A Simple Approach to the 2D Mobile Adsorption of Gases on Heterogeneous Solid Surfaces Exhibiting Random Surface Topography

Based on a summation to infinity of the virial expansion for the 2D compressibility factor, simple equations have been developed for adsorption isotherms, and heats of adsorption, of 2D dense mobile films adsorbed on solid surfaces. They have subsequently been generalized for the presence of an exte...

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Main Authors: W. Rudzinski, J. Jagiello
Format: Article
Language:English
Published: SAGE Publications 1989-03-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1177/026361748900600105
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author W. Rudzinski
J. Jagiello
author_facet W. Rudzinski
J. Jagiello
author_sort W. Rudzinski
collection DOAJ
description Based on a summation to infinity of the virial expansion for the 2D compressibility factor, simple equations have been developed for adsorption isotherms, and heats of adsorption, of 2D dense mobile films adsorbed on solid surfaces. They have subsequently been generalized for the presence of an external, randomly varying potential field, created by the random surface topography exhibited by heterogeneous solid surfaces.
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spelling doaj.art-adab3b2470024b888fc65dce6765ab502024-03-02T16:05:13ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40381989-03-01610.1177/026361748900600105A Simple Approach to the 2D Mobile Adsorption of Gases on Heterogeneous Solid Surfaces Exhibiting Random Surface TopographyW. RudzinskiJ. JagielloBased on a summation to infinity of the virial expansion for the 2D compressibility factor, simple equations have been developed for adsorption isotherms, and heats of adsorption, of 2D dense mobile films adsorbed on solid surfaces. They have subsequently been generalized for the presence of an external, randomly varying potential field, created by the random surface topography exhibited by heterogeneous solid surfaces.https://doi.org/10.1177/026361748900600105
spellingShingle W. Rudzinski
J. Jagiello
A Simple Approach to the 2D Mobile Adsorption of Gases on Heterogeneous Solid Surfaces Exhibiting Random Surface Topography
Adsorption Science & Technology
title A Simple Approach to the 2D Mobile Adsorption of Gases on Heterogeneous Solid Surfaces Exhibiting Random Surface Topography
title_full A Simple Approach to the 2D Mobile Adsorption of Gases on Heterogeneous Solid Surfaces Exhibiting Random Surface Topography
title_fullStr A Simple Approach to the 2D Mobile Adsorption of Gases on Heterogeneous Solid Surfaces Exhibiting Random Surface Topography
title_full_unstemmed A Simple Approach to the 2D Mobile Adsorption of Gases on Heterogeneous Solid Surfaces Exhibiting Random Surface Topography
title_short A Simple Approach to the 2D Mobile Adsorption of Gases on Heterogeneous Solid Surfaces Exhibiting Random Surface Topography
title_sort simple approach to the 2d mobile adsorption of gases on heterogeneous solid surfaces exhibiting random surface topography
url https://doi.org/10.1177/026361748900600105
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