Synthesis of New Homopiperazine-1.4-Diium Tetrachloridromercurate (II) Monohydrate (C<sub>5</sub>H<sub>14</sub>N<sub>2</sub>)[HgCl<sub>4</sub>]·H<sub>2</sub>O, Crystal Structure, Hirshfeld Surface, Spectroscopy, Thermal Analysis, Antioxidant Activity, Electric and Dielectric Behavior
Using acid–base assays and simple slow evaporation method at ambient temperature, we were successful in producing a novel salt with the chemical formula (C<sub>5</sub>H<sub>14</sub>N<sub>2</sub>)[HgCl<sub>4</sub>]·H<sub>2</sub>O. According...
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MDPI AG
2022-03-01
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| Online Access: | https://www.mdpi.com/2073-4352/12/4/486 |
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| author | Chaima Ayari Abdullah A. Alotaibi Mohammed A. Baashen Khalid M. Alotaibi Khadijah H. Alharbi Abdelhak Othmani Wataru Fujita Cherif Ben Nasr Mohamed Habib Mrad |
| author_facet | Chaima Ayari Abdullah A. Alotaibi Mohammed A. Baashen Khalid M. Alotaibi Khadijah H. Alharbi Abdelhak Othmani Wataru Fujita Cherif Ben Nasr Mohamed Habib Mrad |
| author_sort | Chaima Ayari |
| collection | DOAJ |
| description | Using acid–base assays and simple slow evaporation method at ambient temperature, we were successful in producing a novel salt with the chemical formula (C<sub>5</sub>H<sub>14</sub>N<sub>2</sub>)[HgCl<sub>4</sub>]·H<sub>2</sub>O. According to single-crystal X-ray diffraction data, the crystal packing was regulated by H-bonds and by Coulomb interactions (also called electrostatic interactions) between distinct entities, which formed a 3D network. The 2D fingerprint plots and the Hirshfeld surface were utilized to examine the effect of intermolecular interactions. FTIR spectroscopy, PL spectroscopy, thermal analysis, and electrical conductivity experiments were also carried out, and the antioxidant activity was tested. |
| first_indexed | 2024-03-09T10:59:24Z |
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| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-03-09T10:59:24Z |
| publishDate | 2022-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Crystals |
| spelling | doaj.art-adb96e94a07048328d4b43aee16cb7322023-12-01T01:24:20ZengMDPI AGCrystals2073-43522022-03-0112448610.3390/cryst12040486Synthesis of New Homopiperazine-1.4-Diium Tetrachloridromercurate (II) Monohydrate (C<sub>5</sub>H<sub>14</sub>N<sub>2</sub>)[HgCl<sub>4</sub>]·H<sub>2</sub>O, Crystal Structure, Hirshfeld Surface, Spectroscopy, Thermal Analysis, Antioxidant Activity, Electric and Dielectric BehaviorChaima Ayari0Abdullah A. Alotaibi1Mohammed A. Baashen2Khalid M. Alotaibi3Khadijah H. Alharbi4Abdelhak Othmani5Wataru Fujita6Cherif Ben Nasr7Mohamed Habib Mrad8Materials Chemistry Laboratory, Faculty of Sciences of Bizerte, University of Carthage, Zarzouna 7021, TunisiaDepartment of Chemistry, College of Sciences and Humanities, Shaqra University, Shaqra 11911, Saudi ArabiaDepartment of Chemistry, College of Sciences and Humanities, Shaqra University, Shaqra 11911, Saudi ArabiaDepartment of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi ArabiaDepartment of Chemistry, College of Sciences and Arts, King Abdulaziz University, Rabigh 21589, Saudi ArabiaLaboratory of Material Physics: Structures and Properties, LR01ES15, Faculty of Sciences, University of Carthage, Zarzouna 7021, TunisiaDepartment of Marine Electronics and Mechanical Engineering, Faculty of Marine Engineering, Tokyo University of Marine Science and Technology, Tokyo 135-8533, JapanMaterials Chemistry Laboratory, Faculty