Addition to Electron Deficient Olefins of α-Oxy Carbon- Centered Radicals, Generated from Cyclic Ethers and Acetals by the Reaction with Alkylperoxy- λ3-iodane
Thermal decomposition of 1-tert-butylperoxy-1,2-benziodoxol-3(1H)-one in cyclic ethers and acetals at 50 °C generates α-oxy carbon-centered radicals, which undergo an addition reaction with vinyl sulfones and unsaturated esters.
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2005-01-01
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| Series: | Molecules |
| Subjects: | |
| Online Access: | http://www.mdpi.com/1420-3049/10/1/195/ |
| _version_ | 1811290030471118848 |
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| author | M. Ochiai T. Suefuji Y. Takeuchi T. Sueda |
| author_facet | M. Ochiai T. Suefuji Y. Takeuchi T. Sueda |
| author_sort | M. Ochiai |
| collection | DOAJ |
| description | Thermal decomposition of 1-tert-butylperoxy-1,2-benziodoxol-3(1H)-one in cyclic ethers and acetals at 50 °C generates α-oxy carbon-centered radicals, which undergo an addition reaction with vinyl sulfones and unsaturated esters. |
| first_indexed | 2024-04-13T04:05:46Z |
| format | Article |
| id | doaj.art-adff2d2f778243d89d335f4965dc44b0 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-04-13T04:05:46Z |
| publishDate | 2005-01-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-adff2d2f778243d89d335f4965dc44b02022-12-22T03:03:18ZengMDPI AGMolecules1420-30492005-01-0110119520010.3390/10010195Addition to Electron Deficient Olefins of α-Oxy Carbon- Centered Radicals, Generated from Cyclic Ethers and Acetals by the Reaction with Alkylperoxy- λ3-iodaneM. OchiaiT. SuefujiY. TakeuchiT. SuedaThermal decomposition of 1-tert-butylperoxy-1,2-benziodoxol-3(1H)-one in cyclic ethers and acetals at 50 °C generates α-oxy carbon-centered radicals, which undergo an addition reaction with vinyl sulfones and unsaturated esters.http://www.mdpi.com/1420-3049/10/1/195/Radicaliodaneethervinyl sulfonemaleate |
| spellingShingle | M. Ochiai T. Suefuji Y. Takeuchi T. Sueda Addition to Electron Deficient Olefins of α-Oxy Carbon- Centered Radicals, Generated from Cyclic Ethers and Acetals by the Reaction with Alkylperoxy- λ3-iodane Molecules Radical iodane ether vinyl sulfone maleate |
| title | Addition to Electron Deficient Olefins of α-Oxy Carbon- Centered Radicals, Generated from Cyclic Ethers and Acetals by the Reaction with Alkylperoxy- λ3-iodane |
| title_full | Addition to Electron Deficient Olefins of α-Oxy Carbon- Centered Radicals, Generated from Cyclic Ethers and Acetals by the Reaction with Alkylperoxy- λ3-iodane |
| title_fullStr | Addition to Electron Deficient Olefins of α-Oxy Carbon- Centered Radicals, Generated from Cyclic Ethers and Acetals by the Reaction with Alkylperoxy- λ3-iodane |
| title_full_unstemmed | Addition to Electron Deficient Olefins of α-Oxy Carbon- Centered Radicals, Generated from Cyclic Ethers and Acetals by the Reaction with Alkylperoxy- λ3-iodane |
| title_short | Addition to Electron Deficient Olefins of α-Oxy Carbon- Centered Radicals, Generated from Cyclic Ethers and Acetals by the Reaction with Alkylperoxy- λ3-iodane |
| title_sort | addition to electron deficient olefins of aza oxy carbon centered radicals generated from cyclic ethers and acetals by the reaction with alkylperoxy aza 3 iodane |
| topic | Radical iodane ether vinyl sulfone maleate |
| url | http://www.mdpi.com/1420-3049/10/1/195/ |
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