Poly[μ-4,4′-bipyridine-κ2N:N′-μ-thiocyanato-κ2N:S-copper(I)]
In the crystal structure of the title compound, [Cu(NCS)(C10H8N2)]n, the CuI atom is coordinated by two N atoms from two symmetry-related 4,4′-bipyridine (bipy) ligands and one N and one S atom from two symmetry-related thiocyanate ligands in a distorted tetrahedral environment. The thiocy...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808033175 |
| _version_ | 1819279550329126912 |
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| author | Mario Wriedt Sina Sellmer Christian Näther |
| author_facet | Mario Wriedt Sina Sellmer Christian Näther |
| author_sort | Mario Wriedt |
| collection | DOAJ |
| description | In the crystal structure of the title compound, [Cu(NCS)(C10H8N2)]n, the CuI atom is coordinated by two N atoms from two symmetry-related 4,4′-bipyridine (bipy) ligands and one N and one S atom from two symmetry-related thiocyanate ligands in a distorted tetrahedral environment. The thiocyanate ligands bridge the CuI atoms into a zigzag [CuSCN]n chain running parallel to the a axis. These chains are further connected through two bipy ligands that bridge the CuI centers to generate a two-dimensional brick-like network. The pyridyl planes of the ligands exhibit a dihedral angle of 37.35 (12)°. |
| first_indexed | 2024-12-24T00:29:41Z |
| format | Article |
| id | doaj.art-ad3e2510e37d49fdb3085ad422cec833 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:29:41Z |
| publishDate | 2008-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-ad3e2510e37d49fdb3085ad422cec8332022-12-21T17:24:19ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-11-016411m1424m142510.1107/S1600536808033175Poly[μ-4,4′-bipyridine-κ2N:N′-μ-thiocyanato-κ2N:S-copper(I)]Mario WriedtSina SellmerChristian NätherIn the crystal structure of the title compound, [Cu(NCS)(C10H8N2)]n, the CuI atom is coordinated by two N atoms from two symmetry-related 4,4′-bipyridine (bipy) ligands and one N and one S atom from two symmetry-related thiocyanate ligands in a distorted tetrahedral environment. The thiocyanate ligands bridge the CuI atoms into a zigzag [CuSCN]n chain running parallel to the a axis. These chains are further connected through two bipy ligands that bridge the CuI centers to generate a two-dimensional brick-like network. The pyridyl planes of the ligands exhibit a dihedral angle of 37.35 (12)°.http://scripts.iucr.org/cgi-bin/paper?S1600536808033175 |
| spellingShingle | Mario Wriedt Sina Sellmer Christian Näther Poly[μ-4,4′-bipyridine-κ2N:N′-μ-thiocyanato-κ2N:S-copper(I)] Acta Crystallographica Section E |
| title | Poly[μ-4,4′-bipyridine-κ2N:N′-μ-thiocyanato-κ2N:S-copper(I)] |
| title_full | Poly[μ-4,4′-bipyridine-κ2N:N′-μ-thiocyanato-κ2N:S-copper(I)] |
| title_fullStr | Poly[μ-4,4′-bipyridine-κ2N:N′-μ-thiocyanato-κ2N:S-copper(I)] |
| title_full_unstemmed | Poly[μ-4,4′-bipyridine-κ2N:N′-μ-thiocyanato-κ2N:S-copper(I)] |
| title_short | Poly[μ-4,4′-bipyridine-κ2N:N′-μ-thiocyanato-κ2N:S-copper(I)] |
| title_sort | poly 956 4 4 8242 bipyridine 954 2n n 8242 956 thiocyanato 954 2n s copper i |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808033175 |
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