N,N′-Bis(4-chlorobenzylidene)-3,3′-dimethoxybiphenyl-4,4′-diamine
The title compound, C28H22Cl2N2O2, crystallized with two independent molecules (A and B) in the asymmetric unit. The two molecules differ essentially in the orientation of the outer aromatic rings. These dihedral angles are 56.07 (13) and 27.62 (15) &...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811015467 |
| _version_ | 1828138950507626496 |
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| author | Ashokkumar Subashini Kandasamy Ramamurthi Helen Stoeckli-Evans |
| author_facet | Ashokkumar Subashini Kandasamy Ramamurthi Helen Stoeckli-Evans |
| author_sort | Ashokkumar Subashini |
| collection | DOAJ |
| description | The title compound, C28H22Cl2N2O2, crystallized with two independent molecules (A and B) in the asymmetric unit. The two molecules differ essentially in the orientation of the outer aromatic rings. These dihedral angles are 56.07 (13) and 27.62 (15) Å for molecules A and B, respectively. In the crystal, A molecules are related as centrosymmetric pairs through a weak π–π interaction [centroid–centroid distance = 3.6959 (15) Å]. There are also a number of intermolecular C—H...O, C—H...N and C—H...π interactions present. |
| first_indexed | 2024-04-11T18:44:29Z |
| format | Article |
| id | doaj.art-ae3a29296c294704be58b0a1faff8c53 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T18:44:29Z |
| publishDate | 2011-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-ae3a29296c294704be58b0a1faff8c532022-12-22T04:08:53ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-06-01676o1296o129710.1107/S1600536811015467N,N′-Bis(4-chlorobenzylidene)-3,3′-dimethoxybiphenyl-4,4′-diamineAshokkumar SubashiniKandasamy RamamurthiHelen Stoeckli-EvansThe title compound, C28H22Cl2N2O2, crystallized with two independent molecules (A and B) in the asymmetric unit. The two molecules differ essentially in the orientation of the outer aromatic rings. These dihedral angles are 56.07 (13) and 27.62 (15) Å for molecules A and B, respectively. In the crystal, A molecules are related as centrosymmetric pairs through a weak π–π interaction [centroid–centroid distance = 3.6959 (15) Å]. There are also a number of intermolecular C—H...O, C—H...N and C—H...π interactions present.http://scripts.iucr.org/cgi-bin/paper?S1600536811015467 |
| spellingShingle | Ashokkumar Subashini Kandasamy Ramamurthi Helen Stoeckli-Evans N,N′-Bis(4-chlorobenzylidene)-3,3′-dimethoxybiphenyl-4,4′-diamine Acta Crystallographica Section E |
| title | N,N′-Bis(4-chlorobenzylidene)-3,3′-dimethoxybiphenyl-4,4′-diamine |
| title_full | N,N′-Bis(4-chlorobenzylidene)-3,3′-dimethoxybiphenyl-4,4′-diamine |
| title_fullStr | N,N′-Bis(4-chlorobenzylidene)-3,3′-dimethoxybiphenyl-4,4′-diamine |
| title_full_unstemmed | N,N′-Bis(4-chlorobenzylidene)-3,3′-dimethoxybiphenyl-4,4′-diamine |
| title_short | N,N′-Bis(4-chlorobenzylidene)-3,3′-dimethoxybiphenyl-4,4′-diamine |
| title_sort | n n amp 8242 bis 4 chlorobenzylidene 3 3 amp 8242 dimethoxybiphenyl 4 4 amp 8242 diamine |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811015467 |
| work_keys_str_mv | AT ashokkumarsubashini nnamp8242bis4chlorobenzylidene33amp8242dimethoxybiphenyl44amp8242diamine AT kandasamyramamurthi nnamp8242bis4chlorobenzylidene33amp8242dimethoxybiphenyl44amp8242diamine AT helenstoecklievans nnamp8242bis4chlorobenzylidene33amp8242dimethoxybiphenyl44amp8242diamine |