Effect of SiO2/Al2O3 ratio on the whiteness of ceramic tile engobes with low zircon content

Abstract Micronized zircon (ZrSiO4) is used as an opacifier in the production of engobes, opaque glazes, and floor tile bodies. Elevated price levels incentivize researchers to develop alternative engobe formulations with reduced zircon ratios. In this study, new engobes with low zircon content were...

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Main Authors: S. Ö. Varışli, F. Taşkıran, B. Öztürk, B. Çiçek
Format: Article
Language:English
Published: Associação Brasileira de Cerâmica 2023-12-01
Series:Cerâmica
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0366-69132023000300254&tlng=en
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author S. Ö. Varışli
F. Taşkıran
B. Öztürk
B. Çiçek
author_facet S. Ö. Varışli
F. Taşkıran
B. Öztürk
B. Çiçek
author_sort S. Ö. Varışli
collection DOAJ
description Abstract Micronized zircon (ZrSiO4) is used as an opacifier in the production of engobes, opaque glazes, and floor tile bodies. Elevated price levels incentivize researchers to develop alternative engobe formulations with reduced zircon ratios. In this study, new engobes with low zircon content were developed with varying SiO2-Al2O3 mixtures. The effect of the SiO2/Al2O3 ratio on the performance and opacity of the wall and floor tile engobes was investigated. It has been observed that the amount of zircon in the sample compositions could be reduced up to 40% by optimizing the refractoriness-water absorption balance of the engobe with the SiO2/Al2O3 ratio while keeping the opacity in the preferred levels. The color difference (∆E) value relative to the standard surface was below 1, which is acceptable for visual perception for all the samples. Other measurements such as water absorption and firing shrinkage of the floor tile samples were found to be compatible with the standard composition.
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spelling doaj.art-ad675efd28794b0d8e84c2c0b4a235532023-12-12T07:44:39ZengAssociação Brasileira de CerâmicaCerâmica1678-45532023-12-016939125426010.1590/0366-69132023693913465Effect of SiO2/Al2O3 ratio on the whiteness of ceramic tile engobes with low zircon contentS. Ö. Varışlihttps://orcid.org/0000-0002-2643-6828F. TaşkıranB. ÖztürkB. ÇiçekAbstract Micronized zircon (ZrSiO4) is used as an opacifier in the production of engobes, opaque glazes, and floor tile bodies. Elevated price levels incentivize researchers to develop alternative engobe formulations with reduced zircon ratios. In this study, new engobes with low zircon content were developed with varying SiO2-Al2O3 mixtures. The effect of the SiO2/Al2O3 ratio on the performance and opacity of the wall and floor tile engobes was investigated. It has been observed that the amount of zircon in the sample compositions could be reduced up to 40% by optimizing the refractoriness-water absorption balance of the engobe with the SiO2/Al2O3 ratio while keeping the opacity in the preferred levels. The color difference (∆E) value relative to the standard surface was below 1, which is acceptable for visual perception for all the samples. Other measurements such as water absorption and firing shrinkage of the floor tile samples were found to be compatible with the standard composition.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0366-69132023000300254&tlng=enceramicengobeopacifierSiO2/Al2O3 ratiotilezircon
spellingShingle S. Ö. Varışli
F. Taşkıran
B. Öztürk
B. Çiçek
Effect of SiO2/Al2O3 ratio on the whiteness of ceramic tile engobes with low zircon content
Cerâmica
ceramic
engobe
opacifier
SiO2/Al2O3 ratio
tile
zircon
title Effect of SiO2/Al2O3 ratio on the whiteness of ceramic tile engobes with low zircon content
title_full Effect of SiO2/Al2O3 ratio on the whiteness of ceramic tile engobes with low zircon content
title_fullStr Effect of SiO2/Al2O3 ratio on the whiteness of ceramic tile engobes with low zircon content
title_full_unstemmed Effect of SiO2/Al2O3 ratio on the whiteness of ceramic tile engobes with low zircon content
title_short Effect of SiO2/Al2O3 ratio on the whiteness of ceramic tile engobes with low zircon content
title_sort effect of sio2 al2o3 ratio on the whiteness of ceramic tile engobes with low zircon content
topic ceramic
engobe
opacifier
SiO2/Al2O3 ratio
tile
zircon
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0366-69132023000300254&tlng=en
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