Photocatalytic degradation of direct green & fast orange red dyes: Electrochemical sensor of lead using cupric oxide nanoparticles synthesized via sonochemical route
In this study, nanocrystalline cupric oxide was produced using a basic, low-cost sonochemical method (CuO). Through powder X-ray diffraction, the phase and nanocrystalline nature of CuO nanoparticles (NPs) were determined. The Kubelka-Monk function revealed that the band gap of CuO in diffuse reflec...
Main Authors: | , , |
---|---|
Format: | Article |
Language: | English |
Published: |
KeAi Communications Co., Ltd.
2022-01-01
|
Series: | Sensors International |
Subjects: | |
Online Access: | http://www.sciencedirect.com/science/article/pii/S2666351122000493 |
_version_ | 1811177234393726976 |
---|---|
author | D.A. Raghupathy G. Ramgopal C.R. Ravikumar |
author_facet | D.A. Raghupathy G. Ramgopal C.R. Ravikumar |
author_sort | D.A. Raghupathy |
collection | DOAJ |
description | In this study, nanocrystalline cupric oxide was produced using a basic, low-cost sonochemical method (CuO). Through powder X-ray diffraction, the phase and nanocrystalline nature of CuO nanoparticles (NPs) were determined. The Kubelka-Monk function revealed that the band gap of CuO in diffuse reflectance spectra (DRS) is 1.75 eV. Ingenious photocatalysts for the removal of the dyes Direct green (DG) and Fast orange red (F-OR) have been demonstrated to work with CuO NPs. To examine the photocatalytic characteristics of NPs under UV light and sunlight irradiation, Direct Green (DG) and Fast Orange Red (F-OR) dyes were utilised as traditional dyes. Direct green dye was found to be excited at 624.1 and 623.8 nm in UV and sunlight, while Fast orange red dye is excited at 496.8 and 495.1 nm. Lead in 0.1 N HCl solution was detected using the cyclic voltammetry (CV) method with a modified carbon paste electrode (MCPE). According to electrochemical performance, CuO is an advantageous sensing electrode material for an element like lead. |
first_indexed | 2024-04-10T22:59:25Z |
format | Article |
id | doaj.art-ae0e4187e7654c27b928e99625c6192d |
institution | Directory Open Access Journal |
issn | 2666-3511 |
language | English |
last_indexed | 2024-04-10T22:59:25Z |
publishDate | 2022-01-01 |
publisher | KeAi Communications Co., Ltd. |
record_format | Article |
series | Sensors International |
spelling | doaj.art-ae0e4187e7654c27b928e99625c6192d2023-01-14T04:27:29ZengKeAi Communications Co., Ltd.Sensors International2666-35112022-01-013100204Photocatalytic degradation of direct green & fast orange red dyes: Electrochemical sensor of lead using cupric oxide nanoparticles synthesized via sonochemical routeD.A. Raghupathy0G. Ramgopal1C.R. Ravikumar2Department of Physics, Dr. Ambedkar Institute of Technology, Bangalore, 560056, India; Bharathiar University, Coimbatore, Tamilnadu, 641046, IndiaDepartment of Physics, Maharani''s Science College for Women, Maharani Cluster University, Bengaluru, 560001, India; Corresponding author.Research Center, Department of Science, East West Institute of Technology, VTU, Bangalore, 560091, India; Corresponding author.In this study, nanocrystalline cupric oxide was produced using a basic, low-cost sonochemical method (CuO). Through powder X-ray diffraction, the phase and nanocrystalline nature of CuO nanoparticles (NPs) were determined. The Kubelka-Monk function revealed that the band gap of CuO in diffuse reflectance spectra (DRS) is 1.75 eV. Ingenious photocatalysts for the removal of the dyes Direct green (DG) and Fast orange red (F-OR) have been demonstrated to work with CuO NPs. To examine the photocatalytic characteristics of NPs under UV light and sunlight irradiation, Direct Green (DG) and Fast Orange Red (F-OR) dyes were utilised as traditional dyes. Direct green dye was found to be excited at 624.1 and 623.8 nm in UV and sunlight, while Fast orange red dye is excited at 496.8 and 495.1 nm. Lead in 0.1 N HCl solution was detected using the cyclic voltammetry (CV) method with a modified carbon paste electrode (MCPE). According to electrochemical performance, CuO is an advantageous sensing electrode material for an element like lead.http://www.sciencedirect.com/science/article/pii/S2666351122000493Cupric oxide nanoparticlesDirect greenFast orange redCPECyclic voltammetryLead sensor |
spellingShingle | D.A. Raghupathy G. Ramgopal C.R. Ravikumar Photocatalytic degradation of direct green & fast orange red dyes: Electrochemical sensor of lead using cupric oxide nanoparticles synthesized via sonochemical route Sensors International Cupric oxide nanoparticles Direct green Fast orange red CPE Cyclic voltammetry Lead sensor |
title | Photocatalytic degradation of direct green & fast orange red dyes: Electrochemical sensor of lead using cupric oxide nanoparticles synthesized via sonochemical route |
title_full | Photocatalytic degradation of direct green & fast orange red dyes: Electrochemical sensor of lead using cupric oxide nanoparticles synthesized via sonochemical route |
title_fullStr | Photocatalytic degradation of direct green & fast orange red dyes: Electrochemical sensor of lead using cupric oxide nanoparticles synthesized via sonochemical route |
title_full_unstemmed | Photocatalytic degradation of direct green & fast orange red dyes: Electrochemical sensor of lead using cupric oxide nanoparticles synthesized via sonochemical route |
title_short | Photocatalytic degradation of direct green & fast orange red dyes: Electrochemical sensor of lead using cupric oxide nanoparticles synthesized via sonochemical route |
title_sort | photocatalytic degradation of direct green amp fast orange red dyes electrochemical sensor of lead using cupric oxide nanoparticles synthesized via sonochemical route |
topic | Cupric oxide nanoparticles Direct green Fast orange red CPE Cyclic voltammetry Lead sensor |
url | http://www.sciencedirect.com/science/article/pii/S2666351122000493 |
work_keys_str_mv | AT daraghupathy photocatalyticdegradationofdirectgreenampfastorangereddyeselectrochemicalsensorofleadusingcupricoxidenanoparticlessynthesizedviasonochemicalroute AT gramgopal photocatalyticdegradationofdirectgreenampfastorangereddyeselectrochemicalsensorofleadusingcupricoxidenanoparticlessynthesizedviasonochemicalroute AT crravikumar photocatalyticdegradationofdirectgreenampfastorangereddyeselectrochemicalsensorofleadusingcupricoxidenanoparticlessynthesizedviasonochemicalroute |