A universal Urbach rule for disordered organic semiconductors
The sub-gap absorption coefficient in organic semiconductors is often characterized by Urbach energies, which quantify both structural and dynamic disorders, yet the fundamental is not well-understood. Here, the authors provide a strategy to determine excitonic disorder energy, and reveal that absor...
Main Authors: | , , , , , |
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Format: | Article |
Language: | English |
Published: |
Nature Portfolio
2021-06-01
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Series: | Nature Communications |
Online Access: | https://doi.org/10.1038/s41467-021-24202-9 |
Summary: | The sub-gap absorption coefficient in organic semiconductors is often characterized by Urbach energies, which quantify both structural and dynamic disorders, yet the fundamental is not well-understood. Here, the authors provide a strategy to determine excitonic disorder energy, and reveal that absorption at energies well below the gap is universally dominated by thermal broadening. |
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ISSN: | 2041-1723 |