Interesterificação química de óleo de soja e óleo de soja totalmente hidrogenado: influência do tempo de reação Chemical interesterification of soybean oil and fully hydrogenated soybean oil: Influence of the reaction time

<abstract language="eng">Chemical interesterification is an important alternative to produce zero trans fats. In practice, however, excessive reaction times are used to ensure complete randomization. This work evaluated the influence of the reaction time on the interesterification of...

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Main Authors: Ana Paula Badan Ribeiro, Monise Helen Masuchi, Renato Grimaldi, Lireny Aparecida Guaraldo Gonçalves
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2009-01-01
Series:Química Nova
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422009000400021
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author Ana Paula Badan Ribeiro
Monise Helen Masuchi
Renato Grimaldi
Lireny Aparecida Guaraldo Gonçalves
author_facet Ana Paula Badan Ribeiro
Monise Helen Masuchi
Renato Grimaldi
Lireny Aparecida Guaraldo Gonçalves
author_sort Ana Paula Badan Ribeiro
collection DOAJ
description <abstract language="eng">Chemical interesterification is an important alternative to produce zero trans fats. In practice, however, excessive reaction times are used to ensure complete randomization. This work evaluated the influence of the reaction time on the interesterification of soybean oil/fully hydrogenated soybean oil blend, carried out in the following conditions: 100 ºC, 500 rpm stirring speed, 0.4% (w/w) sodium methoxide catalyst. The triacylglycerol composition, solid fat content and melting point analysis showed that the reaction was very fast, reaching the equilibrium within 5 min. This result suggests the interesterification can be performed in substantially lower times, with reduction in process costs.
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spelling doaj.art-ae6371ca671f4a3e960ed08a80cd23b82022-12-21T22:36:01ZengSociedade Brasileira de QuímicaQuímica Nova0100-40421678-70642009-01-0132493994510.1590/S0100-40422009000400021Interesterificação química de óleo de soja e óleo de soja totalmente hidrogenado: influência do tempo de reação Chemical interesterification of soybean oil and fully hydrogenated soybean oil: Influence of the reaction timeAna Paula Badan RibeiroMonise Helen MasuchiRenato GrimaldiLireny Aparecida Guaraldo Gonçalves<abstract language="eng">Chemical interesterification is an important alternative to produce zero trans fats. In practice, however, excessive reaction times are used to ensure complete randomization. This work evaluated the influence of the reaction time on the interesterification of soybean oil/fully hydrogenated soybean oil blend, carried out in the following conditions: 100 ºC, 500 rpm stirring speed, 0.4% (w/w) sodium methoxide catalyst. The triacylglycerol composition, solid fat content and melting point analysis showed that the reaction was very fast, reaching the equilibrium within 5 min. This result suggests the interesterification can be performed in substantially lower times, with reduction in process costs.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422009000400021chemical interesterificationreaction timelow trans fat
spellingShingle Ana Paula Badan Ribeiro
Monise Helen Masuchi
Renato Grimaldi
Lireny Aparecida Guaraldo Gonçalves
Interesterificação química de óleo de soja e óleo de soja totalmente hidrogenado: influência do tempo de reação Chemical interesterification of soybean oil and fully hydrogenated soybean oil: Influence of the reaction time
Química Nova
chemical interesterification
reaction time
low trans fat
title Interesterificação química de óleo de soja e óleo de soja totalmente hidrogenado: influência do tempo de reação Chemical interesterification of soybean oil and fully hydrogenated soybean oil: Influence of the reaction time
title_full Interesterificação química de óleo de soja e óleo de soja totalmente hidrogenado: influência do tempo de reação Chemical interesterification of soybean oil and fully hydrogenated soybean oil: Influence of the reaction time
title_fullStr Interesterificação química de óleo de soja e óleo de soja totalmente hidrogenado: influência do tempo de reação Chemical interesterification of soybean oil and fully hydrogenated soybean oil: Influence of the reaction time
title_full_unstemmed Interesterificação química de óleo de soja e óleo de soja totalmente hidrogenado: influência do tempo de reação Chemical interesterification of soybean oil and fully hydrogenated soybean oil: Influence of the reaction time
title_short Interesterificação química de óleo de soja e óleo de soja totalmente hidrogenado: influência do tempo de reação Chemical interesterification of soybean oil and fully hydrogenated soybean oil: Influence of the reaction time
title_sort interesterificacao quimica de oleo de soja e oleo de soja totalmente hidrogenado influencia do tempo de reacao chemical interesterification of soybean oil and fully hydrogenated soybean oil influence of the reaction time
topic chemical interesterification
reaction time
low trans fat
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422009000400021
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