Neoproterozoic Aksu Diabase Dyke, Chinese South Tianshan: Magma Sources and Implications for Regional Gold Metallogeny

Tianshan is one of the world’s largest gold provinces; however, the relationship between gold mineralization and metasomatized subcontinental lithospheric mantle (SCLM) remains poorly understood. To improve our understanding, we present new bulk-rock geochemistry and platinum group element (PGE) con...

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Main Authors: Guoxiong Ma, Xiaobo Zhao, Chunji Xue, Renke Wang
Format: Article
Language:English
Published: MDPI AG 2023-02-01
Series:Minerals
Subjects:
Online Access:https://www.mdpi.com/2075-163X/13/3/326
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author Guoxiong Ma
Xiaobo Zhao
Chunji Xue
Renke Wang
author_facet Guoxiong Ma
Xiaobo Zhao
Chunji Xue
Renke Wang
author_sort Guoxiong Ma
collection DOAJ
description Tianshan is one of the world’s largest gold provinces; however, the relationship between gold mineralization and metasomatized subcontinental lithospheric mantle (SCLM) remains poorly understood. To improve our understanding, we present new bulk-rock geochemistry and platinum group element (PGE) concentrations of the SCLM-sourced Aksu Neoproterozoic diabase dykes in Chinese South Tianshan. These data, combined with in situ laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) analyses of hydrothermal pyrite grains in the diabase dykes, are used to discuss the SCLM source characteristics in the region and their potential links to formation of gold deposits. The diabase dykes exhibit high Th/Yb (0.47–0.62) and low Nb/U (13.4–16.3) ratios, indicating that magma evolution involves subduction-related fluid metasomatism and limited contamination of the continental crust. This is consistent with little variation in whole-rock Pd/Zr, Cu/Zr, and Ni/MgO ratios, suggesting that no sulfide segregation was caused by crustal contamination and magma mixing. In addition, the diabase dykes show low PGE and Au contents, with high Cu/Pd (>10<sup>5</sup>) and low Cu/Zr (<0.5) ratios, indicating that magmas were derived from low-degree partial melting of the SCLM under S-saturated conditions. Such source characteristics indicate residual sulfides and chalcophile elements (e.g., PGEs, Au, and Cu) were concentrated at the SCLM reservoir in South Tianshan. Hydrothermal pyrite in the studied dykes has similar Au/Ag ratios and trace element distribution patterns to gold-bearing pyrite of lode gold deposits in Chinese South Tianshan, indicating that metasomatized SCLM may have contributed ore metals during the formation of these gold deposits. Adding to the available data, our study highlights that the SCLM may be a potential metal source reservoir, and it may have contributed to formation of the lode gold deposits in Chinese South Tianshan.
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spelling doaj.art-ae79d9e7a36a42ddb2bae077199963ab2023-11-17T12:47:03ZengMDPI AGMinerals2075-163X2023-02-0113332610.3390/min13030326Neoproterozoic Aksu Diabase Dyke, Chinese South Tianshan: Magma Sources and Implications for Regional Gold MetallogenyGuoxiong Ma0Xiaobo Zhao1Chunji Xue2Renke Wang3State Key Laboratory of Geological Processes and Mineral Resources, School of Earth Sciences and Resources, China University of Geosciences, Xueyuan Road 29, Beijing 100083, ChinaState Key Laboratory of Geological Processes and Mineral Resources, School of Earth Sciences and Resources, China University of Geosciences, Xueyuan Road 29, Beijing 100083, ChinaState Key Laboratory of Geological Processes and Mineral Resources, School of Earth Sciences and Resources, China University of Geosciences, Xueyuan Road 29, Beijing 100083, ChinaState Key Laboratory of Geological Processes and Mineral Resources, School of Earth Sciences and Resources, China University of Geosciences, Xueyuan Road 29, Beijing 100083, ChinaTianshan is one of the world’s largest gold provinces; however, the relationship between gold mineralization and metasomatized subcontinental lithospheric mantle (SCLM) remains poorly understood. To improve our understanding, we present new bulk-rock geochemistry and platinum group element (PGE) concentrations of the SCLM-sourced Aksu Neoproterozoic diabase dykes in Chinese South Tianshan. These data, combined with in situ laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) analyses of hydrothermal pyrite grains in the diabase dykes, are used to discuss the SCLM source characteristics in the region and their potential links to formation of gold deposits. The diabase dykes exhibit high Th/Yb (0.47–0.62) and low Nb/U (13.4–16.3) ratios, indicating that magma evolution involves subduction-related fluid metasomatism and limited contamination of the continental crust. This is consistent with little variation in whole-rock Pd/Zr, Cu/Zr, and Ni/MgO ratios, suggesting that no sulfide segregation was caused by crustal contamination and magma mixing. In addition, the diabase dykes show low PGE and Au contents, with high Cu/Pd (>10<sup>5</sup>) and low Cu/Zr (<0.5) ratios, indicating that magmas were derived from low-degree partial melting of the SCLM under S-saturated conditions. Such source characteristics indicate residual sulfides and chalcophile elements (e.g., PGEs, Au, and Cu) were concentrated at the SCLM reservoir in South Tianshan. Hydrothermal pyrite in the studied dykes has similar Au/Ag ratios and trace element distribution patterns to gold-bearing pyrite of lode gold deposits in Chinese South Tianshan, indicating that metasomatized SCLM may have contributed ore metals during the formation of these gold deposits. Adding to the available data, our study highlights that the SCLM may be a potential metal source reservoir, and it may have contributed to formation of the lode gold deposits in Chinese South Tianshan.https://www.mdpi.com/2075-163X/13/3/326diabase dykessub-continental lithospheric mantlelode gold depositmetal sourceChinese South Tianshan
spellingShingle Guoxiong Ma
Xiaobo Zhao
Chunji Xue
Renke Wang
Neoproterozoic Aksu Diabase Dyke, Chinese South Tianshan: Magma Sources and Implications for Regional Gold Metallogeny
Minerals
diabase dykes
sub-continental lithospheric mantle
lode gold deposit
metal source
Chinese South Tianshan
title Neoproterozoic Aksu Diabase Dyke, Chinese South Tianshan: Magma Sources and Implications for Regional Gold Metallogeny
title_full Neoproterozoic Aksu Diabase Dyke, Chinese South Tianshan: Magma Sources and Implications for Regional Gold Metallogeny
title_fullStr Neoproterozoic Aksu Diabase Dyke, Chinese South Tianshan: Magma Sources and Implications for Regional Gold Metallogeny
title_full_unstemmed Neoproterozoic Aksu Diabase Dyke, Chinese South Tianshan: Magma Sources and Implications for Regional Gold Metallogeny
title_short Neoproterozoic Aksu Diabase Dyke, Chinese South Tianshan: Magma Sources and Implications for Regional Gold Metallogeny
title_sort neoproterozoic aksu diabase dyke chinese south tianshan magma sources and implications for regional gold metallogeny
topic diabase dykes
sub-continental lithospheric mantle
lode gold deposit
metal source
Chinese South Tianshan
url https://www.mdpi.com/2075-163X/13/3/326
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AT xiaobozhao neoproterozoicaksudiabasedykechinesesouthtianshanmagmasourcesandimplicationsforregionalgoldmetallogeny
AT chunjixue neoproterozoicaksudiabasedykechinesesouthtianshanmagmasourcesandimplicationsforregionalgoldmetallogeny
AT renkewang neoproterozoicaksudiabasedykechinesesouthtianshanmagmasourcesandimplicationsforregionalgoldmetallogeny