Crystal structure of N′-(2,6-dimethylphenyl)benzenecarboximidamide tetrahydrofuran monosolvate
The asymmetric unit of the title compound, C15H16N2·C4H8O, contains two amidine molecules (A and B) with slightly different conformations and two tetrahydrofuran (THF) solvent molecules. In the amidine molecules, the dimethylphenyl ring and the NH2 group lie to the same side of the N=C bond and the...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2015-01-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989014026255 |
| _version_ | 1798031224484134912 |
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| author | Jian-Ping Zhao Rui-Qin Liu Zhi-Hao Jiang Sheng-Di Bai |
| author_facet | Jian-Ping Zhao Rui-Qin Liu Zhi-Hao Jiang Sheng-Di Bai |
| author_sort | Jian-Ping Zhao |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, C15H16N2·C4H8O, contains two amidine molecules (A and B) with slightly different conformations and two tetrahydrofuran (THF) solvent molecules. In the amidine molecules, the dimethylphenyl ring and the NH2 group lie to the same side of the N=C bond and the dihedral angles between the aromatic rings are 54.25 (7) (molecule A) and 58.88 (6) ° (molecule B). In the crystal, N—H...N hydrogen bonds link the amidine molecules into [100] C(4) chains of alternating A and B molecules. Both amidine molecules form an N—H...O hydrogen bond to an adjacent THF solvent molecule. |
| first_indexed | 2024-04-11T19:54:00Z |
| format | Article |
| id | doaj.art-adaefae4e5004f968effa0327999a5ac |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-04-11T19:54:00Z |
| publishDate | 2015-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-adaefae4e5004f968effa0327999a5ac2022-12-22T04:06:14ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-01-01711o28o2910.1107/S2056989014026255hb7332Crystal structure of N′-(2,6-dimethylphenyl)benzenecarboximidamide tetrahydrofuran monosolvateJian-Ping Zhao0Rui-Qin Liu1Zhi-Hao Jiang2Sheng-Di Bai3Institute of Applied Chemistry, Shanxi University, Taiyuan 030006, People's Republic of ChinaInstitute of Applied Chemistry, Shanxi University, Taiyuan 030006, People's Republic of ChinaInstitute of Applied Chemistry, Shanxi University, Taiyuan 030006, People's Republic of ChinaInstitute of Applied Chemistry, Shanxi University, Taiyuan 030006, People's Republic of ChinaThe asymmetric unit of the title compound, C15H16N2·C4H8O, contains two amidine molecules (A and B) with slightly different conformations and two tetrahydrofuran (THF) solvent molecules. In the amidine molecules, the dimethylphenyl ring and the NH2 group lie to the same side of the N=C bond and the dihedral angles between the aromatic rings are 54.25 (7) (molecule A) and 58.88 (6) ° (molecule B). In the crystal, N—H...N hydrogen bonds link the amidine molecules into [100] C(4) chains of alternating A and B molecules. Both amidine molecules form an N—H...O hydrogen bond to an adjacent THF solvent molecule.http://scripts.iucr.org/cgi-bin/paper?S2056989014026255crystal structurebenzenecarboximidamidetetrahydrofuran solvatehydrogen bonding |
| spellingShingle | Jian-Ping Zhao Rui-Qin Liu Zhi-Hao Jiang Sheng-Di Bai Crystal structure of N′-(2,6-dimethylphenyl)benzenecarboximidamide tetrahydrofuran monosolvate Acta Crystallographica Section E: Crystallographic Communications crystal structure benzenecarboximidamide tetrahydrofuran solvate hydrogen bonding |
| title | Crystal structure of N′-(2,6-dimethylphenyl)benzenecarboximidamide tetrahydrofuran monosolvate |
| title_full | Crystal structure of N′-(2,6-dimethylphenyl)benzenecarboximidamide tetrahydrofuran monosolvate |
| title_fullStr | Crystal structure of N′-(2,6-dimethylphenyl)benzenecarboximidamide tetrahydrofuran monosolvate |
| title_full_unstemmed | Crystal structure of N′-(2,6-dimethylphenyl)benzenecarboximidamide tetrahydrofuran monosolvate |
| title_short | Crystal structure of N′-(2,6-dimethylphenyl)benzenecarboximidamide tetrahydrofuran monosolvate |
| title_sort | crystal structure of n 2 6 dimethylphenyl benzenecarboximidamide tetrahydrofuran monosolvate |
| topic | crystal structure benzenecarboximidamide tetrahydrofuran solvate hydrogen bonding |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989014026255 |
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