Ultrasmall barium titanate nanoparticles modulated stretchable dielectric elastomer sensors with large deformability and high sensitivity

Abstract Large deformability and high sensitivity is difficult to be realized simultaneously in flexible sensors. Herein, taking advantage of the high permittivity and highly active surfaces of the ultrasmall barium titanate nanoparticles (BT NPs) and the high stretchability of the p(BA‐GMA) elastom...

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Main Authors: Zun‐Peng Feng, Ya‐Nan Hao, Jing Qin, Shao‐Long Zhong, Ke Bi, Yu Zhao, Li‐Juan Yin, Jia‐Yao Pei, Zhi‐Min Dang
Format: Article
Language:English
Published: Wiley 2023-08-01
Series:InfoMat
Subjects:
Online Access:https://doi.org/10.1002/inf2.12413
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author Zun‐Peng Feng
Ya‐Nan Hao
Jing Qin
Shao‐Long Zhong
Ke Bi
Yu Zhao
Li‐Juan Yin
Jia‐Yao Pei
Zhi‐Min Dang
author_facet Zun‐Peng Feng
Ya‐Nan Hao
Jing Qin
Shao‐Long Zhong
Ke Bi
Yu Zhao
Li‐Juan Yin
Jia‐Yao Pei
Zhi‐Min Dang
author_sort Zun‐Peng Feng
collection DOAJ
description Abstract Large deformability and high sensitivity is difficult to be realized simultaneously in flexible sensors. Herein, taking advantage of the high permittivity and highly active surfaces of the ultrasmall barium titanate nanoparticles (BT NPs) and the high stretchability of the p(BA‐GMA) elastomer matrix, we propose a high‐performance soft stretchable sensor. The addition of the ultrasmall BT NPs can not only increase the permittivity and capacitance of polyacrylate‐matrix composite dielectric material to obtain a high sensitivity, but also basically maintains the excellent mechanical properties of the polymer matrix. The dielectric constants of the composite films increase from 5.68 to 13.13 at 10 kHz with the increase of BT NPs content from 0 to 15 vol.%, which results in a high capacitance of 236.16 pF for 15 vol.% BT/p(BA‐GMA) sensor. Combining the high permittivity and the large deformability (a maximal deformation of 87.2%), the 15 vol.% BT/p(BA‐GMA) sensor has high sensitivity and shows high linearity and stable output even if under dynamic measurement. The dual‐mode sensor that utilizes the orthogonality of capacitance‐resistance is designed, which shows excellent performance in monitoring human body movements and noncontact measurement. The results present that the BT/p(BA‐GMA)‐based sensor has high stability and reliability not exceed 65°C, which can meet the application requirements in dynamic monitoring.
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spelling doaj.art-ad9ca287680f40c7847c002aa43965792023-08-29T23:42:21ZengWileyInfoMat2567-31652023-08-0158n/an/a10.1002/inf2.12413Ultrasmall barium titanate nanoparticles modulated stretchable dielectric elastomer sensors with large deformability and high sensitivityZun‐Peng Feng0Ya‐Nan Hao1Jing Qin2Shao‐Long Zhong3Ke Bi4Yu Zhao5Li‐Juan Yin6Jia‐Yao Pei7Zhi‐Min Dang8State Key Laboratory of Information Photonics and Optical Communications, School of Science Beijing University of Posts and Telecommunications Beijing the People's Republic of ChinaState Key Laboratory of Information Photonics and Optical Communications, School of Science Beijing University of Posts and Telecommunications Beijing the People's Republic of ChinaState Key Laboratory of Information Photonics and Optical Communications, School of Science Beijing University of Posts and Telecommunications Beijing the People's Republic of ChinaState Key Laboratory of Power System, Department of Electrical Engineering Tsinghua University Beijing the People's Republic of ChinaState Key Laboratory of Information Photonics and Optical Communications, School of Science Beijing University of Posts and Telecommunications Beijing the People's Republic of ChinaSchool of Electrical Engineering Zheng Zhou University ZhengZhou the People's Republic of ChinaState Key Laboratory of Power System, Department of Electrical Engineering Tsinghua University Beijing the People's Republic of ChinaState Key Laboratory of Power System, Department of Electrical Engineering Tsinghua University Beijing the People's Republic of ChinaState Key Laboratory of Power System, Department of Electrical Engineering Tsinghua University Beijing the People's Republic of ChinaAbstract Large deformability and high sensitivity is difficult to be realized simultaneously in flexible sensors. Herein, taking advantage of the high permittivity and highly active surfaces of the ultrasmall barium titanate nanoparticles (BT NPs) and the high stretchability of the p(BA‐GMA) elastomer matrix, we propose a high‐performance soft stretchable sensor. The addition of the ultrasmall BT NPs can not only increase the permittivity and capacitance of polyacrylate‐matrix composite dielectric material to obtain a high sensitivity, but also basically maintains the excellent mechanical properties of the polymer matrix. The dielectric constants of the composite films increase from 5.68 to 13.13 at 10 kHz with the increase of BT NPs content from 0 to 15 vol.%, which results in a high capacitance of 236.16 pF for 15 vol.% BT/p(BA‐GMA) sensor. Combining the high permittivity and the large deformability (a maximal deformation of 87.2%), the 15 vol.% BT/p(BA‐GMA) sensor has high sensitivity and shows high linearity and stable output even if under dynamic measurement. The dual‐mode sensor that utilizes the orthogonality of capacitance‐resistance is designed, which shows excellent performance in monitoring human body movements and noncontact measurement. The results present that the BT/p(BA‐GMA)‐based sensor has high stability and reliability not exceed 65°C, which can meet the application requirements in dynamic monitoring.https://doi.org/10.1002/inf2.12413barium titanatecomposite dielectricelastomernanoparticlesstretchable sensor
spellingShingle Zun‐Peng Feng
Ya‐Nan Hao
Jing Qin
Shao‐Long Zhong
Ke Bi
Yu Zhao
Li‐Juan Yin
Jia‐Yao Pei
Zhi‐Min Dang
Ultrasmall barium titanate nanoparticles modulated stretchable dielectric elastomer sensors with large deformability and high sensitivity
InfoMat
barium titanate
composite dielectric
elastomer
nanoparticles
stretchable sensor
title Ultrasmall barium titanate nanoparticles modulated stretchable dielectric elastomer sensors with large deformability and high sensitivity
title_full Ultrasmall barium titanate nanoparticles modulated stretchable dielectric elastomer sensors with large deformability and high sensitivity
title_fullStr Ultrasmall barium titanate nanoparticles modulated stretchable dielectric elastomer sensors with large deformability and high sensitivity
title_full_unstemmed Ultrasmall barium titanate nanoparticles modulated stretchable dielectric elastomer sensors with large deformability and high sensitivity
title_short Ultrasmall barium titanate nanoparticles modulated stretchable dielectric elastomer sensors with large deformability and high sensitivity
title_sort ultrasmall barium titanate nanoparticles modulated stretchable dielectric elastomer sensors with large deformability and high sensitivity
topic barium titanate
composite dielectric
elastomer
nanoparticles
stretchable sensor
url https://doi.org/10.1002/inf2.12413
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