Fabrication and Characterization of Fullerene-Based Bulk Heterojunction Solar Cells with Porphyrin, CuInS2, Diamond and Exciton-Diffusion Blocking Layer

Fullerene-based bulk heterojunction solar cells were fabricated, and the electronic and optical properties were investigated. C60 were used as n-type semiconductors, and porphyrin, CuInS2 and diamond were used as p-type semiconductors. An effect of exciton-diffusion blocking layer of perylene deriva...

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Main Authors: Takeo Oku, Akihiro Takeda, Akihiko Nagata, Tatsuya Noma, Atsushi Suzuki, Kenji Kikuchi
Format: Article
Language:English
Published: MDPI AG 2010-04-01
Series:Energies
Subjects:
Online Access:http://www.mdpi.com/1996-1073/3/4/671/
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author Takeo Oku
Akihiro Takeda
Akihiko Nagata
Tatsuya Noma
Atsushi Suzuki
Kenji Kikuchi
author_facet Takeo Oku
Akihiro Takeda
Akihiko Nagata
Tatsuya Noma
Atsushi Suzuki
Kenji Kikuchi
author_sort Takeo Oku
collection DOAJ
description Fullerene-based bulk heterojunction solar cells were fabricated, and the electronic and optical properties were investigated. C60 were used as n-type semiconductors, and porphyrin, CuInS2 and diamond were used as p-type semiconductors. An effect of exciton-diffusion blocking layer of perylene derivative on the solar cells between active layer and metal layer was also investigated. Optimized structures with the exciton-diffusion blocking layer improved conversion efficiencies. Electronic structures of the molecules were investigated by molecular orbital calculation, and energy levels of the solar cells were discussed. Nanostructures of the solar cells were investigated by transmission electron microscopy, electron diffraction and X-ray diffraction, which indicated formation of mixed nanocrystals.
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spelling doaj.art-ad04db2f3b3d490ebc3a90e638b675952022-12-22T03:18:35ZengMDPI AGEnergies1996-10732010-04-013467168510.3390/en3040671Fabrication and Characterization of Fullerene-Based Bulk Heterojunction Solar Cells with Porphyrin, CuInS2, Diamond and Exciton-Diffusion Blocking LayerTakeo OkuAkihiro TakedaAkihiko NagataTatsuya NomaAtsushi SuzukiKenji KikuchiFullerene-based bulk heterojunction solar cells were fabricated, and the electronic and optical properties were investigated. C60 were used as n-type semiconductors, and porphyrin, CuInS2 and diamond were used as p-type semiconductors. An effect of exciton-diffusion blocking layer of perylene derivative on the solar cells between active layer and metal layer was also investigated. Optimized structures with the exciton-diffusion blocking layer improved conversion efficiencies. Electronic structures of the molecules were investigated by molecular orbital calculation, and energy levels of the solar cells were discussed. Nanostructures of the solar cells were investigated by transmission electron microscopy, electron diffraction and X-ray diffraction, which indicated formation of mixed nanocrystals.http://www.mdpi.com/1996-1073/3/4/671/fullerenesolar cellsporphyrinCuInS2diamond
spellingShingle Takeo Oku
Akihiro Takeda
Akihiko Nagata
Tatsuya Noma
Atsushi Suzuki
Kenji Kikuchi
Fabrication and Characterization of Fullerene-Based Bulk Heterojunction Solar Cells with Porphyrin, CuInS2, Diamond and Exciton-Diffusion Blocking Layer
Energies
fullerene
solar cells
porphyrin
CuInS2
diamond
title Fabrication and Characterization of Fullerene-Based Bulk Heterojunction Solar Cells with Porphyrin, CuInS2, Diamond and Exciton-Diffusion Blocking Layer
title_full Fabrication and Characterization of Fullerene-Based Bulk Heterojunction Solar Cells with Porphyrin, CuInS2, Diamond and Exciton-Diffusion Blocking Layer
title_fullStr Fabrication and Characterization of Fullerene-Based Bulk Heterojunction Solar Cells with Porphyrin, CuInS2, Diamond and Exciton-Diffusion Blocking Layer
title_full_unstemmed Fabrication and Characterization of Fullerene-Based Bulk Heterojunction Solar Cells with Porphyrin, CuInS2, Diamond and Exciton-Diffusion Blocking Layer
title_short Fabrication and Characterization of Fullerene-Based Bulk Heterojunction Solar Cells with Porphyrin, CuInS2, Diamond and Exciton-Diffusion Blocking Layer
title_sort fabrication and characterization of fullerene based bulk heterojunction solar cells with porphyrin cuins2 diamond and exciton diffusion blocking layer
topic fullerene
solar cells
porphyrin
CuInS2
diamond
url http://www.mdpi.com/1996-1073/3/4/671/
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