Three-dimensional organization of pyrrolo[3,2-b]pyrrole-based triazine framework using nanostructural spherical carbon: enhancing electrochemical performance of materials for supercapacitors
Abstract Covalent triazine-based frameworks have attracted much interest recently due to their high surface area and excellent thermal and electrochemical stabilities. This study shows that covalently immobilizing triazine-based structures on spherical carbon nanostructures results in the organizati...
| Main Authors: | , , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
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Nature Portfolio
2023-07-01
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| Series: | Scientific Reports |
| Online Access: | https://doi.org/10.1038/s41598-023-37708-7 |
| _version_ | 1797784643495264256 |
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| author | Agnieszka Hryniewicka Joanna Breczko Gabriela Siemiaszko Anthony N. Papathanassiou Kinga Góra-Marek Karolina A. Tarach Krzysztof Brzezinski Anna Ilnicka Artur P. Terzyk Karolina H. Markiewicz Luis Echegoyen Marta E. Plonska-Brzezinska |
| author_facet | Agnieszka Hryniewicka Joanna Breczko Gabriela Siemiaszko Anthony N. Papathanassiou Kinga Góra-Marek Karolina A. Tarach Krzysztof Brzezinski Anna Ilnicka Artur P. Terzyk Karolina H. Markiewicz Luis Echegoyen Marta E. Plonska-Brzezinska |
| author_sort | Agnieszka Hryniewicka |
| collection | DOAJ |
| description | Abstract Covalent triazine-based frameworks have attracted much interest recently due to their high surface area and excellent thermal and electrochemical stabilities. This study shows that covalently immobilizing triazine-based structures on spherical carbon nanostructures results in the organization of micro- and mesopores in a three-dimensional manner. We selected the nitrile-functionalized pyrrolo[3,2-b]pyrrole unit to form triazine rings to construct a covalent organic framework. Combining spherical carbon nanostructures with the triazine framework produced a material with unique physicochemical properties, exhibiting the highest specific capacitance value of 638 F g−1 in aqueous acidic solutions. This phenomenon is attributed to many factors. The material exhibits a large surface area, a high content of micropores, a high content of graphitic N, and N-sites with basicity and semi-crystalline character. Thanks to the high structural organization and reproducibility, and remarkably high specific capacitance, these systems are promising materials for use in electrochemistry. For the first time, hybrid systems containing triazine-based frameworks and carbon nano-onions were used as electrodes for supercapacitors. |
| first_indexed | 2024-03-13T00:42:49Z |
| format | Article |
| id | doaj.art-ad4eab6387c94fa4a4daf4d40f717162 |
| institution | Directory Open Access Journal |
| issn | 2045-2322 |
| language | English |
| last_indexed | 2024-03-13T00:42:49Z |
| publishDate | 2023-07-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Scientific Reports |
| spelling | doaj.art-ad4eab6387c94fa4a4daf4d40f7171622023-07-09T11:13:55ZengNature PortfolioScientific Reports2045-23222023-07-0113111410.1038/s41598-023-37708-7Three-dimensional organization of pyrrolo[3,2-b]pyrrole-based triazine framework using nanostructural spherical carbon: enhancing electrochemical performance of materials for supercapacitorsAgnieszka Hryniewicka0Joanna Breczko1Gabriela Siemiaszko2Anthony N. Papathanassiou3Kinga Góra-Marek4Karolina A. Tarach5Krzysztof Brzezinski6Anna Ilnicka7Artur P. Terzyk8Karolina H. Markiewicz9Luis Echegoyen10Marta E. Plonska-Brzezinska11Department of Organic Chemistry, Faculty of Pharmacy with the Division of Laboratory Medicine, Medical University of BialystokDepartment of Organic Chemistry, Faculty of Pharmacy with the Division of Laboratory Medicine, Medical University of BialystokDepartment of Organic Chemistry, Faculty of Pharmacy with the Division of Laboratory Medicine, Medical University of BialystokPhysics Department, Condensed Matter Physics Section, National and Kapodistrian University of AthensFaculty of Chemistry, Jagiellonian University in KrakowFaculty of Chemistry, Jagiellonian University in KrakowDepartment of Structural Biology of Prokaryotic Organisms, Institute of Bioorganic Chemistry, Polish Academy of SciencesFaculty of Chemistry, Nicolaus Copernicus University in TorunFaculty of Chemistry, Nicolaus Copernicus University in TorunFaculty of Chemistry, University of BialystokDepartment of Chemistry, University of Texas at El PasoDepartment of Organic Chemistry, Faculty of Pharmacy with the Division of Laboratory Medicine, Medical University of BialystokAbstract Covalent triazine-based frameworks have attracted much interest recently due to their high surface area and excellent thermal and electrochemical stabilities. This study shows that covalently immobilizing triazine-based structures on spherical carbon nanostructures results in the organization of micro- and mesopores in a three-dimensional manner. We selected the nitrile-functionalized pyrrolo[3,2-b]pyrrole unit to form triazine rings to construct a covalent organic framework. Combining spherical carbon nanostructures with the triazine framework produced a material with unique physicochemical properties, exhibiting the highest specific capacitance value of 638 F g−1 in aqueous acidic solutions. This phenomenon is attributed to many factors. The material exhibits a large surface area, a high content of micropores, a high content of graphitic N, and N-sites with basicity and semi-crystalline character. Thanks to the high structural organization and reproducibility, and remarkably high specific capacitance, these systems are promising materials for use in electrochemistry. For the first time, hybrid systems containing triazine-based frameworks and carbon nano-onions were used as electrodes for supercapacitors.https://doi.org/10.1038/s41598-023-37708-7 |
| spellingShingle | Agnieszka Hryniewicka Joanna Breczko Gabriela Siemiaszko Anthony N. Papathanassiou Kinga Góra-Marek Karolina A. Tarach Krzysztof Brzezinski Anna Ilnicka Artur P. Terzyk Karolina H. Markiewicz Luis Echegoyen Marta E. Plonska-Brzezinska Three-dimensional organization of pyrrolo[3,2-b]pyrrole-based triazine framework using nanostructural spherical carbon: enhancing electrochemical performance of materials for supercapacitors Scientific Reports |
| title | Three-dimensional organization of pyrrolo[3,2-b]pyrrole-based triazine framework using nanostructural spherical carbon: enhancing electrochemical performance of materials for supercapacitors |
| title_full | Three-dimensional organization of pyrrolo[3,2-b]pyrrole-based triazine framework using nanostructural spherical carbon: enhancing electrochemical performance of materials for supercapacitors |
| title_fullStr | Three-dimensional organization of pyrrolo[3,2-b]pyrrole-based triazine framework using nanostructural spherical carbon: enhancing electrochemical performance of materials for supercapacitors |
| title_full_unstemmed | Three-dimensional organization of pyrrolo[3,2-b]pyrrole-based triazine framework using nanostructural spherical carbon: enhancing electrochemical performance of materials for supercapacitors |
| title_short | Three-dimensional organization of pyrrolo[3,2-b]pyrrole-based triazine framework using nanostructural spherical carbon: enhancing electrochemical performance of materials for supercapacitors |
| title_sort | three dimensional organization of pyrrolo 3 2 b pyrrole based triazine framework using nanostructural spherical carbon enhancing electrochemical performance of materials for supercapacitors |
| url | https://doi.org/10.1038/s41598-023-37708-7 |
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