of Sciences of Bizerte, University of Carthage, Zarzouna 7021, TunisiaMaterials Chemistry Laboratory, Faculty of Sciences of Bizerte, University of Carthage, Zarzouna 7021, TunisiaUsing acid–base assays and simple slow evaporation method at ambient temperature, we were successful in producing a novel salt with the chemical formula (C<sub>5</sub>H<sub>14</sub>N<sub>2</sub>)[HgCl<sub>4</sub>]·H<sub>2</sub>O. According to single-crystal X-ray diffraction data, the crystal packing was regulated by H-bonds and by Coulomb interactions (also called electrostatic interactions) between distinct entities, which formed a 3D network. The 2D fingerprint plots and the Hirshfeld surface were utilized to examine the effect of intermolecular interactions. FTIR spectroscopy, PL spectroscopy, thermal analysis, and electrical conductivity experiments were also carried out, and the antioxidant activity was tested.https://www.mdpi.com/2073-4352/12/4/486photoluminescenceFT-IRchloromercurate (II)dielectric analysisantioxidant activity |
| spellingShingle | Chaima Ayari Abdullah A. Alotaibi Mohammed A. Baashen Khalid M. Alotaibi Khadijah H. Alharbi Abdelhak Othmani Wataru Fujita Cherif Ben Nasr Mohamed Habib Mrad Synthesis of New Homopiperazine-1.4-Diium Tetrachloridromercurate (II) Monohydrate (C<sub>5</sub>H<sub>14</sub>N<sub>2</sub>)[HgCl<sub>4</sub>]·H<sub>2</sub>O, Crystal Structure, Hirshfeld Surface, Spectroscopy, Thermal Analysis, Antioxidant Activity, Electric and Dielectric Behavior Crystals photoluminescence FT-IR chloromercurate (II) dielectric analysis antioxidant activity |
| title | Synthesis of New Homopiperazine-1.4-Diium Tetrachloridromercurate (II) Monohydrate (C<sub>5</sub>H<sub>14</sub>N<sub>2</sub>)[HgCl<sub>4</sub>]·H<sub>2</sub>O, Crystal Structure, Hirshfeld Surface, Spectroscopy, Thermal Analysis, Antioxidant Activity, Electric and Dielectric Behavior |
| title_full | Synthesis of New Homopiperazine-1.4-Diium Tetrachloridromercurate (II) Monohydrate (C<sub>5</sub>H<sub>14</sub>N<sub>2</sub>)[HgCl<sub>4</sub>]·H<sub>2</sub>O, Crystal Structure, Hirshfeld Surface, Spectroscopy, Thermal Analysis, Antioxidant Activity, Electric and Dielectric Behavior |
| title_fullStr | Synthesis of New Homopiperazine-1.4-Diium Tetrachloridromercurate (II) Monohydrate (C<sub>5</sub>H<sub>14</sub>N<sub>2</sub>)[HgCl<sub>4</sub>]·H<sub>2</sub>O, Crystal Structure, Hirshfeld Surface, Spectroscopy, Thermal Analysis, Antioxidant Activity, Electric and Dielectric Behavior |
| title_full_unstemmed | Synthesis of New Homopiperazine-1.4-Diium Tetrachloridromercurate (II) Monohydrate (C<sub>5</sub>H<sub>14</sub>N<sub>2</sub>)[HgCl<sub>4</sub>]·H<sub>2</sub>O, Crystal Structure, Hirshfeld Surface, Spectroscopy, Thermal Analysis, Antioxidant Activity, Electric and Dielectric Behavior |
| title_short | Synthesis of New Homopiperazine-1.4-Diium Tetrachloridromercurate (II) Monohydrate (C<sub>5</sub>H<sub>14</sub>N<sub>2</sub>)[HgCl<sub>4</sub>]·H<sub>2</sub>O, Crystal Structure, Hirshfeld Surface, Spectroscopy, Thermal Analysis, Antioxidant Activity, Electric and Dielectric Behavior |
| title_sort | synthesis of new homopiperazine 1 4 diium tetrachloridromercurate ii monohydrate c sub 5 sub h sub 14 sub n sub 2 sub hgcl sub 4 sub ·h sub 2 sub o crystal structure hirshfeld surface spectroscopy thermal analysis antioxidant activity electric and dielectric behavior |
| topic | photoluminescence FT-IR chloromercurate (II) dielectric analysis antioxidant activity |
| url | https://www.mdpi.com/2073-4352/12/4/486 |
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