Summary: | Photo-catalytically converting the greenhouse gas CO<sub>2</sub> into ethanol is an important avenue for the mitigation of climate issues and the utilization of renewable energies. Catalysts play critical roles in the reaction of photocatalytic CO<sub>2</sub> conversion to ethanol, and a number of catalysts have been investigated, including semiconductors and plasmonic metal-based catalysts, as well as several other catalysts. In this review, the progress in the development of each category of catalysts is summarized, the current status is reviewed, the remaining challenges are pointed out, and the future research directions are prospected, with the aim being to pave pathways for the rational design of better catalysts.
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