Selective Pre-leaching of Tellurium From Telluride-Type Gold Concentrate

With a telluride-type gold ore flotation concentrate as the research object, the Na2S + NaOH collaborative leaching process was applied to selectively separate tellurium before the cyanide leaching of gold and silver. The effects of process parameters including the type of leaching agent, the amount...

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Main Authors: Wei Yang, Xuechen Lan, Qian Wang, Ping Dong, Gang Wang
Format: Article
Language:English
Published: Frontiers Media S.A. 2021-03-01
Series:Frontiers in Chemistry
Subjects:
Online Access:https://www.frontiersin.org/articles/10.3389/fchem.2021.593888/full
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author Wei Yang
Wei Yang
Xuechen Lan
Xuechen Lan
Qian Wang
Qian Wang
Ping Dong
Ping Dong
Gang Wang
Gang Wang
author_facet Wei Yang
Wei Yang
Xuechen Lan
Xuechen Lan
Qian Wang
Qian Wang
Ping Dong
Ping Dong
Gang Wang
Gang Wang
author_sort Wei Yang
collection DOAJ
description With a telluride-type gold ore flotation concentrate as the research object, the Na2S + NaOH collaborative leaching process was applied to selectively separate tellurium before the cyanide leaching of gold and silver. The effects of process parameters including the type of leaching agent, the amount of leaching agent, liquid-solid ratio, leaching temperature, and leaching time on the leaching rate of tellurium were investigated. The results showed that the tellurium leaching rate could reach 78.14% under the optimum conditions of −0.038 mm (95%) grinding fineness, 80 g/L Na2S concentration, 30 g/L NaOH concentration, 4:1 liquid-solid ratio, 80°C leaching temperature and 3 h′s leaching time. The kinetic analysis showed that the leaching process of tellurium from telluride-type gold concentrate was a mixed type of chemical reaction control and diffusion control. The grain parameter in the leaching process was 0.26263 and the apparent activation energy E = 17.12 kJ/mol. Tellurium could be pre-leached from the telluride-type gold flotation concentrate through the Na2S + NaOH alkaline leaching process to achieve the effective separation of tellurium from noble metals, which, when eliminating the adverse effects of telluride on the leaching of gold and silver, provides new ideas for the extraction of rare element tellurium.
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spelling doaj.art-ae406c20788544068186bb9cd5587ee22022-12-21T20:22:22ZengFrontiers Media S.A.Frontiers in Chemistry2296-26462021-03-01910.3389/fchem.2021.593888593888Selective Pre-leaching of Tellurium From Telluride-Type Gold ConcentrateWei Yang0Wei Yang1Xuechen Lan2Xuechen Lan3Qian Wang4Qian Wang5Ping Dong6Ping Dong7Gang Wang8Gang Wang9School of Resource Engineering, Xi'an University of Architecture and Technology, Xi’an, ChinaKey Laboratory of Gold and Resources in Shaanxi Province, Xi’an, ChinaSchool of Resource Engineering, Xi'an University of Architecture and Technology, Xi’an, ChinaKey Laboratory of Gold and Resources in Shaanxi Province, Xi’an, ChinaSchool of Resource Engineering, Xi'an University of Architecture and Technology, Xi’an, ChinaKey Laboratory of Gold and Resources in Shaanxi Province, Xi’an, ChinaSchool of Resource Engineering, Xi'an University of Architecture and Technology, Xi’an, ChinaKey Laboratory of Gold and Resources in Shaanxi Province, Xi’an, ChinaSchool of Resource Engineering, Xi'an University of Architecture and Technology, Xi’an, ChinaKey Laboratory of Gold and Resources in Shaanxi Province, Xi’an, ChinaWith a telluride-type gold ore flotation concentrate as the research object, the Na2S + NaOH collaborative leaching process was applied to selectively separate tellurium before the cyanide leaching of gold and silver. The effects of process parameters including the type of leaching agent, the amount of leaching agent, liquid-solid ratio, leaching temperature, and leaching time on the leaching rate of tellurium were investigated. The results showed that the tellurium leaching rate could reach 78.14% under the optimum conditions of −0.038 mm (95%) grinding fineness, 80 g/L Na2S concentration, 30 g/L NaOH concentration, 4:1 liquid-solid ratio, 80°C leaching temperature and 3 h′s leaching time. The kinetic analysis showed that the leaching process of tellurium from telluride-type gold concentrate was a mixed type of chemical reaction control and diffusion control. The grain parameter in the leaching process was 0.26263 and the apparent activation energy E = 17.12 kJ/mol. Tellurium could be pre-leached from the telluride-type gold flotation concentrate through the Na2S + NaOH alkaline leaching process to achieve the effective separation of tellurium from noble metals, which, when eliminating the adverse effects of telluride on the leaching of gold and silver, provides new ideas for the extraction of rare element tellurium.https://www.frontiersin.org/articles/10.3389/fchem.2021.593888/fulltelluride-type gold concentratecooperative leachingpre-separationtelluriumleaching rate
spellingShingle Wei Yang
Wei Yang
Xuechen Lan
Xuechen Lan
Qian Wang
Qian Wang
Ping Dong
Ping Dong
Gang Wang
Gang Wang
Selective Pre-leaching of Tellurium From Telluride-Type Gold Concentrate
Frontiers in Chemistry
telluride-type gold concentrate
cooperative leaching
pre-separation
tellurium
leaching rate
title Selective Pre-leaching of Tellurium From Telluride-Type Gold Concentrate
title_full Selective Pre-leaching of Tellurium From Telluride-Type Gold Concentrate
title_fullStr Selective Pre-leaching of Tellurium From Telluride-Type Gold Concentrate
title_full_unstemmed Selective Pre-leaching of Tellurium From Telluride-Type Gold Concentrate
title_short Selective Pre-leaching of Tellurium From Telluride-Type Gold Concentrate
title_sort selective pre leaching of tellurium from telluride type gold concentrate
topic telluride-type gold concentrate
cooperative leaching
pre-separation
tellurium
leaching rate
url https://www.frontiersin.org/articles/10.3389/fchem.2021.593888/full
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