catena-Poly[[bis[2-(1H-1,2,4-triazol-1-yl-κN4)pyrazine]cadmium(II)]-di-μ-thiocyanato-κ2S:N;κ2N:S]
The title compound, [Cd(NCS)2(C6H5N5)2]n, is a coordination polymer with the CdII centre located on a twofold rotation axis. The CdII centre assumes a distorted octahedral geometry. The thiocyanate anions function as bridging ligands between the CdII centres, leading to a chain-like arrangement expa...
Main Authors: | , |
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Format: | Article |
Language: | English |
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International Union of Crystallography
2009-08-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809027135 |
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author | Long Miao Xie Hong Li |
author_facet | Long Miao Xie Hong Li |
author_sort | Long Miao Xie |
collection | DOAJ |
description | The title compound, [Cd(NCS)2(C6H5N5)2]n, is a coordination polymer with the CdII centre located on a twofold rotation axis. The CdII centre assumes a distorted octahedral geometry. The thiocyanate anions function as bridging ligands between the CdII centres, leading to a chain-like arrangement expanding along [001]. |
first_indexed | 2024-12-20T08:05:49Z |
format | Article |
id | doaj.art-ae5bf41040144dffbad10c3b96d0b48f |
institution | Directory Open Access Journal |
issn | 1600-5368 |
language | English |
last_indexed | 2024-12-20T08:05:49Z |
publishDate | 2009-08-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E |
spelling | doaj.art-ae5bf41040144dffbad10c3b96d0b48f2022-12-21T19:47:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-08-01658m935m93510.1107/S1600536809027135catena-Poly[[bis[2-(1H-1,2,4-triazol-1-yl-κN4)pyrazine]cadmium(II)]-di-μ-thiocyanato-κ2S:N;κ2N:S]Long Miao XieHong LiThe title compound, [Cd(NCS)2(C6H5N5)2]n, is a coordination polymer with the CdII centre located on a twofold rotation axis. The CdII centre assumes a distorted octahedral geometry. The thiocyanate anions function as bridging ligands between the CdII centres, leading to a chain-like arrangement expanding along [001].http://scripts.iucr.org/cgi-bin/paper?S1600536809027135 |
spellingShingle | Long Miao Xie Hong Li catena-Poly[[bis[2-(1H-1,2,4-triazol-1-yl-κN4)pyrazine]cadmium(II)]-di-μ-thiocyanato-κ2S:N;κ2N:S] Acta Crystallographica Section E |
title | catena-Poly[[bis[2-(1H-1,2,4-triazol-1-yl-κN4)pyrazine]cadmium(II)]-di-μ-thiocyanato-κ2S:N;κ2N:S] |
title_full | catena-Poly[[bis[2-(1H-1,2,4-triazol-1-yl-κN4)pyrazine]cadmium(II)]-di-μ-thiocyanato-κ2S:N;κ2N:S] |
title_fullStr | catena-Poly[[bis[2-(1H-1,2,4-triazol-1-yl-κN4)pyrazine]cadmium(II)]-di-μ-thiocyanato-κ2S:N;κ2N:S] |
title_full_unstemmed | catena-Poly[[bis[2-(1H-1,2,4-triazol-1-yl-κN4)pyrazine]cadmium(II)]-di-μ-thiocyanato-κ2S:N;κ2N:S] |
title_short | catena-Poly[[bis[2-(1H-1,2,4-triazol-1-yl-κN4)pyrazine]cadmium(II)]-di-μ-thiocyanato-κ2S:N;κ2N:S] |
title_sort | catena poly bis 2 1h 1 2 4 triazol 1 yl amp 954 n4 pyrazine cadmium ii di amp 956 thiocyanato amp 954 2s n amp 954 2n s |
url | http://scripts.iucr.org/cgi-bin/paper?S1600536809027135 |
work_keys_str_mv | AT longmiaoxie catenapolybis21h124triazol1ylamp954n4pyrazinecadmiumiidiamp956thiocyanatoamp9542snamp9542ns AT hongli catenapolybis21h124triazol1ylamp954n4pyrazinecadmiumiidiamp956thiocyanatoamp9542snamp9542ns |