Study of the interaction of sorbed silver, gold and copper ions with functional groups on hydrolyzed fibroin using Charmm22 force field calculations
We studied the sorption of silver, gold, and copper ions into powdered hydrolyzed fibroin derived from silk fibroin fibers. Metal ions sorbed into hydrolyzed fibroin have been found to interact with active functional groups over time. It was hypothesized that the silver and gold ions sorbed into hyd...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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Iranian Chemical Science and Technologies Association
2022-05-01
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| Series: | Chemical Review and Letters |
| Subjects: | |
| Online Access: | https://www.chemrevlett.com/article_150104_896714c29a8732c3c764947ff011ceb9.pdf |
| _version_ | 1797802470591692800 |
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| author | Khushnudbek Eshchanov Mukhabbat Baltaeva |
| author_facet | Khushnudbek Eshchanov Mukhabbat Baltaeva |
| author_sort | Khushnudbek Eshchanov |
| collection | DOAJ |
| description | We studied the sorption of silver, gold, and copper ions into powdered hydrolyzed fibroin derived from silk fibroin fibers. Metal ions sorbed into hydrolyzed fibroin have been found to interact with active functional groups over time. It was hypothesized that the silver and gold ions sorbed into hydrolyzed fibroin would form nanoparticles as a result of the reduction reaction, while the copper ions would form a coordination bond. Charmm22 force field calculations were performed on this basis. The IR spectral results obtained by calculations were compared with the IR spectral results obtained in practice, and it was proved that silver and gold nanoparticles were formed and that copper ions formed coordination bonds with fibroin |
| first_indexed | 2024-03-13T05:06:05Z |
| format | Article |
| id | doaj.art-ae5a6315f4924dc8b30f8ac31da51e85 |
| institution | Directory Open Access Journal |
| issn | 2676-7279 2645-4947 |
| language | English |
| last_indexed | 2024-03-13T05:06:05Z |
| publishDate | 2022-05-01 |
| publisher | Iranian Chemical Science and Technologies Association |
| record_format | Article |
| series | Chemical Review and Letters |
| spelling | doaj.art-ae5a6315f4924dc8b30f8ac31da51e852023-06-16T12:45:02ZengIranian Chemical Science and Technologies AssociationChemical Review and Letters2676-72792645-49472022-05-015316116810.22034/crl.2022.335548.1159150104Study of the interaction of sorbed silver, gold and copper ions with functional groups on hydrolyzed fibroin using Charmm22 force field calculationsKhushnudbek Eshchanov0Mukhabbat Baltaeva1Department of Chemistry, Faculty of Natural Sciences,Urgench State University, Urgench, UzbekistanDepartment of Chemistry, Faculty of Natural Sciences,Urgench State University, Urgench, UzbekistanWe studied the sorption of silver, gold, and copper ions into powdered hydrolyzed fibroin derived from silk fibroin fibers. Metal ions sorbed into hydrolyzed fibroin have been found to interact with active functional groups over time. It was hypothesized that the silver and gold ions sorbed into hydrolyzed fibroin would form nanoparticles as a result of the reduction reaction, while the copper ions would form a coordination bond. Charmm22 force field calculations were performed on this basis. The IR spectral results obtained by calculations were compared with the IR spectral results obtained in practice, and it was proved that silver and gold nanoparticles were formed and that copper ions formed coordination bonds with fibroinhttps://www.chemrevlett.com/article_150104_896714c29a8732c3c764947ff011ceb9.pdfcharmm22 force fieldhydrolyzed fibroin (“ hf” )nanoparticlescoordination bondsir spectrum |
| spellingShingle | Khushnudbek Eshchanov Mukhabbat Baltaeva Study of the interaction of sorbed silver, gold and copper ions with functional groups on hydrolyzed fibroin using Charmm22 force field calculations Chemical Review and Letters charmm22 force field hydrolyzed fibroin (“ hf” ) nanoparticles coordination bonds ir spectrum |
| title | Study of the interaction of sorbed silver, gold and copper ions with functional groups on hydrolyzed fibroin using Charmm22 force field calculations |
| title_full | Study of the interaction of sorbed silver, gold and copper ions with functional groups on hydrolyzed fibroin using Charmm22 force field calculations |
| title_fullStr | Study of the interaction of sorbed silver, gold and copper ions with functional groups on hydrolyzed fibroin using Charmm22 force field calculations |
| title_full_unstemmed | Study of the interaction of sorbed silver, gold and copper ions with functional groups on hydrolyzed fibroin using Charmm22 force field calculations |
| title_short | Study of the interaction of sorbed silver, gold and copper ions with functional groups on hydrolyzed fibroin using Charmm22 force field calculations |
| title_sort | study of the interaction of sorbed silver gold and copper ions with functional groups on hydrolyzed fibroin using charmm22 force field calculations |
| topic | charmm22 force field hydrolyzed fibroin (“ hf” ) nanoparticles coordination bonds ir spectrum |
| url | https://www.chemrevlett.com/article_150104_896714c29a8732c3c764947ff011ceb9.pdf |
| work_keys_str_mv | AT khushnudbekeshchanov studyoftheinteractionofsorbedsilvergoldandcopperionswithfunctionalgroupsonhydrolyzedfibroinusingcharmm22forcefieldcalculations AT mukhabbatbaltaeva studyoftheinteractionofsorbedsilvergoldandcopperionswithfunctionalgroupsonhydrolyzedfibroinusingcharmm22forcefieldcalculations |