinoline (Biqu) ligand and two mutually cis Br− anions. The Biqu ligand is not planar, the dihedral angle between the quinoline systems being 17.2 (2)°. In the crystal, the complex molecules are connected by C—H...Br hydrogen bonds, forming chains along the c axis. When viewed down the b axis, successive chains are stacked in opposite directions. Intramolecular C—H...Br hydrogen bonds are also observed.http://scripts.iucr.org/cgi-bin/paper?S1600536812015425 |
| spellingShingle | Kwang Ha (2,2′-Biquinoline-κ2N,N′)dibromidopalladium(II) Acta Crystallographica Section E |
| title | (2,2′-Biquinoline-κ2N,N′)dibromidopalladium(II) |
| title_full | (2,2′-Biquinoline-κ2N,N′)dibromidopalladium(II) |
| title_fullStr | (2,2′-Biquinoline-κ2N,N′)dibromidopalladium(II) |
| title_full_unstemmed | (2,2′-Biquinoline-κ2N,N′)dibromidopalladium(II) |
| title_short | (2,2′-Biquinoline-κ2N,N′)dibromidopalladium(II) |
| title_sort | 2 2 amp 8242 biquinoline amp 954 2n n amp 8242 dibromidopalladium ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812015425 |
| work_keys_str_mv | AT kwangha 22amp8242biquinolineamp9542nnamp8242dibromidopalladiumii |