Distribution and Speciation of Trace Elements in Soils of Four Land-Use Systems

Land use has a greater impact on trace element (TE) concentration present in soils. In mountainous regions of the western Himalayas, some dominating geogenic and human-dependent anthropogenic factors are involved in the spatial distribution of TEs in various land uses. Soil samples were collected fr...

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Main Authors: Farid Ul Haque, Faridullah Faridullah, Muhammad Irshad, Aziz-Ur-Rahim Bacha, Zahid Ullah, Muhammad Fawad, Farhan Hafeez, Akhtar Iqbal, Rashid Nazir, Abdulwahed Fahad Alrefaei, Mikhlid H. Almutairi
Format: Article
Language:English
Published: MDPI AG 2023-10-01
Series:Land
Subjects:
Online Access:https://www.mdpi.com/2073-445X/12/10/1894
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author Farid Ul Haque
Faridullah Faridullah
Muhammad Irshad
Aziz-Ur-Rahim Bacha
Zahid Ullah
Muhammad Fawad
Farhan Hafeez
Akhtar Iqbal
Rashid Nazir
Abdulwahed Fahad Alrefaei
Mikhlid H. Almutairi
author_facet Farid Ul Haque
Faridullah Faridullah
Muhammad Irshad
Aziz-Ur-Rahim Bacha
Zahid Ullah
Muhammad Fawad
Farhan Hafeez
Akhtar Iqbal
Rashid Nazir
Abdulwahed Fahad Alrefaei
Mikhlid H. Almutairi
author_sort Farid Ul Haque
collection DOAJ
description Land use has a greater impact on trace element (TE) concentration present in soils. In mountainous regions of the western Himalayas, some dominating geogenic and human-dependent anthropogenic factors are involved in the spatial distribution of TEs in various land uses. Soil samples were collected from permafrost, pasture, forest, and agricultural land-use systems of Babusar Valley and Fairy Meadows in Diamer districts and the Rama region in Astore Districts in replications for investigation of three TEs, i.e., copper (Cu), zinc (Zn), and nickel (Ni). These samples were analyzed for exchangeable, adsorbed, organically bound, carbonate precipitated, and residual forms. Significant differences among these TEs were observed. Differences in the levels of TEs within soil samples were observed to be influenced by land usage patterns. The physicochemical properties of soil samples were also investigated. Additionally, the total metals (Ni, Zn, Cu) were extracted and their concentrations were measured in all samples. The concentration of soil TEs was observed in the following order: adsorbed < organically bound < exchangeable < residual < carbonate precipitated form across all the land uses. The results indicate that the contents of TEs (Ni, Zn, Cu) in agricultural soils were greater than in the permafrost pasture and forest soil samples. The total TE concentration varied as Zn > Ni > Cu irrespective of the area and land uses. We believe this work will open avenues for researchers to explore TEs in various regions of the world.
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spelling doaj.art-ad90b3b93a544f63bef1b04b50fffb542023-11-19T17:04:06ZengMDPI AGLand2073-445X2023-10-011210189410.3390/land12101894Distribution and Speciation of Trace Elements in Soils of Four Land-Use SystemsFarid Ul Haque0Faridullah Faridullah1Muhammad Irshad2Aziz-Ur-Rahim Bacha3Zahid Ullah4Muhammad Fawad5Farhan Hafeez6Akhtar Iqbal7Rashid Nazir8Abdulwahed Fahad Alrefaei9Mikhlid H. Almutairi10Department of Environmental Sciences, COMSATS University Islamabad, Abbottabad Campus, Abbottabad 22060, PakistanDepartment of Environmental Sciences, COMSATS University Islamabad, Abbottabad Campus, Abbottabad 22060, PakistanDepartment of Environmental Sciences, COMSATS University Islamabad, Abbottabad Campus, Abbottabad 22060, PakistanState Key Laboratory of Urban Water Resource and Environment, Shenzhen Key Laboratory of Organic Pollution Prevention and Control, School of Civil and Environmental Engineering, Harbin Institute of Technology Shenzhen, Shenzhen 518055, ChinaState Key Laboratory of Biogeology and Environmental Geology, School of Environmental Studies, China University of Geosciences, Wuhan 430074, ChinaDepartment of Environmental Sciences, COMSATS University Islamabad, Abbottabad Campus, Abbottabad 22060, PakistanDepartment of Environmental Sciences, COMSATS University Islamabad, Abbottabad Campus, Abbottabad 22060, PakistanDepartment of Environmental Sciences, COMSATS University Islamabad, Abbottabad Campus, Abbottabad 22060, PakistanDepartment of Environmental Sciences, COMSATS University Islamabad, Abbottabad Campus, Abbottabad 22060, PakistanDepartment of Zoology, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi ArabiaDepartment of Zoology, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi ArabiaLand use has a greater impact on trace element (TE) concentration present in soils. In mountainous regions of the western Himalayas, some dominating geogenic and human-dependent anthropogenic factors are involved in the spatial distribution of TEs in various land uses. Soil samples were collected from permafrost, pasture, forest, and agricultural land-use systems of Babusar Valley and Fairy Meadows in Diamer districts and the Rama region in Astore Districts in replications for investigation of three TEs, i.e., copper (Cu), zinc (Zn), and nickel (Ni). These samples were analyzed for exchangeable, adsorbed, organically bound, carbonate precipitated, and residual forms. Significant differences among these TEs were observed. Differences in the levels of TEs within soil samples were observed to be influenced by land usage patterns. The physicochemical properties of soil samples were also investigated. Additionally, the total metals (Ni, Zn, Cu) were extracted and their concentrations were measured in all samples. The concentration of soil TEs was observed in the following order: adsorbed < organically bound < exchangeable < residual < carbonate precipitated form across all the land uses. The results indicate that the contents of TEs (Ni, Zn, Cu) in agricultural soils were greater than in the permafrost pasture and forest soil samples. The total TE concentration varied as Zn > Ni > Cu irrespective of the area and land uses. We believe this work will open avenues for researchers to explore TEs in various regions of the world.https://www.mdpi.com/2073-445X/12/10/1894trace elementspermafrost soilspasture soilsforest soilsagricultural soils
spellingShingle Farid Ul Haque
Faridullah Faridullah
Muhammad Irshad
Aziz-Ur-Rahim Bacha
Zahid Ullah
Muhammad Fawad
Farhan Hafeez
Akhtar Iqbal
Rashid Nazir
Abdulwahed Fahad Alrefaei
Mikhlid H. Almutairi
Distribution and Speciation of Trace Elements in Soils of Four Land-Use Systems
Land
trace elements
permafrost soils
pasture soils
forest soils
agricultural soils
title Distribution and Speciation of Trace Elements in Soils of Four Land-Use Systems
title_full Distribution and Speciation of Trace Elements in Soils of Four Land-Use Systems
title_fullStr Distribution and Speciation of Trace Elements in Soils of Four Land-Use Systems
title_full_unstemmed Distribution and Speciation of Trace Elements in Soils of Four Land-Use Systems
title_short Distribution and Speciation of Trace Elements in Soils of Four Land-Use Systems
title_sort distribution and speciation of trace elements in soils of four land use systems
topic trace elements
permafrost soils
pasture soils
forest soils
agricultural soils
url https://www.mdpi.com/2073-445X/12/10/1894
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