Removal of 2,4-Dichlorophenoxyacetic Acid from Aqueous Solutions Using Al<sub>2</sub>O<sub>3</sub>/Graphene Oxide Granules Prepared by Spray-Drying Method
Within this study, aluminum oxide granules with 0.25%vol. of graphene oxide were prepared by a spray-drying method to make an adsorbent for the 2,4-Dichlorophenoxyacetic acid (2,4-D) herbicide removal from aqueous solutions. The obtained adsorbent was studied using infrared spectroscopy, scanning el...
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2024-03-01
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author | Alexandra Yu. Kurmysheva Ekaterina Kuznetsova Marina D. Vedenyapina Pavel Podrabinnik Nestor Washington Solís Pinargote Anton Smirnov Sergey N. Grigoriev |
author_facet | Alexandra Yu. Kurmysheva Ekaterina Kuznetsova Marina D. Vedenyapina Pavel Podrabinnik Nestor Washington Solís Pinargote Anton Smirnov Sergey N. Grigoriev |
author_sort | Alexandra Yu. Kurmysheva |
collection | DOAJ |
description | Within this study, aluminum oxide granules with 0.25%vol. of graphene oxide were prepared by a spray-drying method to make an adsorbent for the 2,4-Dichlorophenoxyacetic acid (2,4-D) herbicide removal from aqueous solutions. The obtained adsorbent was studied using infrared spectroscopy, scanning electron microscopy and Raman spectroscopy. The presence of graphene in the spray-dried powder was confirmed. The adsorption removal of 2,4-D using the obtained material was performed at an ambient temperature by varying the process parameters such as pH and adsorption time. The adsorption of 2,4-D was a monolayer chemisorption according to the Langmuir isotherm pattern and a pseudo-second-order kinetic model. The maximum Langmuir adsorption capacity of the monolayer was 35.181 mg/g. The results show that the Al<sub>2</sub>O<sub>3</sub>-0.25%vol. GO powder obtained by spray drying is suitable for the production of adsorbents for toxic herbicides. |
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language | English |
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spelling | doaj.art-ad19b0d66fd04a5eae81d32b384897f02024-03-27T14:03:01ZengMDPI AGResources2079-92762024-03-011334010.3390/resources13030040Removal of 2,4-Dichlorophenoxyacetic Acid from Aqueous Solutions Using Al<sub>2</sub>O<sub>3</sub>/Graphene Oxide Granules Prepared by Spray-Drying MethodAlexandra Yu. Kurmysheva0Ekaterina Kuznetsova1Marina D. Vedenyapina2Pavel Podrabinnik3Nestor Washington Solís Pinargote4Anton Smirnov5Sergey N. Grigoriev6Laboratory of Electric Current Assisted Sintering Technologies, Moscow State University of Technology “STANKIN”, Vadkovsky per. 1, 127055 Moscow, RussiaLaboratory of 3D Structural and Functional Engineering, Moscow State University of Technology “STANKIN”, Vadkovsky per. 1, 127055 Moscow, RussiaN. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospect 47, 119991 Moscow, RussiaLaboratory of Electric Current Assisted Sintering Technologies, Moscow State University of Technology “STANKIN”, Vadkovsky per. 1, 127055 Moscow, RussiaLaboratory of 3D Structural and Functional Engineering, Moscow State University of Technology “STANKIN”, Vadkovsky per. 1, 127055 Moscow, RussiaLaboratory of 3D Structural and Functional Engineering, Moscow State University of Technology “STANKIN”, Vadkovsky per. 1, 127055 Moscow, RussiaLaboratory of Electric Current Assisted Sintering Technologies, Moscow State University of Technology “STANKIN”, Vadkovsky per. 1, 127055 Moscow, RussiaWithin this study, aluminum oxide granules with 0.25%vol. of graphene oxide were prepared by a spray-drying method to make an adsorbent for the 2,4-Dichlorophenoxyacetic acid (2,4-D) herbicide removal from aqueous solutions. The obtained adsorbent was studied using infrared spectroscopy, scanning electron microscopy and Raman spectroscopy. The presence of graphene in the spray-dried powder was confirmed. The adsorption removal of 2,4-D using the obtained material was performed at an ambient temperature by varying the process parameters such as pH and adsorption time. The adsorption of 2,4-D was a monolayer chemisorption according to the Langmuir isotherm pattern and a pseudo-second-order kinetic model. The maximum Langmuir adsorption capacity of the monolayer was 35.181 mg/g. The results show that the Al<sub>2</sub>O<sub>3</sub>-0.25%vol. GO powder obtained by spray drying is suitable for the production of adsorbents for toxic herbicides.https://www.mdpi.com/2079-9276/13/3/402,4-D adsorptionherbicide adsorptionalumina adsorbentgraphene oxidespray dry |
spellingShingle | Alexandra Yu. Kurmysheva Ekaterina Kuznetsova Marina D. Vedenyapina Pavel Podrabinnik Nestor Washington Solís Pinargote Anton Smirnov Sergey N. Grigoriev Removal of 2,4-Dichlorophenoxyacetic Acid from Aqueous Solutions Using Al<sub>2</sub>O<sub>3</sub>/Graphene Oxide Granules Prepared by Spray-Drying Method Resources 2,4-D adsorption herbicide adsorption alumina adsorbent graphene oxide spray dry |
title | Removal of 2,4-Dichlorophenoxyacetic Acid from Aqueous Solutions Using Al<sub>2</sub>O<sub>3</sub>/Graphene Oxide Granules Prepared by Spray-Drying Method |
title_full | Removal of 2,4-Dichlorophenoxyacetic Acid from Aqueous Solutions Using Al<sub>2</sub>O<sub>3</sub>/Graphene Oxide Granules Prepared by Spray-Drying Method |
title_fullStr | Removal of 2,4-Dichlorophenoxyacetic Acid from Aqueous Solutions Using Al<sub>2</sub>O<sub>3</sub>/Graphene Oxide Granules Prepared by Spray-Drying Method |
title_full_unstemmed | Removal of 2,4-Dichlorophenoxyacetic Acid from Aqueous Solutions Using Al<sub>2</sub>O<sub>3</sub>/Graphene Oxide Granules Prepared by Spray-Drying Method |
title_short | Removal of 2,4-Dichlorophenoxyacetic Acid from Aqueous Solutions Using Al<sub>2</sub>O<sub>3</sub>/Graphene Oxide Granules Prepared by Spray-Drying Method |
title_sort | removal of 2 4 dichlorophenoxyacetic acid from aqueous solutions using al sub 2 sub o sub 3 sub graphene oxide granules prepared by spray drying method |
topic | 2,4-D adsorption herbicide adsorption alumina adsorbent graphene oxide spray dry |
url | https://www.mdpi.com/2079-9276/13/3/40 |
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