A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization
The ultimate control in polymer synthesis, precise monomer sequencing, is a highly sought after but complex problem. Here, the authors employ a repetitive and iterative intramolecular cyclization reaction, via a radical intermediate, to generate sequence-controlled vinyl oligomers.
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2016-03-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/ncomms11064 |
| _version_ | 1818842150723387392 |
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| author | Yusuke Hibi Makoto Ouchi Mitsuo Sawamoto |
| author_facet | Yusuke Hibi Makoto Ouchi Mitsuo Sawamoto |
| author_sort | Yusuke Hibi |
| collection | DOAJ |
| description | The ultimate control in polymer synthesis, precise monomer sequencing, is a highly sought after but complex problem. Here, the authors employ a repetitive and iterative intramolecular cyclization reaction, via a radical intermediate, to generate sequence-controlled vinyl oligomers. |
| first_indexed | 2024-12-19T04:37:24Z |
| format | Article |
| id | doaj.art-adb05ec269384e26887e8eee9d8579f9 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-19T04:37:24Z |
| publishDate | 2016-03-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-adb05ec269384e26887e8eee9d8579f92022-12-21T20:35:43ZengNature PortfolioNature Communications2041-17232016-03-01711910.1038/ncomms11064A strategy for sequence control in vinyl polymers via iterative controlled radical cyclizationYusuke Hibi0Makoto Ouchi1Mitsuo Sawamoto2Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-kuDepartment of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-kuDepartment of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-kuThe ultimate control in polymer synthesis, precise monomer sequencing, is a highly sought after but complex problem. Here, the authors employ a repetitive and iterative intramolecular cyclization reaction, via a radical intermediate, to generate sequence-controlled vinyl oligomers.https://doi.org/10.1038/ncomms11064 |
| spellingShingle | Yusuke Hibi Makoto Ouchi Mitsuo Sawamoto A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization Nature Communications |
| title | A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization |
| title_full | A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization |
| title_fullStr | A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization |
| title_full_unstemmed | A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization |
| title_short | A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization |
| title_sort | strategy for sequence control in vinyl polymers via iterative controlled radical cyclization |
| url | https://doi.org/10.1038/ncomms11064 |
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