Synthesis and Structural Analysis of -2,4,6,8- Tetrabenzyl -2,4,6,8- Tetraazabicyclo [3.3.0] Octane from Condensation of Glyoxal, Benzylamine and Formaldehyde
The condensation of glyoxal with benzylamine in the presence of formaldehyde leads to 2,4,6,8-Tetrabenzyl-2,4,6,8-Tetraazabicyclo [3.3.0] octan (6) in methanol. The scopes and limitations of the reaction have been determined. At low temperatures, a mixture of (6) and diol (7) is formed.
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| Format: | Article |
| Language: | English |
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Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
1992-06-01
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| Series: | Iranian Journal of Chemistry & Chemical Engineering |
| Subjects: | |
| Online Access: | http://www.ijcce.ac.ir/article_10414_5e7ac159ed983c7682cf816f468e3e91.pdf |
| _version_ | 1818759519772082176 |
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| author | M. Farnia A. Kakanejadifard |
| author_facet | M. Farnia A. Kakanejadifard |
| author_sort | M. Farnia |
| collection | DOAJ |
| description | The condensation of glyoxal with benzylamine in the presence of formaldehyde leads to 2,4,6,8-Tetrabenzyl-2,4,6,8-Tetraazabicyclo [3.3.0] octan (6) in methanol. The scopes and limitations of the reaction have been determined. At low temperatures, a mixture of (6) and diol (7) is formed. |
| first_indexed | 2024-12-18T06:44:01Z |
| format | Article |
| id | doaj.art-ad41b3c62f854ad6bf7b5135b0ebe01a |
| institution | Directory Open Access Journal |
| issn | 1021-9986 1021-9986 |
| language | English |
| last_indexed | 2024-12-18T06:44:01Z |
| publishDate | 1992-06-01 |
| publisher | Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR |
| record_format | Article |
| series | Iranian Journal of Chemistry & Chemical Engineering |
| spelling | doaj.art-ad41b3c62f854ad6bf7b5135b0ebe01a2022-12-21T21:17:33ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering1021-99861021-99861992-06-01111394410414Synthesis and Structural Analysis of -2,4,6,8- Tetrabenzyl -2,4,6,8- Tetraazabicyclo [3.3.0] Octane from Condensation of Glyoxal, Benzylamine and FormaldehydeM. Farnia0A. Kakanejadifard1Chemistry Department, Faculty of Sciences, University of Tehran, P.O. Box 13145-143, Tehran, I.R. IRANChemistry Department, Faculty of Sciences, University of Tehran , P.O. Box 13145-143, Tehran, I.R. IRANThe condensation of glyoxal with benzylamine in the presence of formaldehyde leads to 2,4,6,8-Tetrabenzyl-2,4,6,8-Tetraazabicyclo [3.3.0] octan (6) in methanol. The scopes and limitations of the reaction have been determined. At low temperatures, a mixture of (6) and diol (7) is formed.http://www.ijcce.ac.ir/article_10414_5e7ac159ed983c7682cf816f468e3e91.pdffetraaza-bicyclo [3.3.0] octanesyn-dienvelopepolyazapolycyclic |
| spellingShingle | M. Farnia A. Kakanejadifard Synthesis and Structural Analysis of -2,4,6,8- Tetrabenzyl -2,4,6,8- Tetraazabicyclo [3.3.0] Octane from Condensation of Glyoxal, Benzylamine and Formaldehyde Iranian Journal of Chemistry & Chemical Engineering fetraaza-bicyclo [3.3.0] octane syn-dienvelope polyazapolycyclic |
| title | Synthesis and Structural Analysis of -2,4,6,8- Tetrabenzyl -2,4,6,8- Tetraazabicyclo [3.3.0] Octane from Condensation of Glyoxal, Benzylamine and Formaldehyde |
| title_full | Synthesis and Structural Analysis of -2,4,6,8- Tetrabenzyl -2,4,6,8- Tetraazabicyclo [3.3.0] Octane from Condensation of Glyoxal, Benzylamine and Formaldehyde |
| title_fullStr | Synthesis and Structural Analysis of -2,4,6,8- Tetrabenzyl -2,4,6,8- Tetraazabicyclo [3.3.0] Octane from Condensation of Glyoxal, Benzylamine and Formaldehyde |
| title_full_unstemmed | Synthesis and Structural Analysis of -2,4,6,8- Tetrabenzyl -2,4,6,8- Tetraazabicyclo [3.3.0] Octane from Condensation of Glyoxal, Benzylamine and Formaldehyde |
| title_short | Synthesis and Structural Analysis of -2,4,6,8- Tetrabenzyl -2,4,6,8- Tetraazabicyclo [3.3.0] Octane from Condensation of Glyoxal, Benzylamine and Formaldehyde |
| title_sort | synthesis and structural analysis of 2 4 6 8 tetrabenzyl 2 4 6 8 tetraazabicyclo 3 3 0 octane from condensation of glyoxal benzylamine and formaldehyde |
| topic | fetraaza-bicyclo [3.3.0] octane syn-dienvelope polyazapolycyclic |
| url | http://www.ijcce.ac.ir/article_10414_5e7ac159ed983c7682cf816f468e3e91.pdf |
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