Bis{2-[(2,4-dimethylphenyl)iminomethyl]pyridine-κ2N,N′}bis(thiocyanato-κN)cadmium
The title compound, [Cd(NCS)2(C14H14N2)2], features crystallographic inversion symmetry with the CdII ion located on a centre of inversion. The CdII ion is six-coordinated in a slightly distorted octahedral geometry with the thiocyanate anions in axial positions. The angle between the benzene and py...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812002772 |
| _version_ | 1819290745111052288 |
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| author | Mohammad Malekshahian Mohamad Reza Talei Bavil Olyai Behrouz Notash |
| author_facet | Mohammad Malekshahian Mohamad Reza Talei Bavil Olyai Behrouz Notash |
| author_sort | Mohammad Malekshahian |
| collection | DOAJ |
| description | The title compound, [Cd(NCS)2(C14H14N2)2], features crystallographic inversion symmetry with the CdII ion located on a centre of inversion. The CdII ion is six-coordinated in a slightly distorted octahedral geometry with the thiocyanate anions in axial positions. The angle between the benzene and pyridine rings is 69.64 (9)°. An intermolecular C—H...S hydrogen bond stabilizes the crystal structure. |
| first_indexed | 2024-12-24T03:27:37Z |
| format | Article |
| id | doaj.art-ae5994354eeb499394bf871f2b12fa35 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:27:37Z |
| publishDate | 2012-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-ae5994354eeb499394bf871f2b12fa352022-12-21T17:17:18ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682m218m21910.1107/S1600536812002772Bis{2-[(2,4-dimethylphenyl)iminomethyl]pyridine-κ2N,N′}bis(thiocyanato-κN)cadmiumMohammad MalekshahianMohamad Reza Talei Bavil OlyaiBehrouz NotashThe title compound, [Cd(NCS)2(C14H14N2)2], features crystallographic inversion symmetry with the CdII ion located on a centre of inversion. The CdII ion is six-coordinated in a slightly distorted octahedral geometry with the thiocyanate anions in axial positions. The angle between the benzene and pyridine rings is 69.64 (9)°. An intermolecular C—H...S hydrogen bond stabilizes the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536812002772 |
| spellingShingle | Mohammad Malekshahian Mohamad Reza Talei Bavil Olyai Behrouz Notash Bis{2-[(2,4-dimethylphenyl)iminomethyl]pyridine-κ2N,N′}bis(thiocyanato-κN)cadmium Acta Crystallographica Section E |
| title | Bis{2-[(2,4-dimethylphenyl)iminomethyl]pyridine-κ2N,N′}bis(thiocyanato-κN)cadmium |
| title_full | Bis{2-[(2,4-dimethylphenyl)iminomethyl]pyridine-κ2N,N′}bis(thiocyanato-κN)cadmium |
| title_fullStr | Bis{2-[(2,4-dimethylphenyl)iminomethyl]pyridine-κ2N,N′}bis(thiocyanato-κN)cadmium |
| title_full_unstemmed | Bis{2-[(2,4-dimethylphenyl)iminomethyl]pyridine-κ2N,N′}bis(thiocyanato-κN)cadmium |
| title_short | Bis{2-[(2,4-dimethylphenyl)iminomethyl]pyridine-κ2N,N′}bis(thiocyanato-κN)cadmium |
| title_sort | bis 2 2 4 dimethylphenyl iminomethyl pyridine amp 954 2n n amp 8242 bis thiocyanato amp 954 n cadmium |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812002772 |
| work_keys_str_mv | AT mohammadmalekshahian bis224dimethylphenyliminomethylpyridineamp9542nnamp8242bisthiocyanatoamp954ncadmium AT mohamadrezataleibavilolyai bis224dimethylphenyliminomethylpyridineamp9542nnamp8242bisthiocyanatoamp954ncadmium AT behrouznotash bis224dimethylphenyliminomethylpyridineamp9542nnamp8242bisthiocyanatoamp954ncadmium |